Abstract
Fully dense ZrB2–SiC and HfB2–SiC ultra-high-temperature ceramics (UHTCs) composites are fabricated by first synthesizing via self-propagating high-temperature synthesis (SHS) the composite powders from B4C, Si, and Zr or Hf reactants, and subsequently consolidating the product by spark plasma sintering (SPS) without the addition of any sintering aid. It was found that the SHS technique leads to the complete conversion of reactants to the desired products and the SPS allows for the full consolidation (>99.5% relative density) under the optimal operating conditions of 1800 °C/20 min/20 MPa and 1800 °C/30 min/20 MPa, for the cases of ZrB2–SiC and HfB2–SiC, respectively. Based on the results reported in this work, it can be stated that the combination of SHS and SPS methods represents a particularly rapid and convenient preparation route (lower sintering temperature and processing time) for UHTCs as compared to the techniques available in the literature for the fabrication of analogous products.
Similar content being viewed by others
References
Upadhya K, Yang JM, Hoffmann WP (1997) Am Ceram Soc Bull 58:51
Fahrenholtz WG, Hilmas GE, Talmy IG, Zaykoski JA (2007) J Am Ceram Soc 90:1347
“Thermal protection materials and systems branch” NASA web site (https://doi.org/asm.arc.nasa.gov/materials.html) visited on October 2007
Levine SR, Opila EJ, Halbig MC, Kiser JD, Singh M, Salem JA (2003) J Eur Ceram Soc 22:2757
Savino R, De Stefano Fumo P, Paterna D, Serpico M (2005) Aerosp Sci Technol 9:151
Tripp WC, Davis HH, Graham HC (1973) Am Ceram Soc Bull 52:612
Monteverde F, Bellosi A (2003) J Electrochem Soc 150:552
Monteverde F, Bellosi A (2005) Solid State Sci 7:622
Monteverde F, Bellosi A (2005) J Eur Ceram Soc 25:1025
Monteverde F, Guicciardi S, Bellosi A (2003) Mat Sci Eng A 346:310
Fahrenholtz WG, Hilmas GE, Chamberlain AL, Zimmermann JW, Fahrenholtz B (2004) J Mater Sci 39:5951. doi:https://doi.org/10.1023/B:JMSC.0000041691.41116.bf
Chamberlain AL, Fahrenholtz WG, Hilmas GE, Ellerby DT (2004) J Am Ceram Soc 87:1170
Marschall J, Erlich DC, Manning H, Duppler W, Ellerby D, Gasch M (2004) J Mater Sci 39:5959. doi:https://doi.org/10.1023/B:JMSC.0000041692.72915.e8
Opeka MM, Talmy IG, Wuchina EJ, Zaykoski JA, Causey SJ (1999) J Eur Ceram Soc 19:2404
Zhang G-J, Deng Z-Y, Kondo N, Yang J-F, Ohji T (2000) J Am Ceram Soc 83:2330
Monteverde F, Bellosi A (2004) J Mater Res 19:3576
Medri V, Monteverde F, Balbo A, Bellosi A (2005) Adv Eng Mater 7:159
Anselmi-Tamburini U, Kodera Y, Gasch M, Unuvar C, Munir ZA, Ohyanagi M, Johnson SM (2006) J Mater Sci 41:3097. doi:https://doi.org/10.1007/s10853-005-2457-y
Monteverde F, Melandri C, Guicciardi S (2006) Mater Chem Phys 100:513
Monteverde F (2007) J Alloys Comp 428:197
Licheri R, Orrù R, Musa C, Cao G (2008) Mater Lett 62:432
Munir ZA, Anselmi-Tamburini U, Ohyanagi M (2006) J Mater Sci 41:763. doi:https://doi.org/10.1007/s10853-006-6555-2
Munir ZA, Anselmi-Tamburini U (1989) Mater Sci Rep 3:277
Cincotti A, Licheri R, Locci AM, Orrù R, Cao G (2003) J Chem Technol Biot 78:122
Locci AM, Orrù R, Cao G, Munir ZA (2006) J Am Ceram Soc 89:848
Matthews FL, Rawlings R (1994) Composite materials: engineering and science. Chapman & Hall, Great Britain
Barin I (1993) Thermochemical data of pure substances. VHC, Weinheim, Germany
Gasch M, Ellerby D, Irby E, Beckman S, Gusman M, Johnson S (2004) J Mater Sci 39:5925. doi:https://doi.org/10.1023/B:JMSC.0000041689.90456.af
Acknowledgements
IM Innovative Materials s.r.l. (Italy) is gratefully acknowledged for granting the use of SPS apparatus. We also gratefully acknowledge the Regione Autonoma della Sardegna (Italy) for financial support through the project POR Sardegna 2000–2006 (Misura 3.13). In addition the authors would like to thank Dr. Luigi Scatteia from CIRA (Italy) for the measurements of resistance to oxidation of SPS samples.
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Licheri, R., Orrù, R., Musa, C. et al. Spark plasma sintering of UHTC powders obtained by self-propagating high-temperature synthesis. J Mater Sci 43, 6406–6413 (2008). https://doi.org/10.1007/s10853-008-2630-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-008-2630-1