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Highly Efficient and Magnetically Recyclable Pt Catalysts for Hydrosilylation Reactions

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Abstract

Fe3O4@SiO2-APTES-Pt was prepared from 3-aminopropyl triethoxysilane via immobilization on Fe3O4@SiO2, followed by reacted with chloroplatinic acid. The obtained catalyst was characterized by XRD, TEM, FT-IR, XPS and ICP-AES. This catalyst showed extraordinary catalytic performances for hydrosilylation of olefins with triethoxysilane. It was recovered from the reaction medium just by sequestering by a magnet and then reused several times without significant loss in catalytic activity and selectivity.

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Acknowledgements

The work was financially supported by the National Natural Science Foundation of China (21576248 and 21571159), Scientific and Technological Project of Henan Province (152102210355), a research fund from the doctoral program of Zhengzhou University of Light Industry (2014BSJJ007) and Science Foundation of Zhengzhou University of Light Industry (2015XJJY007).

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Correspondence to Jianbo Zhao or Shaoming Fang.

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Zhao, J., Gui, Y., Liu, Y. et al. Highly Efficient and Magnetically Recyclable Pt Catalysts for Hydrosilylation Reactions. Catal Lett 147, 1127–1132 (2017). https://doi.org/10.1007/s10562-017-1984-x

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  • DOI: https://doi.org/10.1007/s10562-017-1984-x

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