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Synthesis of Some Octahedral Nickel(II) Complexes of One Isomer of Isomeric Me8[14]anes: X-ray Structure of Diisothiocyanato(3,10-C-meso-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane, LC)nickel(II), [NiLC(NCS)2]

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Abstract

One isomer, LC of the isomeric Me8[14]anes, LA, LB and LC; on reaction with Ni(NCS)2 produces a six coordinate octahedral diisothiocyanato complex, [NiLC(NCS)2]. This complex undergoes axial substitution reactions with the small ligands to yield corresponding monosubstituted derivatives having general formula [NiLC(NCS)X] whereas X = Cl, Br, I, NO2 or NO3. The complexes have been characterized on the basis of analytical, spectroscopic, magnetic and conductance data. The structure of [NiLC(NCS)2] (triclinic, space group P−1, α = 8.0421(17) Å, β = 8.9085(18) Å, χ = 9.687(2) Å, α = 67.561(3) Å, β = 82,896(4) Å, ζ = 598.7(2) Å3, Z = 2, Dc = 1.352 mg/m3, μ(Mo Kα) = 1.003 mm−1) was confirmed by X-ray crystallography.

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Acknowledgement

TGR is thankful to KOSEF for providing a post-doctoral fellowship. Also Kims and Park wish to acknowledge the support of Korea Research Foundation Grant (KRF-2004-005-C0009).

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Authors and Affiliations

  1. Department of Chemistry, University of Chittagong, Chittagong, 4331, Bangladesh

    Tapashi G. Roy, Saroj K. S. Hazari, Benu K. Dey & Ashish Nath

  2. Department of Chemistry, Kyungpook National University, Daegu, 702-701, Korea

    D. I. Kim, E. H. Kim & Y. C. Park

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  1. Tapashi G. Roy
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  2. Saroj K. S. Hazari
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  3. Benu K. Dey
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  6. E. H. Kim
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  7. Y. C. Park
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Correspondence to Y. C. Park.

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Roy, T., Hazari, S.S., Dey, B. et al. Synthesis of Some Octahedral Nickel(II) Complexes of One Isomer of Isomeric Me8[14]anes: X-ray Structure of Diisothiocyanato(3,10-C-meso-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane, LC)nickel(II), [NiLC(NCS)2]. J Incl Phenom Macrocycl Chem 58, 249–255 (2007). https://doi.org/10.1007/s10847-006-9150-x

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