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Photo-and thermochromic spiranes. 29. New photochromic indolinospiropyrans containing a quinoline fragment

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A new photochromic spiropyran of the indoline series, containing a quinoline fragment, has been synthesized. The photochromic properties of the spiropyran and its iodomethylate have been studied. Features of the molecular structure of the compounds were determined by X-ray structural investigations. It was established that the pyridopyran fragments of the cations in the crystal of the iodomethylate salt, unlike those in the crystal of the neutral spiropyran, emerge from 21-stacks, disposed jointly with I− ions, which causes their higher mobility and aids the course of reversible photoconversions on UV irradiation in solution.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432 Moscow region

    V. V. Tkachev, S. M. Aldoshin, N. A. Sanina & A. N. Utenyshev

  2. Institute of Physical and Organic Chemistry, Rostov State University, Rostov-on-Don, 344090, Russia

    B. S. Lukyanov, V. I. Minkin, K. N. Khalanskiy & Yu. S. Alekseenko

Authors
  1. V. V. Tkachev
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  2. S. M. Aldoshin
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  3. N. A. Sanina
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  4. B. S. Lukyanov
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  5. V. I. Minkin
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  6. A. N. Utenyshev
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  7. K. N. Khalanskiy
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  8. Yu. S. Alekseenko
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Additional information

For Part 28 see [1].

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 690–702, May, 2007.

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Tkachev, V.V., Aldoshin, S.M., Sanina, N.A. et al. Photo-and thermochromic spiranes. 29. New photochromic indolinospiropyrans containing a quinoline fragment. Chem Heterocycl Compd 43, 576–586 (2007). https://doi.org/10.1007/s10593-007-0092-z

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  • DOI: https://doi.org/10.1007/s10593-007-0092-z

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