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Synthesis, Characterization and Crystal Structure of New 2-Morpholinoethyl-Substituted Bis-(NHC)Pd(II) Complexes and the Catalytic Activity in the Direct Arylation Reaction

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Abstract

This paper contains the synthesis of the new 2-morpholinoethyl substituted bis-(NHC)Pd(II) complexes and their catalytic activity in direct arylation reaction. The new bis-(NHC)Pd(II) complexes have been prepared from Ag(I)NHC complexes by using transmetallation method. The new bis-(NHC)Pd(II) complexes have been characterized by using 1H NMR, 13C NMR, FTIR spectroscopy and elemental analysis techniques. Molecular and crystal structure of the complex 1a and its ligand (N-benzylbenzimidazole) were obtained by single crystal X-ray diffraction method. The new bis-(NHC)Pd(II) complexes exhibit activity in the reaction after being examined as catalysts in the direct arylation (C–H activation) reaction.

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Acknowledgements

The authors acknowledge İnönü University Scientific and Technology Center for the elemental analyses of the compounds and Dokuz Eylül University for the use of the Rigaku Oxford Xcalibur Eos Diffractometer (purchased under University Research Grant No: 2010.KB.FEN.13).

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, İnönü University, 44280, Malatya, Turkey

    Yakup Sarı, Aydın Aktaş & Yetkin Gök

  2. Department of Physics, Faculty of Science, Dokuz Eylül University, 35160, Buca, Izmir, Turkey

    Duygu Barut Celepci & Muhittin Aygün

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  1. Yakup Sarı
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  2. Aydın Aktaş
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  3. Duygu Barut Celepci
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  4. Yetkin Gök
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  5. Muhittin Aygün
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Correspondence to Aydın Aktaş.

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Sarı, Y., Aktaş, A., Barut Celepci, D. et al. Synthesis, Characterization and Crystal Structure of New 2-Morpholinoethyl-Substituted Bis-(NHC)Pd(II) Complexes and the Catalytic Activity in the Direct Arylation Reaction. Catal Lett 147, 2340–2351 (2017). https://doi.org/10.1007/s10562-017-2132-3

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  • DOI: https://doi.org/10.1007/s10562-017-2132-3

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