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Ferroelectric and piezoelectric properties of Mn-modified BiFeO3-BaTiO3 ceramics

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Abstract

Mn-modified 0.67BiFeO3-0.33BaTiO3 (BF-BT) bulk ceramics were prepared via a solid-state reaction process using quenching method. The X-ray diffraction peaks shifted toward higher angles as increasing Mn content. Ferroelectric properties were improved by a small amount of Mn content. Leakage current density of 1 mol% Mn-modified ceramic showed the lowest leakage current density, 9.74 × 10−7 A/cm2 at 30 kV/cm. The value of small- and large-field piezoelectric coefficients (d 33 and d 33 *) were 135 pC/N and 250 pm/V, respectively, in 1 mol% Mn-modified BF-BT ceramic. A small amount of Mn content was effective to improve electrical properties and sintering behavior in Mn-modified BF-BT system.

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Acknowledgments

This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIP) (No. 2011–0030058, 2012–0007403) and by the Priority Research Centers Program through the National Research Foundation of Korea (NRF) funded by the MEST (2013R1A1A4A01010612, 2012–045424) and Following are results of a study on the “Leaders Industry-university Cooperation” Project, supported by the Ministry of Education (MOE) (No. 2013-E-7232-010109).

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Authors and Affiliations

  1. School of Advanced Materials Science and Engineering, Changwon National University, Changwon, Gyeongnam, 641-773, Korea

    D. J. Kim, M. H. Lee, J. S. Park, M.-H. Kim & T. K. Song

  2. Department of Physics, Changwon National University, Changwon, Gyeongnam, 641-773, Korea

    S. W. Kim, W.-J. Kim, K. W. Jang & S. S. Kim

  3. Department of Advanced Materials Engineering, Keimyung University, Daegu, 704-701, Korea

    D. Do

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  1. D. J. Kim
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Correspondence to T. K. Song.

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Kim, D.J., Lee, M.H., Park, J.S. et al. Ferroelectric and piezoelectric properties of Mn-modified BiFeO3-BaTiO3 ceramics. J Electroceram 33, 37–41 (2014). https://doi.org/10.1007/s10832-014-9912-6

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  • DOI: https://doi.org/10.1007/s10832-014-9912-6

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