Skip to main content
SpringerLink
Log in

Study of structure and properties of ZnO–Bi2O3–P2O5 glasses

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Glasses of the ternary system ZnO–Bi2O3–P2O5 were prepared and studied in two compositional series 50ZnO–xBi2O3–(50 − x)P2O5 and (50 − y)ZnO–yBi2O3–50P2O5. Two distinct glass-forming regions were found in the 50ZnO–xBi2O3–(50 − x)P2O5 glass series with x = 0–10 and 20–35 mol.% Bi2O3. All prepared Bi2O3-containing glasses reveal a high chemical durability. Small additions of Bi2O3 (∼5 mol.%) improve thermal stability of glasses. All glasses crystallize on heating within the temperature range of 505–583 °C. Structural studies by Raman and 31P MAS NMR spectroscopies showed the rapid depolymerisation of phosphate chains within the first region with x = 0–15 and the presence of isolated Q0 phosphate units within the second region with x = 20–35. Raman studies showed that bismuth is incorporated in the glass structure in BiO6 units and their vibrational bands were observed within the spectral region of 350–700 cm−1. The evolution of properties and the spectroscopic data are both in accordance with a network former effect of Bi2O3.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Ray NH (1978) Inorganic polymers. Academic Press, London

    Google Scholar 

  2. Peng YB, Day DE (1991) Glass Technol 32:166

    CAS  Google Scholar 

  3. Montagne L, Palavit G, Mairesse G (1996) Phys Chem Glasses 37:206

    CAS  Google Scholar 

  4. Shaim A, Et-Tabirou M (2003) Ann Chim Sci Mat 28:17

    Article  CAS  Google Scholar 

  5. Daviero S, Montagne L, Palavit G, Mairesse G, Belin S, Briois V (2003) J Phys Chem Solids 64:253

    Article  CAS  Google Scholar 

  6. Montagne L, Palavit G, Mairesse G, Draoui M, Aomari K, Saidi Idrissi M (1997) Phys Chem Glasses 38:15

    Google Scholar 

  7. Ahaman Z, Et-Tabirou M, Hafid M (1996) Phase Trans 56:247

    Article  CAS  Google Scholar 

  8. Shaim A, Et-Tabirou M (2001) Phys Chem Glasses 42:381

    CAS  Google Scholar 

  9. Shaim A, Et-Tabirou M, Montagne L, Palavit G (2002) Phys Chem Glasses 37:2459

    CAS  Google Scholar 

  10. Shaim A, Et-Tabirou M, Montagne L, Palavit G (2003) Phys Chem Glasses 44:26

    CAS  Google Scholar 

  11. Montagne L, Daviero S, Palavit G, Shaim A, Et-Tabirou M (2003) Chem Mater 15:4709

    Article  CAS  Google Scholar 

  12. Chahine A, Et-Tabirou M (2002) Mater Res Bull 37:1973

    CAS  Google Scholar 

  13. Chahine A, Et-Tabirou M, Pascal JL (2004) Phys Chem Glasses 45:32

    CAS  Google Scholar 

  14. Chahine A, Et-Tabirou M, Pascal JL (2004) Mater Lett 58:2776

    Article  CAS  Google Scholar 

  15. Elouadi B, Ouchetto M, Arbib ElH, Amraoui N (1988) Phase Trans 13:219

    Article  CAS  Google Scholar 

  16. Van Wazer J (1951) Phosphorus and its compounds, vol 1 and 2. Interscience, New York

    Google Scholar 

  17. Brow RK, Tallant DR, Myers ST, Phifer CC (1995) J Non-Cryst Solids 191:45

    Article  CAS  Google Scholar 

  18. Wiench JW, Pruski M, Tischendorf B, Otaigbe JU, Sales BC (2000) J Non-Cryst Solids 263/264:101

    Article  Google Scholar 

  19. Bobovich YS (1962) Opt Spektrosk 13:492

    CAS  Google Scholar 

  20. Nelson BN, Exarhos GJ (1979) J Chem Phys 71:2739

    Article  CAS  Google Scholar 

  21. Fawcett V, Long AD, Taylor LH (1976) In: Schmid ED, Brandmueller J, Kiefer W (eds) Proc. Int. Conf. Raman Spectrosc., 5th edn. Hans Ferdinand Schulz Verlag, Freiburg, p 112

  22. Nakamoto K (1997) Infrared and Raman spectra of inorganic and coordination compounds. John Wiley & Sons, New York

    Google Scholar 

  23. Baia L, Simon S, Iliescu T, Kiefer W (2001) J Mol Struct 599:9

    Article  CAS  Google Scholar 

  24. Kharlamov AA, Almeida RM, Heo J (1996) J Non-Cryst Solids 202:233

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The Czech authors are grateful for the financial support from the research project No. 0021627501 of the Ministry of Education of Czech Republic and grant No. 104/07/0315 of Grant Agency of Czech Republic.

Author information

Authors and Affiliations

  1. Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, 532 10, Pardubice, Czech Republic

    Josef Jirák, Ladislav Koudelka, Jaroslav Pospíšil & Petr Mošner

  2. Unité de Catalyse et Chimie du Solide, Université des Sciences et Technologies de Lille, Ecole Nationale Superieure de Chimie de Lille, BP108, 59652, Villeneuve d’Ascq cedex, France

    Lionel Montagne & Laurent Delevoye

Authors
  1. Josef Jirák
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ladislav Koudelka
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jaroslav Pospíšil
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Petr Mošner
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Lionel Montagne
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Laurent Delevoye
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Ladislav Koudelka.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jirák, J., Koudelka, L., Pospíšil, J. et al. Study of structure and properties of ZnO–Bi2O3–P2O5 glasses. J Mater Sci 42, 8592–8598 (2007). https://doi.org/10.1007/s10853-007-1848-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-007-1848-7

Keywords

Search

Navigation