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Nd(III)-PVC Membrane Sensor Based on 2-{[(6-aminopyridin-2-yl)imino]methyl}-phenol

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Abstract

We report the development of a novel Nd(III) ion-selective PVC-based membrane sensor, based on 2-{[(6-aminopyridin-2-yl)imino]methyl}phenol (APIMP) as the membrane carrier. The sensor has a Nernstian slope of 19.6±0.3 mV per decade over the concentration range of 1.0× 10−5−1.0×10−2 M, and a detection limit of 2.0× 10−6 M of Nd(III) ions. The potentiometric response of the sensor is independent pH solution in the pH range 3.5–8.5. It has advantages of low resistance, very fast response time (<10 s) and, most importantly, good selectivity with respect to a number of lanthanide ions. Using the proposed membrane sensor in a 6 weeks period caused no significant divergences in its potential response. To assess its analytical applicability the sensor was successfully applied as an indicator electrode in the titration of Nd(III) ion solution with EDTA.

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References

  1. O.R. Kirk and F.D. Othmer (1982) Encyclopedia of Chemical Technology. Vol. 19. Wiley, New York, p. 851.

    Google Scholar 

  2. P. Buhlmann, E. Pretsch and E. Bakker, Chem Rev 98 (1998) 1593.

    Article  Google Scholar 

  3. M.R. Ganjali, A. Daftari, M. Qomi and P. Norouzi, Sens. Actuators. B 98 (2004) 92.

    Article  CAS  Google Scholar 

  4. M.R. Ganjali, A. Daftari and M. Rezapour, Talanta 59 (2003) 613.

    Article  CAS  Google Scholar 

  5. M.M. Hassanien, K.S. Abou-El-Sherbini and G.A.E. Mostafa, Talanta 59 (2003) 383.

    Article  CAS  Google Scholar 

  6. T. Itot, C. Goto and K. Noguchi, Anal. Chim. Acta 443 (2001) 41.

    Article  Google Scholar 

  7. K. Susheel, S.K. Mittal, A. Kumar and H.K. Sharma, Talanta 62 (2004) 801.

    Article  CAS  Google Scholar 

  8. M.R. Ganjali, R. Kiani, M. Shamsipur, T. Poursaberi, M. Salavati-Niasari, Z. Talebpour and M. Emami, Electroanalysis 16 (2004) 1002.

    Article  CAS  Google Scholar 

  9. V.K. Gupta, S. Jain and S. Chandra, Anal. Chim. Acta 486 (2003) 199.

    Article  CAS  Google Scholar 

  10. M. Shamsipur, V. Yousefi and M.R. Ganjali, Anal. Chem. 72 (2000) 2391.

    Article  CAS  Google Scholar 

  11. H. Karami, M.F. Mousavi, M. Shamsipur, I. Yavari and A.A. Alizadeh, Anal. Lett. 36 (2003) 1065

    Article  CAS  Google Scholar 

  12. M.R. Ganjali, M.R. Pourjavid, M. Rezapour and V. Haghgoo, Sens Actuators B 89 (2003) 21.

    Article  Google Scholar 

  13. M.R. Ganjali, M. Rezapour, M.R. Pourjavid and S. Haghgoo, Anal. Sci. 20 (2004) 1007.

    Article  CAS  Google Scholar 

  14. S.K. Mittal, H.K. Sharma and A.S.K. Kumar, Sensors 4 (2004) 125.

    Article  CAS  Google Scholar 

  15. M.R. Ganjali, M. Rahimi, B. Maddah, A. Moghimi and S. Borhani, Anal. Sci. 20 (2004) 1427.

    Article  CAS  Google Scholar 

  16. M.R. Ganjali, M. Tahami, M. Shamsipur, T. Poursaberi, S. Haghgoo and M. Hosseini, Electroanalysis 15 (2003) 1038.

    Article  CAS  Google Scholar 

  17. M.R. Ganjali, M. Salavati-Niasari, M. Emami, M. Javanbakht, M. Shamsipur and M. yousefi, Sens. Actuators B 105 (2005) 127.

    Article  CAS  Google Scholar 

  18. M.R. Ganjali, J. Ravanshad, M. Hosseini, M. Salavati-Niasari, M.R. Pourjavid and M.R. Baezzat, Electroanalysis 16 (2004) 1771.

    Article  CAS  Google Scholar 

  19. M.R. Ganjali, L. Naji, T. Poursaberi, M. Shamsipur and S. Haghgoo, Anal. Chim. Acta 475 (2003) 59

    Article  CAS  Google Scholar 

  20. M. Shamsipur, M. Hosseini, M.F. Mousavi, A. Garau, V. Lippolis and A. Yari, Anal. Chem. 77 (2005) 276.

    Article  CAS  Google Scholar 

  21. M.R. Ganjali, M.H. Zargazi and A. Mohajeri, Polish J. Chem. 75 (2001) 743.

    CAS  Google Scholar 

  22. D. Ammann, E. Pretsch, W. Simon, E. Lindner, A. Bezegh and E. Pungor, Anal. Chim. Acta 171 (1985) 119.

    Article  CAS  Google Scholar 

  23. T. Rosatzin, E. Bekker, K. Suzuki and W. Simon, Anal. Chim. Acta 280 (1993) 197.

    Article  CAS  Google Scholar 

  24. U. Schaller, E. Bakker, U.E. Spichiger and E. Pretsch, Anal. Chem. 66 (1994) 391.

    Article  CAS  Google Scholar 

  25. P. Gehrig, V. Morf, W.E. Welti, E. Pretsch and W. Simon, Helv. Chim. Acta 73 (1990) 203.

    Article  CAS  Google Scholar 

  26. R. Eugster, U.E. Spichiger and W. Simon, Anal. Chem. 65 (1993) 689.

    Article  CAS  Google Scholar 

  27. G.G. Guilbault, R.A. Durst, M.S. Frant, H. Freiser, E.H. Hansen, T.S. Light, E. Pungor, G. Rechnitz, N.M. Rice, T.J. Rohm, W. Simon and J.D.R. Thomas, Pure Appl. Chem. 46 (1976) 127.

    Article  Google Scholar 

  28. Y. Umezawa, K. Umezawa and H. Sato, Pure Appl. Chem. 67 (1995) 507.

    Article  Google Scholar 

  29. P.R. Buck and E. Lindneri, Pure Appl. Chem. 66 (1994) 2527.

    Article  CAS  Google Scholar 

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Acknowledgement

The authors express their appreciation to the University of Tehran Research Council for financial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, University of Tehran, Tehran, Iran

    M.R. Ganjali, P. Norouzi & M. Adib

  2. Faculty of Chemistry, Tarbiat Moallem University, Tehran, Iran

    A. Ahmadalinezhad

Authors
  1. M.R. Ganjali
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  2. A. Ahmadalinezhad
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  3. P. Norouzi
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  4. M. Adib
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Correspondence to M.R. Ganjali.

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Ganjali, M., Ahmadalinezhad, A., Norouzi, P. et al. Nd(III)-PVC Membrane Sensor Based on 2-{[(6-aminopyridin-2-yl)imino]methyl}-phenol. J Appl Electrochem 36, 931–936 (2006). https://doi.org/10.1007/s10800-006-9154-7

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  • DOI: https://doi.org/10.1007/s10800-006-9154-7

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