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Steam Reforming of Methane Over Catalyst Derived from Ordered Double Perovskite: Effect of Crystalline Phase Transformation

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Abstract

La2NiTiO6 double perovskite was synthesized by modified Pechini method. The catalyst activity for steam reforming of methane was investigated at temperatures from 450 to 950 °C, under different reduction conditions. By reducing La2NiTiO6 with 10 % H2/N2 at 1,000 °C, the crystalline phase changed to mainly Ni0 and La2TiO5, which decreases the onset temperature of methane conversion to 550 °C and provides a maximum methane conversion of 95 % at 950 °C. This activity is higher when compared to that achieved with La2NiTiO6 reduced with 1.8 % H2/Ar, which is composed of Ni0 supported on both non-stoichiometric La2NiTiO6 and La2O3, and also to those of unreduced La2NiTiO6 and Ni/La2O3 formed by reduction of LaNiO3. Activity improvement is related to the increased number of active sites and/or metal-support interaction.

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Acknowledgments

The authors thank Carlos André de Castro Perez from NUCAT/PEQ/COPPE/UFRJ for Rietveld analysis and Pablo V. Tuza acknowledges to Secretaría de Educación Superior, Ciencia, Tecnologia e Innovación SENESCYT-Ecuador for the financial support of this work.

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Authors and Affiliations

  1. Escola de Química, Centro de Tecnologia, Universidade Federal do Rio de Janeiro (UFRJ), Bloco E, Sala 206, Rio De Janeiro, RJ, CEP 21941-909, Brazil

    Pablo V. Tuza & Mariana M. V. M. Souza

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  1. Pablo V. Tuza
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  2. Mariana M. V. M. Souza
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Correspondence to Mariana M. V. M. Souza.

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Tuza, P.V., Souza, M.M.V.M. Steam Reforming of Methane Over Catalyst Derived from Ordered Double Perovskite: Effect of Crystalline Phase Transformation. Catal Lett 146, 47–53 (2016). https://doi.org/10.1007/s10562-015-1617-1

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  • DOI: https://doi.org/10.1007/s10562-015-1617-1

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