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One-Pot Synthesis of Carboxymethylcellulose-Templated Copper-NPs for Heterocatalytic Huisgen-Click Reactions on Lignocellulosic Bamboo Slices

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Abstract

We demonstrated the one-pot synthesis of copper nanoparticles (mainly as Cu0; CuNPs) mediated by carboxymethylcellulose in water and their heterocatalytic activity when supported on lignocellulosic bamboo slices (CuNPs-BSs). The real-time monitoring of CuNPs formation was performed by time-domain NMR under different temperatures and concentrations of copper precursor. Several 1,4-disubstituted 1,2,3-triazoles were synthesized in organic and aqueous solution at 70 °C. The unprecedented CuNPs-BSs were reused several times with minimal leaching (1.14 ppm) of the copper nanocatalyst.

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Acknowledgements

The authors are grateful for the financial support from the Serrapilheira Institute (Grant Number Serra-1709-17482), Conselho Nacional de Desenvolvimento Científico e Tecnologico-Brasil (CNPq) (458302/2013-9), Fundação Amparo à Pesquisa do Estado do Rio de Janeiro (FAPERJ) (E-26/010.100622/2018, E-26/010.001646/2019, SEI-260003/001227/2020 and E-26/010.000980/2019) and Coordenação de Aperfeiçoamento de Pessoal de Nível Superior—Brasil (CAPES)—Finance Code 001. PhD student D.S.d.S. is grateful to FAPERJ for scholar fellowships. We thank Prof. Tatiana D. Saint’Pierre and Rafael Rocha for the assistance during the ICP-MS analysis. We are thankful for the access to the facilities for electron microscopy of LabNano (CBPF), Brazil.

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  1. Omar Ginoble Pandoli

    Present address: Dipartimento di Farmacia, Università degli studi di Genova, Viale Bendetto XV, 3, Genova, Italy

Authors and Affiliations

  1. Flowchemistry and Nanochemistry Research Group, Departamento de Química, Pontifícia Universidade Católica do Rio de Janeiro, Rua Marque de São Vincente, 225, Rio de Janeiro, 22451-900, Brazil

    Druval Santos de Sá & Omar Ginoble Pandoli

  2. Laboratório de Serviços em Relaxometria, Instituto de Macromoléculas Professora Eloisa Mano, Universidade Federal do Rio de Janeiro, Cidade Universitária, Av. Horácio Macedo, Rio de Janeiro, 21941-598, Brazil

    Elton Jorge da Rocha Rodrigues

  3. Universidade Federal do Rio de Janeiro, Campus Duque de Caxias, Duque de Caxias, 25240-005, Brazil

    Natasha Midori Suguihiro

  4. Instituto de Química, Universidade Federal do Rio de Janeiro, Avenida Athos da Silveira Ramos, Rio de Janeiro, 21941-909, Brazil

    Amanda Garcez da Veiga

  5. Departamento de Engenharia Química e de Materiais, Pontifícia Universidade Católica, Rua Marque de São Vincente, 225, Rio de Janeiro, 22451-900, Brazil

    Sidnei Paciornik

  6. Dipartimento di Scienze Chimiche, Farmaceutiche e Agrarie, Università di Ferrara, Via Luigi Borsari, 46, 44121, Ferrara, Italy

    Alessandro Massi

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DSS, EJRR, NMS, AGV, SP, AM, OGP designed, performed, evaluated, and discussed the experiments. OGP, DSS, ER wrote the paper. All authors reviewed the manuscript and agreed to the final version.

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de Sá, D.S., da Rocha Rodrigues, E.J., Suguihiro, N.M. et al. One-Pot Synthesis of Carboxymethylcellulose-Templated Copper-NPs for Heterocatalytic Huisgen-Click Reactions on Lignocellulosic Bamboo Slices. Catal Lett 152, 3558–3575 (2022). https://doi.org/10.1007/s10562-022-03923-6

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