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Precipitation Chemistry and Occurrence of Acid Rain Over Dhanbad, Coal City of India

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Abstract

The present study investigated the chemical composition of wet atmospheric precipitation over Dhanbad, coal city of India. The precipitation samples were collected on event basis for three years (July 2003 to October 2005) at Central Mining Research Institute. The precipitation samples were analyzed for pH, conductivity, major anions (F, Cl, NO3, SO4) and cations (Ca, Mg, Na, K, NH4). The pH value varied from 4.01 to 6.92 (avg. 5.37) indicating acidic to alkaline nature of rainwater. The pH of the rainwater was found well above the reference pH (5.6), showing alkalinity during the non-monsoon and early phase of monsoon, but during the late phase of monsoon, pH tendency was towards acidity (<5.6~pH) indicating the non-availability of proper neutralizer for acidic ions. The observed acidic events at this site were 91, (n = 162) accounting 56% for the entire monitoring months. The (NO3 + Cl)/SO4 ratio in majority of samples was found below 1.0, indicating that the acidity is greatly influenced by SO4. The calculated ratio of (Ca + NH4)/(NO3 + SO4) ranges between 0.42–5.13 (average 1.14), however in most of the samples, the ratio is greater than unity (>1.0) indicating that Ca and NH4 play an important role in neutralization of acidic ions in rainwater. Ca and SO4 dominate the bulk ionic deposition and these two ions along with NH4 accounts 63% of the annual ionic deposition.

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References

  • Ayers, G.P., Peng, L.C., Gillette, R.W., & Fook, L.S. (2002). Rainwater composition and acidity at five sites in Malaysia in 1996. Water, Air, and Soil Pollution, 133, 15–30.

    Article  CAS  Google Scholar 

  • Balachandran, S., & Khilare, P.S. (2001). Occurrence of Acid rain over Delhi. Environmental Monitoring and Assessment, 71, 165–176.

    Article  CAS  Google Scholar 

  • BCCL (2003). Brief history of Bharat Coking Coal Limited, Coal India Limited, Koyala Bhavan, Dhanbad. pp. 1–3. http//www.bccl.nic.in

    Google Scholar 

  • Charlson, R.J., & Rodhe, H. (1982). Factors controlling the acidity of natural rainwater. Nature, 295, 667–673.

    Article  Google Scholar 

  • Chndravanshi, C.K., Patel, V.K., & Patel, K.S. (1997). Acid rain in Korba city of India. Indian Journal of Environment Protection, 17, 658–661.

    Google Scholar 

  • CMRI (1999). Carrying capacity of Damodar River Basin. Project report submitted to Ministry of Environment & Forest (Gov. of India) by Central Mining Research Institute.

  • Das, R., Das, S.N., & Misra, V.N. (2005). Chemical composition of rainwater and dustfall at Bhubaneshawar in the east coast of India. Atmospheric Environment (in press).

  • Ducc, R.A., Liss, P.S., Merrill, J.T., Atlas, E.I., Buat-Menard, P., Hicks, B.B., Miller, J.M., Tsunogai, S., Wollast, R., & Zhou, M. (1991). The atmospheric input of trace species to the world ocean. Global Biogeochemical Cycles, 5, 242–244.

    Google Scholar 

  • Finlayson-Pitts, B.J., & Pitts, Jr J.N. (1986). Atmospheric Chemistry Fundamentals and Experimental Techniques. New York: John Wiley.

    Google Scholar 

  • Fujita, S., Takahashi, A., Weng, J.H., Huang, L.F., Kim, H.K., Li, C.K., Huang, F.T., & Jeng, F.T. (2000). Precipitation chemistry in East Asia. Atmospheric Environment, 34, 525–537.

    Article  CAS  Google Scholar 

  • Gupta, R.P., & Prakash, A. (1998). Reflectance aureoles associated with thermal anomalies due to subsurface minefire in the Jharia coalfield, India. International Journal of Remote Sensing, 19, 2619–2622.

    Article  Google Scholar 

  • Hooper, R.P., & Peters, N.E. (1989). Use of multivariate analysis for determining sources of solutes found in wet atmospheric deposition in the United States. Environment Science & Technology, 23, 1263–1268.

    Article  CAS  Google Scholar 

  • Jain, M.K., & Saxena, N.C. (2002). Air quality assessment along Dhanbad–Jharia Road. Environmental Monitoring and Assessment, 79, 239–250.

    Article  CAS  Google Scholar 

  • Johnson, T.M., Liu, F., & Newfarmer, R. (1997). Clear water, blue skies: Chinas environment in the new centaury. Washington, D.C: World Bank.

    Book  Google Scholar 

  • Khare, P., Goel, A., Patel, D., & Behari, J. (2004). Chemical characterization of rainwater at a developing urban habitat of Northern India. Atmospheric Environment, 69, 135–145.

    CAS  Google Scholar 

  • Khemani, L.T., Momin, G.A., Naik M.S., Rao, P.S.P., Kumar, R., & Ramamurthy, Bh.V. (1985). Impact of alkaline particulates on pH of rain water in India. Water, Air, and Soil Pollution, 24, 365–376.

    Article  Google Scholar 

  • Khemani, L.T., Momin, G.A., Rao, P.S.P., Pillai, A.G., Safai, P.D., Mohan, K., & Rao, M.G. (1994). Atmospheric pollutants and their influence on acidification of rain water at an industrial location on the west coast of India. Atmospheric Environment, 28, 3145–3154.

    Article  CAS  Google Scholar 

  • Khemani, L.T., Momin, G.A., Rao, P.S.P., Safai, P.D., Singh, G., & Kapoor, R.K. (1989). Spread of acid rain in India. Atmospheric Environment, 23, 757–762.

    Article  Google Scholar 

  • Kulshrestha, U.C., Saxena, A., Kumar, N., Kumari, K.M., & Srivastava, S.S. (1995). Wet and bulk deposition study at New Delhi (India). Water Air, and Soil Pollution, 85, 2137–2142.

    Article  CAS  Google Scholar 

  • Kulshrestha, U.C., Kulshrestha, M.J., Sekhar, R., Sastry, G.S.R., & Vairamani, M. (2003). Chemical characteristics of rainwater at an urban site of south-central India. Atmospheric Environment, 37, 3019–3026.

    Article  CAS  Google Scholar 

  • Kumar, R., Rani, A., Singh, S.P., Kumari, K.M., & Srivastava, S.S. (2002). A long term study on chemical composition of rainwater at Dayalbagh, a suburban site of semi arid region, Journal of Atmospheric Chemistry, 41, 265–279.

    Article  CAS  Google Scholar 

  • Mahadevan, T.N., Meenakshy, V., & Sathe, A.V. (1984). Some observations on chemical composition of precipitation in an industrial area and its use in air quality assessment. Mausam, 35, 87–91.

    Google Scholar 

  • Mahadevan, T.N., Negi, B.S., & Meenakshy, V. (1989). Measurement of elemental composition of aerosol matter and precipitation from a remote background site in India. Atmospheric Environment, 23, 869–874.

    Article  Google Scholar 

  • Mukhopadhyay, B., Datar, S.V., & Srivastava, H.N. (1992). Precipitation chemistry over the Indian region. Mausam, 43, 249–258.

    Google Scholar 

  • Naik, M.S., Khemani, L.T., Momin, C.A., & Prakash, Rao, P.S. (1988). Measurement of pH and chemical analysis of rain water in rural area in India. Acta Mathematicae Applicatae Sinica, 2, 91–100.

    Google Scholar 

  • Naik, M.S., Momin, G.A., Rao, P.S.P., Safai, P.D., & Ali, K. (2002). Chemical composition of rainwater around an industrial region in Mumbai. Current Science, 82, 1134–1137.

    Google Scholar 

  • Parashar, D.C., Kulshrestha, U.C., & Jain, M. (2001). Precipitation chemistry and aerosols studies in India. Environmental Monitoring and Assessment, 66, 47–61.

    Article  CAS  Google Scholar 

  • Pillai, A.G., Naik, M.S., Momin, G.A., Rao, P.S.P., Safai, P.D., Ali, K., Rodhe, H., & Granat, L. (2001). Studies of wet deposition and dustfall at Pune, India. Water Air, and Soil Pollution, 130, 475–480.

    Article  Google Scholar 

  • Primerano, P., Di Pasquate, S., Mavilia, L., & Corigliano, F. (1998). Sources of strong acidity in the atmosphere. Atmospheric Environment, 32, 225–230.

    Article  CAS  Google Scholar 

  • Ranor, G.S., & Hayes, J.V. (1982). Effects of varying wind trajectories on spatial and temporal precipitation chemistry patterns. Water, Air, and Soil Pollution, 15, 229–245.

    Article  Google Scholar 

  • Rao, P.S.P., Khemani, L.T., Momin, G.A., Safai, P.D., & Pillai, A.G. (1992). Measurement of wet and dry deposition at an urban location in India. Atmospheric Environment, 26, 73–77.

    Google Scholar 

  • Rao, P.S.P., Momin, G.A., Safai, P.D., Pillai, A.G., & Khemani, L.T. (1995). Rainwater and throughfall chemistry in silent valley forest in south India. Atmospheric Environment, 29, 2025–2029.

    Article  CAS  Google Scholar 

  • Rastogi, N., & Sarin, M.M. (2005). Chemical characteristics if individual rain events from a semi-arid region in India: Three–year study. Atmospheric Environment, 39, 3313–3323.

    Article  CAS  Google Scholar 

  • Ravichandran and Padmanabhamurty, B. (1994). Acid precipitation in Delhi. Atmospheric Environment, 28, 2291– 2297.

    Article  CAS  Google Scholar 

  • Samara, C., Tsitouridou and Balafoutis, Ch. (1992). Chemical composition of rain in Thessaloniki, Greece, in relation to meteorological conditions, Atmospheric Environment, 26, 359–367.

    Google Scholar 

  • Satsangi, G.S., Lakhani, A., Khare, P., Singh, S.P., Kumari, K.M., & Srivastava S.S. (1998). Composition of rainwater at a semiarid rural site in India. Atmospheric Environment, 32, 3783–3793.

    Article  CAS  Google Scholar 

  • Saxena, A., Kulshrestha, U.C., Kumar, N., Kumari K.M., & Srivastava, S.S. (1996). Characterisation of precipitation at Agra. Atmospheric Environment, 30, 3405–3412.

    Article  CAS  Google Scholar 

  • Saxena, A., Sharma S., Kulshrestha, U.C., & Srivastava, S.S. (1991). Factors affecting alkaline nature of rain water in Agra (India). Environmental Pollution, 74, 129–138.

    Article  CAS  Google Scholar 

  • Seinfeld, J.H., & Pandis, S.N. (1998). Atmospheric chemistry and physics from air pollution to climate change. Atmospheric Chemistry and Physics. New York: John Wiley.

    Google Scholar 

  • Sequaira, R. (1976). Monsoon deposition of sea salts and air pollutants over Bombay. Tellus, 28, 275–282.

    Article  Google Scholar 

  • Shivashankara, G.P., Ranga, K., Ramalingaiah, & Manoharanrao (1999). Characterisation of bulk precipitation in industrial areas of Bangalore city. Indian Journal of Environmental Health, 41, 229–238.

    CAS  Google Scholar 

  • Pachauri, R.K. (Ed.). Tata energy data directory and yearbook: 1997/98 (pp. 200–220). New Delhi: TERI.

    Google Scholar 

  • Tsuruta, H. (1989). Acid precipitation in Eastern Asia. Kagaku, 59, 305–315.

    CAS  Google Scholar 

  • Varma, P.C., Jha, C., Mian, S.B., & Gupta, V.S. (1994). Air quality studies in an industrial and urban township of Jharia coalfield, Dhanbad. Indian Journal of Environmental Protection, 14, 301–305.

    Google Scholar 

  • Weng, J.H. (1993). Study on acidic precipitation in Beijing. Water Quality Research, 88, 5343–5352.

    Google Scholar 

  • World Resource Institute (1999, 1988–1999). World Resources, A guide to the global environment, environmental change and human health. Oxford: University Press. http://www.wri.org.

    Google Scholar 

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Authors and Affiliations

  1. Environmental Management Group, Central Mining Research Institute, (Council of Scientific & Industrial Research), Dhanbad, 826001, India

    Abhay Kr. Singh, G. C. Mondal, Suresh Kumar & K. K. Singh

  2. Department of Chemistry, V.B. University, Hazaribag, 825 003, India

    K. P. Kamal & A. Sinha

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  1. Abhay Kr. Singh
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  2. G. C. Mondal
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  3. Suresh Kumar
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  4. K. K. Singh
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  5. K. P. Kamal
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Correspondence to Abhay Kr. Singh.

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Singh, A.K., Mondal, G.C., Kumar, S. et al. Precipitation Chemistry and Occurrence of Acid Rain Over Dhanbad, Coal City of India. Environ Monit Assess 125, 99–110 (2007). https://doi.org/10.1007/s10661-006-9243-4

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