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Electrochemical properties of nanostructured Li[Fe0.9Mn0.1]PO4/C as a cathode material for lithium ion batteries prepared by electrospinning method

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Abstract

In this paper, Li[Fe0.9Mn0.1]PO4/C nanofibers were successfully synthesized from a sol-gel precursor by electrospinning and used as a cathode material for lithium ion batteries. The synthesized nanofibers were smooth, and distributed uniformly, and when produced at 750 °C for 10 h in a nitrogen atmosphere had an average diameter of 100 ~ 300 nm. The crystal structures were studied by X-ray diffraction (XRD) and no obvious impurity-related peaks were observed. The electrochemical properties were examined using initial charge-discharge curve, cycle performance, EIS, etc. The initial discharge capacity reached about 124mAh/g. In addition, the impedance was lower than LiFePO4.

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Acknowledgments

The research was financially supported by the Korean Ministry of Education, and Science Technology (MEST), the National Research Foundation of Korea (NRF) through the Human Resource Training Project for Regional Innovation in 2012 (Grant no. 2011-0005529) and the Basic Science Research Program through the National Research Foundation of Korea (Grant no. 2012-0003715).

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Authors and Affiliations

  1. Department of Nano-Polymer Science & Engineering, Korea National University of Transportation, Chungju, Chungbuk, 380-702, Republic of Korea

    Cheong Kim, Seo Ha Kang, Hyo Jin Jeon & Jong Tae Son

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  1. Cheong Kim
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  2. Seo Ha Kang
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  3. Hyo Jin Jeon
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  4. Jong Tae Son
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Correspondence to Jong Tae Son.

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Kim, C., Kang, S.H., Jeon, H.J. et al. Electrochemical properties of nanostructured Li[Fe0.9Mn0.1]PO4/C as a cathode material for lithium ion batteries prepared by electrospinning method. J Electroceram 31, 204–209 (2013). https://doi.org/10.1007/s10832-013-9814-z

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  • DOI: https://doi.org/10.1007/s10832-013-9814-z

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