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Preparation and Evaluation of the Modified Nanoparticle SAPO-18 for Catalytic Conversion of Methanol to Light Olefins

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Abstract

Silicoaluminophosphate-18 can be considered as an effective catalyst for methanol conversion to olefins (MTO). A series of SAPO-18 were prepared to investigate the effects of aging pretreatment on crystallization time. The results exhibit that stirring aging, in addition to reducing the overall particle size of SAPO-18, decreases the crystallization time from 168 to 65 h. Also, the effects of addition order of the reagents and crystallization time on physiochemical properties of the SAPO-18 nanoparticles were studied. Finally detailed investigations were carried out on the catalytic performance of the samples in MTO process and the best catalyst was determined.

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Authors and Affiliations

  1. Chemical Engineering Department, Catalyst Research Center, Faculty of Engineering, Razi University, Bākhtarān, 67149-67346, Iran

    Mohadese Nazari, Gholamreza Moradi & Shadab Abdollahi

  2. Gas Engineering Department, Petroleum University of Technology, Ahvaz, 63431, Iran

    Reza M. Behbahani & Mohamad Ghavipour

Authors
  1. Mohadese Nazari
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  2. Gholamreza Moradi
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  3. Reza M. Behbahani
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  4. Mohamad Ghavipour
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  5. Shadab Abdollahi
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Correspondence to Gholamreza Moradi.

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Nazari, M., Moradi, G., Behbahani, R.M. et al. Preparation and Evaluation of the Modified Nanoparticle SAPO-18 for Catalytic Conversion of Methanol to Light Olefins. Catal Lett 145, 1893–1903 (2015). https://doi.org/10.1007/s10562-015-1607-3

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  • DOI: https://doi.org/10.1007/s10562-015-1607-3

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