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FeZnK/SAPO-34 Catalyst for Efficient Conversion of CO2 to Light Olefins

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Abstract

Herein, a catalyst denoted as FeZnK/SAPO-G was designed and prepared through a granule-stacking method, where the FeZnK was active phase for producing hydrocarbons and SAPO-34 cracked long-chain hydrocarbons into short-chain hydrocarbons dominated by ethylene. This catalyst can achieve a high CO2 conversion (49.4%) with a favorable light olefin selectivity (52.4%) among the hydrocarbon products. Results of characterizations show that the integrated manner of FeZnK and SAPO-34 would have a significant impact on the reducibility, the acidity and CO2 adsorption property of catalyst, leading to different catalytic activity. The catalyst exhibited a favorable stability in 72-h reaction test, indicating a promising candidate for industrial application.

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (21908108 and 51702241), Jiangsu Province Scientific and Technological Project of China (BK20180449), and Top-notch Academic Programs Project of Jiangsu Higher Education Institutions of China.

Funding

This study were funded by Jiangsu Province Scientific and Technological Project of China (BK20180449), Top-notch Academic Programs Project of Jiangsu Higher Education Institutions of China, National Natural Science Foundation of China (21908108 and 51702241).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094, Jiangsu, China

    Qiang Liu, Jie Ding, Ruonan Wang & Qin Zhong

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  1. Qiang Liu
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  2. Jie Ding
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  3. Ruonan Wang
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  4. Qin Zhong
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Correspondence to Jie Ding or Qin Zhong.

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Liu, Q., Ding, J., Wang, R. et al. FeZnK/SAPO-34 Catalyst for Efficient Conversion of CO2 to Light Olefins. Catal Lett 153, 54–61 (2023). https://doi.org/10.1007/s10562-021-03863-7

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  • DOI: https://doi.org/10.1007/s10562-021-03863-7

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