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Baeyer–Villiger Oxidation of Cyclohexanone by Hydrogen Peroxide with Fe3O4@GO as Catalyst Under Solvent Free Conditions

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Abstract

An efficient magnetic nanocomposite catalyst (Fe3O4@GO) was synthesized and utilized as a sustainable and convenient catalyst for Baeyer–Villiger oxidation. The catalyst was characterized by XRD, FT-IR, TEM, SEM, XPS, Raman and VSM. Under solvent free conditions, hydrogen peroxide as green oxidant, Fe3O4@GO showed an efficient catalytic activity and excellent selectivity for Baeyer–Villiger oxidation at room temperature. Conversion of 2-methyl cyclohexanone and selectivity of ε-heptanlactone were 84% and 94%, respectively. The catalyst can be magnetically reused and recycled for several runs without any significant loss in efficiency and selectivity.

Graphical Abstract

An efficient magnetic nanocomposite catalyst (Fe3O4@GO) was synthesized to show high catalytic activity and excellent selectivity for the Baeyer–Villiger oxidation under solvent free conditions with hydrogen peroxide.

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References

  1. Liu Y, Li Z, Shen W (2008) Recent Pat Chem Eng 1:1

    Google Scholar 

  2. Toebes ML, Prinsloo FF, Bitter JH (2003) J Catal 214:78

    Article  CAS  Google Scholar 

  3. Kuila T, Mishra AK, Khanra P (2013) Nanoscale 5:52

    Article  CAS  PubMed  Google Scholar 

  4. Gao W (2015) Springer International Publishing, pp 61–95

  5. Marcano DC, Kosynkin DV, Berlin JM (2010) ACS Nano 4:4806

    Article  CAS  Google Scholar 

  6. Dreyer DR, Park S, Bielawski CW (2009) Chem Soc Rev 39:228

    Article  PubMed  Google Scholar 

  7. Zhu Y, Murali S, Cai W (2010) Cheminform 22:3906

    CAS  Google Scholar 

  8. Chen D, Feng H, Li J (2012) Chem Rev 112:6027

    Article  CAS  Google Scholar 

  9. Dikin DA, Stankovich S, Zimney EJ (2015) Nature 448:457

    Article  CAS  Google Scholar 

  10. Dhakshinamoorthy A, Alvaro M, Garcia H (2012) Chem Commun 48:11275

    Article  CAS  Google Scholar 

  11. Yang S, Zhang ZH, Chen Q (2017) Appl Organomet Chem e4132. https://doi.org/10.1002/aoc.4132

  12. Pescarmona PP, Jacobs PA (2008) Catal Today 137:52

    Article  CAS  Google Scholar 

  13. Haag DR, Kung HH (2014) Top Catal 57:764

    Article  CAS  Google Scholar 

  14. Wiltshire JG, Li LJ, Khlobystov AN (2005) Carbon 43:1151

    Article  CAS  Google Scholar 

  15. Arash GC, Darvishnejad Z, Norouzi M (2015) Appl Organomet Chem 29:170

    Article  CAS  Google Scholar 

  16. Krow GR (1993) Org React 43:251

    CAS  Google Scholar 

  17. Strukul G (2010) Cheminform 29:31

    Article  Google Scholar 

  18. Ech JP, Carretero MA (2017) Chemcatchem 9:15

    Article  CAS  Google Scholar 

  19. Fischer J, Holderich WF (1999) Appl Catal A 180:435

    Article  CAS  Google Scholar 

  20. Schreiber SL, Liew WF (1983) Tetrahedron Lett 24:2363

    Article  CAS  Google Scholar 

  21. Cesar JS, Jose RR (2011) Tetrahedron 2008:64

    Google Scholar 

  22. Benito A, Moustafa FA, Miguel AS (1995) Tetrahedron Lett 36:3401

    Article  Google Scholar 

  23. Corma A, Navarro MT, Renz M (2003) J Catal 219:242

    Article  CAS  Google Scholar 

  24. Lei Z, Zhang Q, Wang R (2006) ChemInform 691:5767

    CAS  Google Scholar 

  25. Pillai UR, Sahle-Demessie E (2003) J Mol Catal A 191:93

    Article  CAS  Google Scholar 

  26. Zhou XT, Ji HB, Yuan QL (2009) J Porphyr Phthalocyanines 12:94

    Article  Google Scholar 

  27. Lei ZQ, Wei LL, Wang RR (2008) Catal Commun 9:15

    Google Scholar 

  28. Ma Y, Liang Z, Feng S (2015) Appl Organomet Chem 29:7

    Article  CAS  Google Scholar 

  29. Olszówka JE, Karcz R, Napruszewska BD (2018) Catal Commun 107:48–52

    Article  CAS  Google Scholar 

  30. Guan FF, Ma TT, Yuan X (2018) Catal Lett 148:443

    Article  CAS  Google Scholar 

  31. Modi CK, Solanki N, Vithalani R (2017) Appl Organomet Chem 32:e3910

    Article  CAS  Google Scholar 

  32. Cuetos A, Rioz-Martínez A, Valenzuela ML (2012) J Mol Catal B 74:178

    Article  CAS  Google Scholar 

  33. Torres Pazmiño DE, Dudek HM, Fraaije MW (2010) Curr Opin Chem Biol 14:138

    Article  CAS  PubMed  Google Scholar 

  34. Du GH, Liu ZL, Xia X, Chu Q, Zhang SM (2006) J Sol-Gel Sci Technol 39:285

    Article  CAS  Google Scholar 

  35. Huo X, Liu J, Wang B, Zhang H, Yang Z, She X, Xi P (2013) J Mater Chem A 1:651

    Article  CAS  Google Scholar 

  36. Corma A, Renz M (2004) Chem Commun 35:550

    Article  Google Scholar 

  37. Aunkor MTH, Mahbubul IM, Saidurb R, Metselaar HSC (2016) RSC Adv 6:27807

    Article  CAS  Google Scholar 

  38. Li P, Jiang EY, Bai HL (2011) J Phys D 44:7879

    Google Scholar 

  39. Hara T, Hatakeyama M, Kim A, Ichikuni N, Shimazu S (2012) Green Chem 14:771

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094, China

    Guansheng Xiao, Xi Gao, Weiting Yan, Tao Wu & Xinhua Peng

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  1. Guansheng Xiao
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  2. Xi Gao
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  3. Weiting Yan
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  4. Tao Wu
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  5. Xinhua Peng
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Correspondence to Xinhua Peng.

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Xiao, G., Gao, X., Yan, W. et al. Baeyer–Villiger Oxidation of Cyclohexanone by Hydrogen Peroxide with Fe3O4@GO as Catalyst Under Solvent Free Conditions. Catal Lett 149, 1765–1771 (2019). https://doi.org/10.1007/s10562-019-02765-z

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