Abstract
A novel method to prepare iron oxide nanoparticles by precipitation in bicontinuous microemulsions is reported. Precipitation reactions were carried out in microemulsions stabilized with a mixture of dodecyltrimethylammonium bromide/didodecyldimethylammonium bromide (3/2, w/w). Nanoparticles were characterized by X-ray diffraction, transmission electronic microscopy (TEM) and vibrating sample magnetometry (VSM), and consisted of magnetite or a mixture of magnetite and maghemite. The particles have an average diameter of 8 nm with a relatively narrow particle size distribution and show possible superparamagnetic behavior. Noticeably higher yields of precipitate are observed for this new approach in comparison with those typicall obtained using reverse microemulsions.
Similar content being viewed by others
References
Shinkai M (2002) J Biosci Bioeng 94:606
Pankhurst QA, Connolly J, Jones SK, Dobson J (2003) J Phys D: Appl Phys 36:R167
Tartaj P, Morales MP, Veintemillas-Verdaguer S, Gonzalez-Carreño T, Serna CJ (2003) J Phys D: Appl Phys 36:R182
Berry CC, Curtis ASG (2003) J Phys D: Appl Phys 36:R198
Gobe M, Kon-no K, Kandori K, Kitahara A (1983) J Colloid Interf Sci 93:293
Bandow S, Kimura K, Kon-no K, Kitahara A (1987) Jpn J Appl Phys 26:713
Lee KM, Sorensen CM, Klabunde KJ, Hadjipanayis GC (1992) IEEE Trans Magn 28:3180
Liz L, Lopez-Quintela MA, Mira J, Rivas J (1994) J Mater Sci 29:3797
Pillai VK (1995) PhD Thesis, University of Florida
Dresco PA, Zaitsev VS, Gambino RJ, Chu B (1999) Langmuir 15:1945
Lee HS, Lee WC, Furubayashi T (1999) J Appl Phys 85:5231
Santra S, Tapec R, Theodoropoulou N, Dobson J, Hebard A, Tan W (2001) Langmuir 17:1900
Liu ZL, Wang X, Yao KL, Du GH, Lu QH, Ding ZH, Tao J, Ning Q, Luo XP, Tian DY, Xi D (2004) J Mater Sci 39:2633
Lee Y, Lee J, Bae CJ, Park JG, Noh HJ, Park JH, Hyeon T (2005) Adv Funct Mater 15:503
Lopez-Lopez MT, Duran JDG, Delgado AV, Gonzalez-Caballero F (2005) J Colloid Interf Sci 291:144
Mikhaylova M, Kim DK, Bobrysheva N, Osmolowsky M, Semenov V, Tsakalakos T, Muhammed M (2004) Langmuir 20:2472
Osseo-Asare K (1999) Handbook of microemulsion science and technology, chap. 18. Marcel Dekker, Inc., New York
Ezrahi S, Aserin A, Garti N (1999) Handbook of microemulsion science and technology, chap. 7. Marcel Dekker, Inc., New York
Salager JL, Anton RE (1999) Handbook of microemulsion science and technology, chap. 8. Marcel Dekker, Inc., New York
Selim S (1997) U.S. Patent 5695901
Lopez Perez JA, Lopez Quintela MA, Mira J, Rivas J, Charles SW (1997) J Phys Chem B 101:8045
Lopez-Perez JA, Lopez-Quintela MA, Mira J, Rivas J (1997) IEEE Trans Magn 33:4359
Kodama RH (1999) J Magn Magn Mater 200:359
Cornell RM, Schwertmann U (1996) The iron oxides. structure, properties, reactions, occurrence and uses. VCH, Weinheim, Germany
Lee Y, Lee J, Bae CJ, Park JG, Noh HJ, Park JH, Hyeon T (2005) Adv Funct Mater 15:2036
Acknowledgment
CONACyT supported this research through grant SEP 2003-CO2-45436. Two of us (IAF and JE) acknowledge scholarships from CONACyT to pursue her Doctoral and MSc works, respectively. We are grateful to Selene Guzmán for her support in TEM measurements and Janet Valdés and Patricia Siller for their assistance in acquiring various specialized documents.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Esquivel, J., Facundo, I.A., Treviño, M.E. et al. A novel method to prepare magnetic nanoparticles: precipitation in bicontinuous microemulsions. J Mater Sci 42, 9015–9020 (2007). https://doi.org/10.1007/s10853-007-1834-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-007-1834-0