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Electrochemical Characteristics of the Fe78.5Ni1.0Mo0.5Si14.0B6.0 Amorphous Alloy in Corrosive Media of Different Nature

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The influence of the nature of corrosive media on the corrosion resistance of the Fe78.5Ni1.0Mo0.5Si14.0B6.0 amorphous ribbon metal alloy is investigated by using different electrochemical methods. We determine the electrochemical characteristics of the alloy in 0.5 M aqueous solutions of NaCl, HCl, KOH, and H2SO4 at T = (293 ± 1)°K. It is shown that the corrosion resistance of the amorphous material strongly depends on the component composition of corrosive media. We observe the formation of dense passivation layers on the surfaces of Fe78.5Ni1.0Mo0.5Si14.0B6.0 alloy in alkaline solutions.

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References

  1. G. Y. Koga, D. Travessa, G. Zepon, D. D. Coimbrao, and A. M. Jorge, “Corrosion resistance of pseudo-high entropy Fe-containing amorphous alloys in chloride-rich media,” J. Alloys Comp., 884, No. 5, 161090 (2021).

  2. J. Li, L. Yang, H. Ma, K. Jiang, and C. Chang, “Improved corrosion resistance of novel Fe-based amorphous alloys,” Mater. Design, 95, No. 5, 225–230 (2016).

    CAS  Google Scholar 

  3. L. Liu and C. Zhang, “Fe-based amorphous coatings: Structures and properties,” Thin Solid Films, 561, No. 30, 70–86 (2014).

    Article  CAS  Google Scholar 

  4. G. Huang, L. Qu, Y. Lu, Y. Wang, H. Li, Z. Qin, and X. Lu, “Corrosion resistance improvement of 45 steel by Fe-based amorphous coating,” Vacuum, 153, 39–42 (2018).

    Article  CAS  Google Scholar 

  5. M. M. Lopachak, K. I. Khrushchyk, V. V. Dnistryan, L. M. Boichyshyn, and O. V. Reshetnyak, “Corrosion resistance of Co77Si11B12 amorphous metal alloys for the electrodes of hydrogen release from alkaline solutions,” Mater. Sci., 56, No. 5, 673–677 (2021).

    Article  CAS  Google Scholar 

  6. M.-O. M. Danyliak and L. M. Boichyshyn, “Corrosion resistance of amorphous alloys Fe82Nb2B14REM2 (REM = Y, Gd, Tb, Dy) in NaCl medium,” Metallofiz. Noveish. Tekhnol., 42, 977–987 (2020).

    Article  CAS  Google Scholar 

  7. C. A. C. Souza, D. V. Ribeiro, and C. S. Kiminami, “Corrosion resistance of Fe–Cr-based amorphous alloys: An overview,” J. Non-Crystal. Solids, 442, 56–66 (2016).

    Article  CAS  Google Scholar 

  8. X. Li, X. Zhao, F. Lv, F. Liu, and Y. Wang, “Improved corrosion resistance of new Fe-based amorphous alloys,” Int. J. Mod. Phys. B, 31, 1744010 (2017).

    Article  CAS  Google Scholar 

  9. L. M. Boichyshyn, O. M. Hertsyk, M. M. Lopachak, M. O. Kovbuz, T. G. Hula, and N. L. Pandyak, “Electrochemical properties of ternary amorphous alloys based on iron and cobalt in alkali solutions,” Mater. Sci., 55, No. 5, 703–709 (2020).

    Article  CAS  Google Scholar 

  10. O. M. Hertsyk, M. O. Kovbuz, T. H. Hula, S. A. Korniy, O. A. Yezerska, and N. L. Pandiak, “Corrosion resistance of modified amorphous alloys based on iron in sulfuric acid,” Mater. Sci., 56, No. 6, 755–763 (2021).

    Article  CAS  Google Scholar 

  11. G. S. Mogilny, B. D. Shanina, V. V. Maslov, V. K. Nosenko, A. D. Shevchenko, and V. G. Gavriljuk, “Structure and magnetic anisotropy of rapidly quenched FeSiB ribbons,” J. Non-Cryst. Solids, 357, 3237–3244 (2011).

    Article  CAS  Google Scholar 

  12. L. M. Boichyshyn and O. M. Hertsyk, Amorphous Metal Alloys: Structure, Properties, and Methods of Investigations: A Tutorial [in Ukrainian], I. Franko National University of Lviv, Lviv (2016).

    Google Scholar 

  13. M. O. Vasylyev, V. K. Nosenko, V. M. Shyvaniuk, H. H. Halstian, and I. V. Zagorulko, “Magnetomechanical effects in amorphous ribbons,” Metallofiz. Noveish. Tekhnol., 42, No. 7, 949–962 (2020).

    Article  CAS  Google Scholar 

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Correspondence to O. M. Hertsyk.

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Translated from Fizyko-Khimichna Mekhanika Materialiv Vol. 58No. 3 Pp. 20–25 May–June 2022

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Hertsyk, O.M., Kovbuz, M.O., Hula, T.H. et al. Electrochemical Characteristics of the Fe78.5Ni1.0Mo0.5Si14.0B6.0 Amorphous Alloy in Corrosive Media of Different Nature. Mater Sci 58, 298–304 (2022). https://doi.org/10.1007/s11003-023-00663-9

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  • DOI: https://doi.org/10.1007/s11003-023-00663-9

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