Skip to main content
SpringerLink
Log in

Structural and electrochemical performance of three-dimensional LiMn2O4 thin film

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

LiMn2O4 thin films with three-dimensional (3D) structure were prepared by the sol–gel method. Polystyrene beads (300 nm) were dispersed in the form of monolayers on Pt/Ti/SiO2/Si substrates, which were then used as templates for fabricating three-dimensionally ordered electrodes. A coating solution prepared from acetylacetonate sources was dropped on the template-deposited substrates, which were then calcinated at 400 °C. The templates were removed by calcinations, and a 3D structure was formed through an annealing process. The discharge capacity of the 3D LiMn2O4 films was 1.63–3.03 μAh cm−2. The capacity loss over 100 cycles was approximately 18%, however, the 3D structure was not destroyed during cycling.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Long JW, Dunn B, Rolison DR, White HS (2004) Chem Rev 104:4463

    Article  CAS  PubMed  Google Scholar 

  2. Nishizawa M, Mukai K, Kuwabata S, Martin CR, Yoneyama H (1997) J Electrochem Soc 144:1923

    Article  CAS  Google Scholar 

  3. Teixidor GT, Zaouk RB, Park BY, Madou MJ (2008) J Power Source 183:730

    Article  CAS  Google Scholar 

  4. Bates JB, Dudney NJ, Neudecker B, Ueda A, Evans CD (2000) Solid State Ionics 135:33

    Article  CAS  Google Scholar 

  5. Ergang NS, Fierke MA, Wang Z, Smyrl WH, Stein A (2007) J Electrochem Soc 154:A1135

    Article  CAS  Google Scholar 

  6. Albano F, Lin YS, Blaauw D, Sylvester DM, Wise KD, Sastry AM (2008) J Power Source 185:1524

    Article  CAS  Google Scholar 

  7. Tonti D, Torralvo MJ, Ensiso E, Sobrados I, Sanz J (2008) Chem Mater 20:4783

    Article  CAS  Google Scholar 

  8. Lee KT, Lytle JC, Eragang NS, Oh SM, Stein A (2005) Adv Funct Mater 15:547

    Article  CAS  Google Scholar 

  9. Son JT, Park KS, Kim HG (2004) J Mater Sci 39:3635. doi:10.1023/B:JMSC.0000030716.52790.96

    Article  CAS  ADS  Google Scholar 

  10. Callone E, Fletcher JM, Carturan G, Raj R (2008) J Mater Sci 43:4862. doi:10.1007/s10853-008-2707-x

    Article  CAS  ADS  Google Scholar 

  11. Wang D, Ding N, Song XH, Chen CH (2009) J Mater Sci 44:198. doi:10.1007/s10853-008-3104-1

    Google Scholar 

  12. Lee JT, Chu YJ, Wang FM, Yang CR, Li CC (2007) J Mater Sci 42:10118. doi:10.1007/s10853-007-2068-x

    Article  CAS  ADS  Google Scholar 

  13. Yi TF, Hu XG, Dai CS, Gao K (2007) J Mater Sci 42:3825. doi:10.1007/s10853-006-0460-6

    Article  CAS  ADS  Google Scholar 

  14. Wu MS, Lee JT, Chiang PCJ, Lin JC (2007) J Mater Sci 42:259. doi:10.1007/s10853-006-1062-z

    Article  CAS  ADS  Google Scholar 

  15. Sorek Y, Zhou P, Fischer E, Ishihara T (2000) J Mater Sci 35:4337. doi:10.1023/A:1004896621411

    Article  CAS  Google Scholar 

  16. Fu YP, Su YH, Lin CH, Wu SH (2006) J Mater Sci 41:1157. doi:10.1007/s10853-005-3646-4

    Article  CAS  ADS  Google Scholar 

  17. Che G, Jirage KB, Fisher ER, Martin CR (1997) J Electrochem Soc 144:4296

    Article  CAS  Google Scholar 

  18. Frangaud P, Nagarajan R, Schleich DM, Vujic D (1995) J Power Sources 54:362

    Article  Google Scholar 

  19. Chiu KF (2007) Thin Solid Films 515:4614

    Article  CAS  ADS  Google Scholar 

  20. Moon HS, Lee W, Reucroft PJ, Park JW (2003) J Power Sources 119–121:710

    Article  CAS  Google Scholar 

  21. Otsuji H, Kawahara K, Ikegami T, Ebihara K (2006) Thin Solid Films 506–507:120

    Article  CAS  Google Scholar 

  22. Xie J, Kohno K, Matsumura T, Imanishi N, Hirano A, Takeda Y, Yamamoto O (2008) Electrochim Acta 54:376

    Article  CAS  Google Scholar 

  23. Huang J, Yang J, Li W, Cai W, Jiang Z (2008) Thin Solid Films 516:3314

    Article  CAS  ADS  Google Scholar 

  24. Park YJ, Kim JG, Chung HT, Um WS, Kim MH, Kim HG (1998) J Power Source 76:41

    Article  CAS  Google Scholar 

  25. Park YJ, Kim JG, Kim MK, Chang HT, Kim HG (2000) Solid State Ionics 130:203

    Article  CAS  Google Scholar 

  26. Park BG, Ryu JH, Choi WY, Park YJ (2009) Bull Korean Chem Soc 30:653

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This study was supported by the Korea Research Foundation Grant funded by the Korean Government (MOEHRD)(KRF-2007-314-D00108).

Author information

Authors and Affiliations

  1. Department of Advanced Materials Engineering, Kyonggi University, San 94-6, Yiui-dong, Yeongtong-gu, Suwon, Gyeonggi-do, 443-760, Republic of Korea

    Bo Gun Park & Yong Joon Park

  2. Center for Energy Materials Research, Korea Institute of Science and Technology, Seoul, 130-650, Republic of Korea

    Soohyun Kim

  3. Department of Chemical and Biological Engineering, Seoul National University, Seoul, 151-744, Republic of Korea

    Soohyun Kim

  4. Optoelectronic Materials Research Center, Korea Institute of Science and Technology, Seoul, 130-650, Republic of Korea

    Il-Doo Kim

Authors
  1. Bo Gun Park
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Soohyun Kim
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Il-Doo Kim
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yong Joon Park
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yong Joon Park.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Park, B.G., Kim, S., Kim, ID. et al. Structural and electrochemical performance of three-dimensional LiMn2O4 thin film. J Mater Sci 45, 3947–3953 (2010). https://doi.org/10.1007/s10853-010-4460-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-010-4460-1

Keywords

Search

Navigation