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Immobilization of a nickel complex onto functionalized Fe3O4 nanoparticles: a green and recyclable catalyst for synthesis of 5-substituted 1H-tetrazoles and oxidation reactions

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Abstract

In the present research, a magnetically recoverable catalyst was easily prepared by anchoring nickel onto the surface of organically modified magnetite nanoparticles. Characterization of the prepared nanostructure was performed by various physico-chemical techniques such as Fourier transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, inductively coupled plasma optical emission spectroscopy, X-ray diffraction, thermal gravimetric analysis and vibrating sample magnetometer measurements. The catalytic behavior of the prepared nanohybrid as an efficient catalyst was successfully probed in the oxidation of sulfides, oxidative coupling of thiols and synthesis of 5-substituted 1H-tetrazoles. This method was found to have significant advantages, including high yield, green reaction conditions, short reaction time, easy separation and workup, as well as the ability to tolerate a wide variety of substitutions in the reagents.

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Acknowledgements

The authors are deeply grateful to the University of Kurdistan and University of Ilam for financial support of this research project.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Kurdistan, Sanandaj, Iran

    Taiebeh Tamoradi, Bita Mehraban-Esfandiari & Mohammad Ghadermazi

  2. Department of Chemistry, Faculty of Science, Ilam University, P.O. Box, 69315516, Ilam, Iran

    Arash Ghorbani-Choghamarani

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  1. Taiebeh Tamoradi
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Correspondence to Taiebeh Tamoradi, Mohammad Ghadermazi or Arash Ghorbani-Choghamarani.

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Tamoradi, T., Mehraban-Esfandiari, B., Ghadermazi, M. et al. Immobilization of a nickel complex onto functionalized Fe3O4 nanoparticles: a green and recyclable catalyst for synthesis of 5-substituted 1H-tetrazoles and oxidation reactions. Res Chem Intermed 44, 1363–1380 (2018). https://doi.org/10.1007/s11164-017-3172-4

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