Abstract
The structural analysis of strontium hexaferrites SrFe x O19 (for x = 12, 11 and 10) and substituted samples Sr0.7Nd0.3Fe12 − y Co0.3O19 (for y = 0.3,1.3 and 2.3) prepared through the citrate precursor method is shown. Nd and Co substitution modifies saturation magnetization (M S ) and increases coercivity (H c ) in samples heat-treated at 1100°C for two hours. Mössbauer analyses show different iron occupancy and the influence of the Fe3 + content is particularly emphasized. Hematite segregation is observed for some compositions. Samples with low Fe3 + content show the best magnetic properties with no secondary phase segregation.
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Herme, C., Jacobo, S.E., Bercoff, P.G. et al. Mössbauer analysis of Nd-Co M-type strontium hexaferrite powders with different iron content. Hyperfine Interact 195, 205–212 (2010). https://doi.org/10.1007/s10751-009-0121-7
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DOI: https://doi.org/10.1007/s10751-009-0121-7