Abstract
Agricultural paper mulch is an indispensable part of modern agriculture. It had the functions of heat preservation, moisture preservation, insect resistance, disease prevention, and weed growth inhibition. In order to extend the service life of the paper mulch, we use the solution immersion method to modify the surface of the paper mulch. A super-hydrophobic paper mulch is mainly prepared by using hydrophobic silica. The static contact angle of the super-hydrophobic paper mulch with water is 160.6°. The super-hydrophobic paper mulch samples were immersed in acid solution (pH = 4.6 H2SO4) and alkaline solution (pH = 8.5 NaOH). The main instruments are contact angle tester, tensile testing machine and high-speed camera. The hydrophobic properties, mechanical properties and rebound properties of the two kinds of paper mulches were compared. The results showed that the tensile strength and droplet bounce height of the superhydrophobic paper mulch decreased after being soaked in acid or alkaline solution for 48 h. The mass loss rate of paper mulch was more significant in acid solution, but its contact angle was still greater than 145°, and it had good bounce performance. After observing the microscopic morphology of its surface, it was found that silica had a micro-rough structure on the surface of the paper mulch. The method was simple and environmentally friendly, and can alleviate the problem of poor acid and alkali corrosion resistance of the paper mulch, and had extraordinary significance for environmental protection.
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References
Adamopoulos FG, Vouvoudi EC, Pavlidou E et al (2021) TEOS-based superhydrophobic coating for the protection of stone-built cultural heritage. Coatings 11(2):135. https://doi.org/10.3390/coatings11020135
Balu B, Breedveld V, Hess DW (2008) Fabrication of “roll-off” and “sticky” superhydrophobic cellulose surfaces via plasma processing. Langmuir 24(9):4785–4790. https://doi.org/10.1021/la703766c
Bongiovanni R, Marchi S, Zeno E et al (2013) Water resistance improvement of filterpaper by a UV-grafting modification with a fluoromonomer. Colloid Surf A 418:52–59. https://doi.org/10.1016/j.colsurfa.2012.11.003
Bower S, Wickramasinghe R, Nagle NJ et al (2008) Modeling sucrose hydrolysis in dilute sulfuric acid solutions at pretreatment conditions for lignocellulosic biomass. Bioresour Technol 99(15):7354–7362. https://doi.org/10.1016/j.biortech.2007.05.045
Chatzigrigoriou A, Manoudis PN, Karapanagiotis I (2013) Fabrication of water repellent coatings using waterborne resins for the protection of the cultural heritage. Macromol Symp 331–332(1):158–165. https://doi.org/10.1002/masy.201300063
Chen KJ, Marsh TL, Tozer PR et al (2019) Biotechnology to sustainability: consumer preferences for food products grown on biodegradable mulches. Food Res Int 116:200–210. https://doi.org/10.1016/j.foodres.2018.08.013
Dickinson M (2003) How to walk on water. Nature 424(6949):621–622. https://doi.org/10.1038/424621a
Ensikat HJ, Ditsche-Kuru P, Neinhuis C et al (2011) Superhydrophobicity in perfection: the outstanding properties of the lotus leaf. Beilstein J Nanotech 2:152–161. https://doi.org/10.3762/bjnano.2.19
Gao XF, Jiang L (2004) Water-repellent legs of water striders. Nature 432:36. https://doi.org/10.1038/432036a
Heinonen S, Huttunen-Saarivirta E, Nikkanen JP (2014) Antibacterial properties and chemical stability of superhydrophobic silver-containing surface produced by sol-gel route. Colloids Surf A 453:149–161. https://doi.org/10.1016/j.colsurfa.2014.04.037
Hejazi I, Seyfi J, Sadeghi GMM et al (2017) Investigating the interrelationship of superhydrophobicity with surface morphology, topography and chemical composition in spray-coated polyurethane/silica nanocomposites. Polymer 128:108–118. https://doi.org/10.1016/j.polymer.2017.09.020
Kalisz A, Siwek P, Sulak K (2018) Influence of spunbond degradable floating row covers on microclimate modification and yield of field cucumber. Span J Agric Res. https://doi.org/10.5424/sjar/2018162-11968
Karapanagiotis I, Grosu D, Aslanidou D et al (2015) Facile method to prepare superhydrophobic and water repellent cellulosic paper 2015. J Nanomater. https://doi.org/10.1155/2015/219013
Kasirajan S, Ngouajio N (2012) Polyethylene and biodegradable mulches for agricultural applications: a review. Agron Sustain Dev 32(2):501–529. https://doi.org/10.1007/s13593-011-0068-3
Kong L, Chen X, Yu L et al (2015) Superhydrophobic cuprous oxide nanostructures on phosphor-copper meshes and their oil-water separation and oil spill cleanup. ACS Appl Mater Inter. https://doi.org/10.1021/am507620s
Landuzzi A, Ghosh J (2003) Improving functionality of polyolefin films through the use of additives. J Plast Film Sheet 19(3):173–187. https://doi.org/10.1177/8756087903040175
Larkin RP (2020) Effects of selected soil amendments and mulch type on soil properties and productivity in organic vegetable production. Agronomy-Basel. https://doi.org/10.3390/agronomy10060795
Lee S, Kim B, Kim SH et al (2017) Superhydrophobic, reversibly elastic, moldable, and electrospun (SupREME) fibers with multimodal functions: from oil absorbents to local drug delivery adjuvants. Adv Funct Mater 27(37):1702310. https://doi.org/10.1002/adfm.201702310
Li QM, Liu H, Zhang SD et al (2019) Superhydrophobic electrically conductive paper for ultrasensitive strain sensor with excellent anticorrosion and self-cleaning property. ACS Appl Mater Inter 11(24):21904–21914. https://doi.org/10.1021/acsami.9b03421
Li Y, Chen S, Wu M et al (2014) All spraying processes for the fabrication of Robust, self-healing, superhydrophobic coatings. Adv Mater 26(20):3344. https://doi.org/10.1002/adma.201306136
Lin F, Zhang YN, Xi JM et al (2008) Petal effect: a superhydrophobic state with high adhesive force. Langmuir 24:4114–4119. https://doi.org/10.1021/la703821h
Song Y, Wang L, Wang X (2014) Preparation of a new superhydrophobic nanofiber film by electrospinning polystyrene mixed with ester modified silicone oil. J Appl Polym Sci 131(17):40718–40726. https://doi.org/10.1002/app.40718
Teng YH, Shi BY, Zhang JW et al (2020) Preparation of robust superhydrophobic paper by roll coating with modified micro/nano SiO2. Adv Publ. https://doi.org/10.1246/cl.200381
Wang GF, Zhou J, Wang MM et al (2020) A superhydrophobic surface with aging resistance, excellent mechanical restorablity and droplet bounce properties. Soft Matter 16(23):5514–5524. https://doi.org/10.1039/D0SM00462F
Xiang H, Zhang L, Wang Z et al (2011) Multifunctional polymethylsilsesquioxane (PMSQ) surfaces prepared by electrospinning at the sol-gel transition: superhyreophobicity, excellent solvent resistance, thermal stability and enhanced sound absorption property. J Colloid Interf Sci 359(1):296–303. https://doi.org/10.1016/j.jcis.2011.03.076
Yang CJ, Wang M, Yang Z et al (2019) Investigation of effects of acid, alkali, and salt solutions on fluorinated superhydrophobic surfaces. Langmuir 35(52):17027–17036. https://doi.org/10.1021/acs.langmuir.9b03469
Yang Y, Li PW, Jiao J et al (2020) Renewable sourced biodegradable mulches and their environment impact. Sci Hortic. https://doi.org/10.1016/j.scienta.2020.109375
Zhang CH, Li C, Si XQ et al (2020a) Mechanical durable ceria superhydrophobic coating fabricated by simple hot-press sintering. Appl Surf Sci. https://doi.org/10.1016/j.apsusc.2020.147113
Zhang H, DeVetter LW, Scheenstra E et al (2020b) Weed pressure, yield, and adhesion of soil-biodegradable mulches with pie pumpkin (Cucurbita pepo). HortScience 55(7):1014–1021. https://doi.org/10.21273/HORTSCI15017-20
Zhao H, Kwak JH, Zhang ZC et al (2007) Studying cellulose fiber structure by SEM, XRD NMR and acid hydrolysis. Carbohyd Polym 68(2):235–241. https://doi.org/10.1016/j.carbpol.2006.12.013
Zhou XY, Wang GF, Wang MM et al (2020) A simple preparation method for superhydrophobic surface on silicon rubber and its properties. Prog Org Coat. https://doi.org/10.1016/j.porgcoat.2020.105612
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This research project was supported by Special fund project for modern agricultural industrial technology system (CARS-14–1-28).
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Zhang, F., Li, A. & Zhao, W. Analysis of the acid and alkali resistance of superhydrophobic paper mulch. Cellulose 28, 8705–8718 (2021). https://doi.org/10.1007/s10570-021-04065-5
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DOI: https://doi.org/10.1007/s10570-021-04065-5