Abstract
Mn modified BiFeO3–BaTiO3 (abbreviated as BFBT-Mnx%, x = 0.1, 0.3, 0.6, 0.9, 1.2) high-temperature lead-free ceramics were prepared by conventional oxide-mixed method and the effect of Mn doping on microstructure and electrical properties was investigated. The solid solutions show a single phase perovskite structure, and the content of Mn has a significant effect on the microstructure of ceramics. The addition of Mn can induce combinatory “hard” and “soft” piezoelectric characteristics due to aliovalent substitutions. In particular, x = 0.6 BFBT-Mnx% ceramic, with a Curie temperature, T c, of ~463 °C, shows optimum piezoelectric properties of d 33 = 131pC/N, k p = 0.298. The simultaneous existence of good piezoelectric properties and high T c makes these ceramics suitable for elevated temperature piezoelectric devices.
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References
Y. Chen, J. Zhu, D. Xiao, B. Qin, Y. Jiang, Mater. Lett. 62, 3567 (2008)
F. Gao, R. Hong, J. Liu, Z. Li, L. Cheng, C. Tian, J. Alloy. Compd. 475, 619 (2009)
F. Gao, R. Hong, J. Liu, J. Eur. Ceram. Soc. 29, 1687 (2009)
S. Chen, X.L. Dong, C.L. Mao, F. Cao, J. Am. Ceram. Soc. 89, 3270 (2006)
Ferroperm full catalogue. http://www.ferroperm-piezo.com
C.J. Stringer, T.R. Shrout, C.A. Randall, I.M. Reaney, J. Appl. Phys. 99, 024106 (2006)
R.E. Eitel, C.A. Randall, T.R. Shrout, S.E. Park, Jpn. J. Appl. Phys. 41, 2099 (2002)
S. Bhattacharjee, S. Tripathi, D. Pandey, Appl. Phys. Lett. 91, 042903 (2007)
J. Chen, H. Shi, G. Liu, J. Cheng, S. Dong, J. Alloy. Compd. 537, 280 (2012)
T. Sebastian, I. Sterianou, I.M. Reaney, T. Leist, W. Jo, J. Rödel, J. Electroceram. 28, 95 (2012)
I. Fujii, K. Nakashima, N. Kumada, S. Wada, J. Ceram. Soc. Jpn. 120, 30 (2012)
S.O. Leontsev, R.E. Eitel, J. Am. Ceram. Soc. 92, 2957 (2009)
S.O. Leontsev, R.E. Eitel, J. Mater. Res. 26, 9 (2011)
C. Zhou, A. Feteira, X. Shan, H. Yang, Q. Zhou, G. Chen, Appl. Phys. Lett. 101, 032901 (2012)
Z. Yao, H. Liu, M. Cao, H. Hao, Z. Yu, Mater. Res. Bull. 46, 1257 (2011)
S.J. Zhang, R.E. Eitel, C.A. Randall, T.R. Shrout, E.F. Alberta, Appl. Phys. Lett. 86, 262904 (2005)
A.P. Barranco, F.C. Pinar, P. Martinez, E.T. Garcia, J. Eur. Ceram. Soc. 21, 523 (2001)
D. Szwagierczak, J. Kulawik, J. Eur. Ceram. Soc. 25, 1657 (2005)
H. Yang, C. Zhou, X. Liu, Q. Zhou, G. Chen, H. Wang, Mater. Res. Bull. 47, 4233 (2012)
H.Y. Park, C.H. Nam, I.T. Seo, J.H. Choi, S. Nahm, H.G. Lee, K.J. Kim, S.M. Jeong, J. Am. Ceram. Soc. 93, 2537 (2010)
Y. Yan, K.H. Cho, S. Priya, J. Am. Ceram. Soc. 94, 3953 (2011)
Y. Yan, A. Kumar, M. Correa, K.H. Cho, R. S. Katiyar, S. Priya. Appl. Phys. Lett. 100, 152902 (2012)
C.A. Randall, N. Kim, J.P. Kucera, W. Cao, T.R. Shrout, J. Am. Ceram. Soc. 81, 677 (1998)
Q.M. Zhang, H. Wang, N. Kim, L.E. Cross, J. Appl. Phys. 75, 454 (1994)
B. Jaffe, W.R. Cook, H (Academic Press, London, Jaffe, 1971)
Y.J. Lee, J.S. Kim, S.H. Han, H.W. Kang, H.G. Lee, C. II. Cheon. J. Korean Phys. Soc. 61, 947 (2012)
I. Fujii, R. Mitsui, K. Nakashima, N. Kumada, M. Shimada, T. Watanabe, J. Hayashi, H. Yabuta, M. Kubota, T. Fukui, S. Wada, Jpn. J. Appl. Phys. 50, 09ND07 (2011)
S. Wada, K. Yamato, P. Pulpan, N. Kumada, B.Y. Lee, T. Iijima, C. Moriyoshi, Y. Kuroiwa, J. Appl. Phys. 108, 094114 (2010)
C.C. Huang, D.P. Cann, J. Appl. Phys. 104, 024117 (2008)
Acknowledgments
This work was supported by the National Nature Science Foundation of China (61261012) Guangxi Nature Science Foundation (2010GXNSFD013007 and 2010GXNSFB013010) and Guangxi Education Department Foundation (201012MS083) and Guangxi Key Laboratory of Information Materials (1110908-09-Z).
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Cen, Z., Zhou, C., Yang, H. et al. Structural, ferroelectric and piezoelectric properties of Mn-modified BiFeO3–BaTiO3 high-temperature ceramics. J Mater Sci: Mater Electron 24, 3952–3957 (2013). https://doi.org/10.1007/s10854-013-1346-4
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DOI: https://doi.org/10.1007/s10854-013-1346-4