Abstract
Cellulose nanofibers (CNFs) and nanocrystals (CNCs) were prepared, and used to prepare thin CNF/CNC films. Rheological behavior of CNF/CNC suspensions and the other relevant properties of the films were characterized in comparison with a commercial porous polymer battery separator (PBS) film of similar thickness. The use of mixed CNFs and CNCs in the film-forming suspension led to significant variation of film morphology, and structural properties. With the addition of CNCs in hybrid nanocellulose material, the CNF/CNC suspension viscosity and zeta potential, film tensile strength, crystallinity index, and optical transparency were increased. With the increased CNF loading in the suspension, film porosity, thermal stability, and thermal expansion were enhanced. The CNF/CNC films exhibited better thermal stability, thermal expansion behavior, and optical properties than those of the commercial PBS film. The coefficient thermal expansion of the CNF/CNC and PBS films were 11.86–17.65 and 178.90 ppm/k, respectively. The CNF/CNC films had more uniform strength along all directions, whereas PBS film demonstrated anisotropic property. This work paves a new strategy to tailor the properties of nanocellulose based films.
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Abdalkarim SYH, Yu H-Y, Wang D, Yao J (2017) Electrospun poly(3-hydroxybutyrate-co-3-hydroxy-valerate)/cellulose reinforced nanofibrous membranes with ZnO nanocrystals for antibacterial wound dressings. Cellulose 24:2925–2938. https://doi.org/10.1007/s10570-017-1303-0
Alam MM, Mandal D (2016) Native cellulose microfiber-based hybrid piezoelectric generator for mechanical energy harvesting utility. ACS Appl Mater Interfaces 8:1555–1558. https://doi.org/10.1021/acsami.5b08168
Cheng S, Zhang Y, Cha R, Yang J, Jiang X (2016) Water-soluble nanocrystalline cellulose films with highly transparent and oxygen barrier properties. Nanoscale 8:973–978. https://doi.org/10.1039/C5NR07647A
Chun S-J, Choi E-S, Lee E-H, Kim JH, Lee S-Y, Lee S-Y (2012) Eco-friendly cellulose nanofiber paper-derived separator membranes featuring tunable nanoporous network channels for lithium-ion batteries. J Mater Chem 22:16618–16626. https://doi.org/10.1039/C2JM32415F
Costa SV, Pingel P, Janietz S, Nogueira AF (2016) Inverted organic solar cells using nanocellulose as substrate. J Appl Polym Sci 133:43679–43685. https://doi.org/10.1002/app.43679
de Morais Teixeira E, Corrêa AC, Manzoli A, de Lima Leite F, de Oliveira CR, Mattoso LHC (2010) Cellulose nanofibers from white and naturally colored cotton fibers. Cellulose 17:595–606. https://doi.org/10.1007/s10570-010-9403-0
Diaz JA, Wu X, Martini A, Youngblood JP, Moon RJ (2013) Thermal expansion of self-organized and shear-oriented cellulose nanocrystal films. Biomacromol 14:2900–2908. https://doi.org/10.1021/bm400794e
El Miri N, Abdelouahdi K, Barakat A, Zahouily M, Fihri A, Solhy A, El Achaby M (2015) Bio-nanocomposite films reinforced with cellulose nanocrystals: rheology of film-forming solutions, transparency, water vapor barrier and tensile properties of films. Carbohydr Polym 129:156–167. https://doi.org/10.1016/j.carbpol.2015.04.051
Fang Z et al (2014) Novel nanostructured paper with ultrahigh transparency and ultrahigh haze for solar cells. Nano Lett 14:765–773. https://doi.org/10.1021/nl404101p
French AD (2014) Idealized powder diffraction patterns for cellulose polymorphs. Cellulose 21:885–896. https://doi.org/10.1007/s10570-013-0030-4
Furukawa T et al (2006) Molecular structure, crystallinity and morphology of polyethylene/polypropylene blends studied by raman mapping, scanning electron microscopy, wide angle X-ray diffraction, and differential scanning calorimetry. Polym J 38:1127–1136
Garusinghe UM, Varanasi S, Garnier G, Batchelor W (2017) Strong cellulose nanofibre–nanosilica composites with controllable pore structure. Cellulose 24:2511–2521. https://doi.org/10.1007/s10570-017-1265-2
Habibi Y, Lucia LA, Rojas OJ (2010) Cellulose nanocrystals: chemistry, self-assembly, and applications. Chem Rev 110:3479–3500. https://doi.org/10.1021/cr900339w
Han J, Zhou C, Wu Y, Liu F, Wu Q (2013) Self-assembling behavior of cellulose nanoparticles during freeze-drying: effect of suspension concentration, particle size, crystal structure, and surface charge. Biomacromolecules 14:1529–1540. https://doi.org/10.1021/bm4001734
Herrera MA, Sirviö JA, Mathew AP, Oksman K (2016) Environmental friendly and sustainable gas barrier on porous materials: nanocellulose coatings prepared using spin- and dip-coating. Mater Des 93:19–25. https://doi.org/10.1016/j.matdes.2015.12.127
Herrera MA, Mathew AP, Oksman K (2017) Barrier and mechanical properties of plasticized and cross-linked nanocellulose coatings for paper packaging applications. Cellulose 24:3969–3980. https://doi.org/10.1007/s10570-017-1405-8
Hollertz R, Durán VL, Larsson PA, Wågberg L (2017) Chemically modified cellulose micro- and nanofibrils as paper-strength additives. Cellulose 24:3883–3899. https://doi.org/10.1007/s10570-017-1387-6
Hua K, Carlsson DO, Alander E, Lindstrom T, Stromme M, Mihranyan A, Ferraz N (2014) Translational study between structure and biological response of nanocellulose from wood and green algae. RSC Adv 4:2892–2903. https://doi.org/10.1039/C3RA45553J
Johar N, Ahmad I, Dufresne A (2012) Extraction, preparation and characterization of cellulose fibres and nanocrystals from rice husk. Ind Crops Prod 37:93–99. https://doi.org/10.1016/j.indcrop.2011.12.016
Kumar H, Christopher LP (2017) Recent trends and developments in dissolving pulp production and application. Cellulose 24:2347–2365. https://doi.org/10.1007/s10570-017-1285-y
Kumar A, Negi YS, Choudhary V, Bhardwaj NK (2014) Characterization of cellulose nanocrystals produced by acid-hydrolysis from sugarcane bagasse as agro-waste. J Mater Phys Chem 2:1–8
Lee H, Yanilmaz M, Toprakci O, Fu K, Zhang X (2014) A review of recent developments in membrane separators for rechargeable lithium-ion batteries. Energy Environ Sci 7:3857–3886. https://doi.org/10.1039/C4EE01432D
Lin W-C, Lien C-C, Yeh H-J, Yu C-M, S-h Hsu (2013) Bacterial cellulose and bacterial cellulose–chitosan membranes for wound dressing applications. Carbohydr Polym 94:603–611. https://doi.org/10.1016/j.carbpol.2013.01.076
Lin J-H et al (2015) Preparation and compatibility evaluation of polypropylene/high density polyethylene. Polyblends Mater 8:5496
Linvill E, Larsson PA, Östlund S (2017) Advanced three-dimensional paper structures: mechanical characterization and forming of sheets made from modified cellulose fibers. Mater Des 128:231–240. https://doi.org/10.1016/j.matdes.2017.05.002
Lizundia E, Urruchi A, Vilas JL, León LM (2016) Increased functional properties and thermal stability of flexible cellulose nanocrystal/ZnO films. Carbohydr Polym 136:250–258. https://doi.org/10.1016/j.carbpol.2015.09.041
Mao R, Goutianos S, Tu W, Meng N, Chen S, Peijs T (2017) Modelling the elastic properties of cellulose nanopaper. Mater Des 126:183–189. https://doi.org/10.1016/j.matdes.2017.04.050
Moon RJ, Martini A, Nairn J, Simonsen J, Youngblood J (2011) Cellulose nanomaterials review: structure, properties and nanocomposites. Chem Soc Rev 40:3941–3994. https://doi.org/10.1039/C0CS00108B
Nagalakshmaiah M, Kissi NE, Mortha G, Dufresne A (2016) Structural investigation of cellulose nanocrystals extracted from chili leftover and their reinforcement in cariflex-IR rubber latex. Carbohydr Polym 136:945–954. https://doi.org/10.1016/j.carbpol.2015.09.096
Orchard GAJ, Davies GR, Ward IM (1984) The thermal expansion behaviour of highly oriented polyethylene. Polymer 25:1203–1210. https://doi.org/10.1016/0032-3861(84)90364-1
Park S, Baker JO, Himmel ME, Parilla PA, Johnson DK (2010) Cellulose crystallinity index: measurement techniques and their impact on interpreting cellulase performance. Biotechnol Biofuels 3(1):10
Salas C, Nypelö T, Rodriguez-Abreu C, Carrillo C, Rojas OJ (2014) Nanocellulose properties and applications in colloids and interfaces. Curr Opin Colloid Interface Sci 19:383–396. https://doi.org/10.1016/j.cocis.2014.10.003
Segal L, Creely JJ, Martin AE, Conrad CM (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer text. Res J 29:786–794. https://doi.org/10.1177/004051755902901003
Shi X, Li C, Huang J, Wang W, Liu H, Xu Q (2016) Preparation and characterization of natural cellulose packaging film. In: Ouyang Y, Xu M, Yang L, Ouyang Y (eds) Advanced graphic communications, packaging technology and materials. Springer, Singapore, pp 827–835. https://doi.org/10.1007/978-981-10-0072-0_102
Sofla MRK, Brown RJ, Tsuzuki T, Rainey TJ (2016) A comparison of cellulose nanocrystals and cellulose nanofibres extracted from bagasse using acid and ball milling methods. Adv Nat Sci Nanosci Nanotechnol 7:035004
Sun X, Wu Q, Ren S, Lei T (2015) Comparison of highly transparent all-cellulose nanopaper prepared using sulfuric acid and TEMPO-mediated oxidation methods. Cellulose 22:1123–1133. https://doi.org/10.1007/s10570-015-0574-6
Sun X, Wu Q, Lee S, Qing Y, Wu Y (2016) Cellulose nanofibers as a modifier for rheology, curing and mechanical performance of oil well cement. Sci Rep 6:31654. https://doi.org/10.1038/srep31654
Terinte N, Ibbett R, Schuster KC (2011) Overview on native cellulose and microcrystalline cellulose I structure studied by X-ray diffraction (WAXD): comparison between measurement techniques. Lenzinger Berichte 89:118–131
Xu X et al (2016) Highly transparent, low-haze, hybrid cellulose nanopaper as electrodes for flexible electronics. Nanoscale 8:12294–12306. https://doi.org/10.1039/c6nr02245f
Xu Q, Wei C, Fan L, Peng S, Xu W, Xu J (2017) A bacterial cellulose/Al2O3 nanofibrous composite membrane for a lithium-ion battery separator. Cellulose 24:1889–1899. https://doi.org/10.1007/s10570-017-1225-x
Yue Y, Han J, Han G, Zhang Q, French AD, Wu Q (2015) Characterization of cellulose I/II hybrid fibers isolated from energycane bagasse during the delignification process: morphology, crystallinity and percentage estimation. Carbohydr Polym 133:438–447. https://doi.org/10.1016/j.carbpol.2015.07.058
Zhang B, Azuma J, Uyama H (2015a) Preparation and characterization of a transparent amorphous cellulose film. RSC Adv 5:2900–2907. https://doi.org/10.1039/C4RA14090G
Zhang H, Wang X, Liang Y (2015b) Preparation and characterization of a lithium-ion battery separator from cellulose nanofibers. Heliyon 1:e00032. https://doi.org/10.1016/j.heliyon.2015.e00032
Zhang X, Wu H, Guo S, Wang Y (2015c) Understanding in crystallization of polyethylene: the role of boron nitride (BN) particles. RSC Adv 5:99812–99819. https://doi.org/10.1039/c5ra19982d
Zhang H, Yu H-Y, Wang C, Yao J (2017) Effect of silver contents in cellulose nanocrystal/silver nanohybrids on PHBV crystallization and property improvements. Carbohydr Polym 173:7–16. https://doi.org/10.1016/j.carbpol.2017.05.064
Zhu H et al (2013) Biodegradable transparent substrates for flexible organic-light-emitting diodes. Energy Environ Sci 6:2105–2111. https://doi.org/10.1039/C3EE40492G
Zhu H, Fang Z, Preston C, Li Y, Hu L (2014) Transparent paper: fabrications, properties, and device applications. Energy Environ Sci 7:269–287. https://doi.org/10.1039/C3EE43024C
Acknowledgments
This study was carried out with support from Louisiana Board of Regents [LEQSF(2017-18)-RD-A-01], LEQSF(2015-17)-RD-B-01], LSU Economic Development Assistantship Program, Henan Agricultural University (Zhengzhou, China), and Henan Academy of Science (Zhengzhou, China).
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Sun, X., Wu, Q., Zhang, X. et al. Nanocellulose films with combined cellulose nanofibers and nanocrystals: tailored thermal, optical and mechanical properties. Cellulose 25, 1103–1115 (2018). https://doi.org/10.1007/s10570-017-1627-9
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DOI: https://doi.org/10.1007/s10570-017-1627-9