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The Influence of Fe, Ti, Ga and Zn on the Fischer–Tropsch Synthesis Catalytic Performance of Co-Based Hierarchically Porous ZSM-5 Zeolite Catalysts

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Abstract

Hierarchically ZSM-5 zeolite was prepared by alkali treatment. It was used as a support for a series of Co-based catalysts for Fischer–Tropsch synthesis with Fe, Ti, Ga or Zn as promoter. This series of catalysts were named Co/M-ZSM-5 (M = Fe, Ti, Ga or Zn). The catalysts were characterized by SEM, XRD, H2-TPR, and XPS, and the FTS catalytic performance of catalysts were compared. The character date revealed that the promoter changed the dispersion, reducibility and stability of Co. The addition of Zn and Ga increased the activity of catalysts, decreased the selectivity to CH4. The Ti promoted catalyst had the highest initial activity, but it deactivated rapidly. The suitable interaction between Co and the Fe-ZSM-5 result in the suitable dispersion and reduction. Thus Fe is the better promoter for the catalyst Co/ZSM-5.

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Acknowledgements

Financial support by the Key Program project of the NSFC and China Petrochemical Corporation Joint Fund (Grant No. U1463210), National Natural Science Foundation of China (Grant Nos. 21473259, 21203253), Key Program of Technology Innovation of Hubei Province (2013AGB002) and Fundamental Research Funds for the Central Universities, South-Central University for Nationalities (Grant No. CZZ16001) are acknowledged.

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Authors and Affiliations

  1. Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission and Ministry of Education, South-Central University for Nationalities, Wuhan, 430074, Hubei, China

    Yao Chen, Yu-hua Zhang, Yan-xi Zhao, Xiong Wen, Xin Zhao & Jin-lin Li

  2. The Hubei Province Key Laboratory of Coal Conversion and New Carbon Materials, School of Chemical Engineering and Technology, Wuhan University of Science and Technology, Wuhan, 430081, Hubei, China

    Cheng-chao Liu

  3. College of Chemistry and Materials Science, Guangxi Teachers Education University, Nanning, 530001, Guangxi, China

    Liang Wei

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  1. Yao Chen
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  2. Cheng-chao Liu
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  3. Yu-hua Zhang
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  4. Yan-xi Zhao
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  5. Liang Wei
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  7. Xin Zhao
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  8. Jin-lin Li
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Correspondence to Jin-lin Li.

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Chen, Y., Liu, Cc., Zhang, Yh. et al. The Influence of Fe, Ti, Ga and Zn on the Fischer–Tropsch Synthesis Catalytic Performance of Co-Based Hierarchically Porous ZSM-5 Zeolite Catalysts. Catal Lett 147, 502–508 (2017). https://doi.org/10.1007/s10562-016-1926-z

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  • DOI: https://doi.org/10.1007/s10562-016-1926-z

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