Skip to main content
Log in

Effect of aluminum content on the passivation behavior of Fe–Al alloys in sulfuric acid solution

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The passivation behavior of Fe–Al alloys (3.4, 10.4, 18.7, 19.4, 29.5, and 41.7 at % Al) and Fe–Al alloys (19.5 and 29.0 at % Al) with 5.1 at % Cr addition in 0.1 N H2SO4 is reported in this paper. The behavior has been evaluated by potentiodynamic polarization measurements. The results show the Fe–Al alloys, which the Al content of alloy exceeds 19 at %, have wide passivation regions with low passivation current. However, when the Al content of Fe–Al alloys exceeds this range, the increment of Al content has slight influence on passivation behavior compared with ternary Cr addition.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. C. G. MCKAMEY, J. H. DE VAN, P. F. TORTORELLI and V. K. SIKKA, J. Mater. Res. 6 (1991) 1779.

    CAS  Google Scholar 

  2. R. R. JUDKINS, U.S. Rao, Intermetallics 8 (2000) 1347.

    Article  CAS  Google Scholar 

  3. V. SHANKAR RAO and V. S. RAJA, Intermetallics 11 (2003) 119.

    Article  CAS  Google Scholar 

  4. C. T. LIU, E. H. LEE and C. G. MCKAMEY, Scr. Metall. 23 (1989) 875.

    Article  CAS  Google Scholar 

  5. C. T. LIU, C. G. MCKAMEY and E. H. LEE, Scr. Metall. Mater. 24 (1990) 385.

    Article  CAS  Google Scholar 

  6. C. L. FU and G. S. PAINTER, J. Mater. Res. 6 (1991) 719.

    CAS  Google Scholar 

  7. A. CASTAGNA and N. S. STOLOFF, Mater. Sci. Eng. A 192/193 (1995) 399.

    Article  Google Scholar 

  8. W. C. LUU and J. K. WU, J. Mater. Sci. 35 (2000) 4121.

    Article  CAS  Google Scholar 

  9. W. C. LUU and J. K. WU, Mater. Chem. Phys. 70 (2001) 236.

    Article  CAS  Google Scholar 

  10. R. BALASUBRAMANIAM, J. Alloy Compd. 330/332 (2002) 506.

    Article  Google Scholar 

  11. C. G. MCKAMEY, J. A. HORTON and C. T. LIU, J. Mater. Res. 4 (1989) 1156.

    CAS  Google Scholar 

  12. C. G. MCKAMEY and C. T. LIU, Scr. Metall. Mater. 24 (1990) 2119.

    Article  CAS  Google Scholar 

  13. R. BALASUBRAMANIAM, J. Alloy Compd. 253/254 (1997) 148.

    Article  Google Scholar 

  14. J. P. TU, L. MENG and M. S. LIU, Scr. Mater. 38 (1998) 833.

    Article  CAS  Google Scholar 

  15. Y. D. HUANG, W. Y. YANG and Z. Q. SUN, Mater. Sci. Eng. A 263 (1999) 75.

    Article  Google Scholar 

  16. W. C. CHIANG, J. K. WU and C. Y. LIAO, Corros. Prevent. Contr. 49 (2002) 71.

    CAS  Google Scholar 

  17. T. B. MASSALSKI, Binary Alloy Phase Diagrams (ASM, OH, 1986) p. 147.

    Google Scholar 

  18. C. G. MCKAMEY, Physical Metallurgy and Processing of Intermetallic Compounds, Chapman & Hall, NY (1994) p. 351.

    Google Scholar 

  19. S. FRANGINI, N. B. DE CRISTOFARO, A. MIGNONE, J. LASCOVICH and R. GIORGI, Corros. Sci. 39 (1997) 1431.

    Article  CAS  Google Scholar 

  20. D. A. JONES, Principles and Prevention of Corrosion, 2nd. edn. Prentice-Hall, NJ, (1996).

    Google Scholar 

  21. H. C. CHOE, H. S. KIM, D. C. CHOI and K. H. KIM, J. Mater. Sci. 32 (1997) 1221.

    Article  CAS  Google Scholar 

  22. V. SHANKAR RAO, R. G. BALIGIDAD and V. S. RAJA, Corros. Sci. 44 (2002) 521.

    Article  CAS  Google Scholar 

  23. E. MCCAFFERTY, Corros. Sci. 44 (2002) 1393.

    Article  CAS  Google Scholar 

  24. S. FRANGINI, J. LASCOVICH and N. B. DE CRISTOFARO, Mater. Sci. Forum 185/188 (1995) 1041.

    Article  Google Scholar 

  25. R. A. BUCHANAN, J. G. KIM, R. E. RICKER and L. A. HELDT, in Physical Metallurgy and Processing of Intermetallic Compounds, ed. N. S. STOLOFF, V. K. SIKKA, Chapman & Hall, NY (1994) p. 517.

  26. M. C. GARCÍA-ALONSO, M. F. LÓPEZ, M. L. ESCUDERO, J. L. GONZÁLEZ-CARRASCO and D. G. MORRIS, Intermetallics 7 (1999) 185.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jiann-Kuo Wu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chiang, WC., Luu, WC. & Wu, JK. Effect of aluminum content on the passivation behavior of Fe–Al alloys in sulfuric acid solution. J Mater Sci 41, 3041–3044 (2006). https://doi.org/10.1007/s10853-006-6783-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-006-6783-5

Keywords

Navigation