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Enhancing the Catalytic Activity of Hollandite Manganese Oxide by Supporting Sub-10 nm Ceria Particles

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Abstract

Sub-10 nm CeO2 particles were highly dispersed on Hollandite-type manganese oxide (HMO) to give a CeOx/HMO catalyst, which showed obviously higher activity than HMO and CeO2 alone in CO oxidation and selective catalytic reduction of NO by NH3. A combination of various characterization data with the catalytic tests revealed that the enhanced catalytic activity results from the strong interaction between CeO2 and HMO to activate the transfer of electron, the improved redox ability of surface oxygen due to an increased electron density, and the presence of more surface active oxygen species.

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Acknowledgments

This work was financially supported by the NSFC (21277032, 21477023, 21177028), the STCSM (14JC1400400), and the SCAPC (201306). Y. Wang wishes to thank the UROP program of Fudan University and CURE.

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Authors and Affiliations

  1. Shanghai Key Laboratory of Atmospheric Particle Pollution & Prevention (LAP3), Department of Environmental Science & Engineering, Fudan University, 200433, Shanghai, China

    Yue Wang, Huan Liu, Pingping Hu, Zhiwei Huang, Jiayi Gao, Fei Xu, Zhen Ma & Xingfu Tang

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  1. Yue Wang
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  2. Huan Liu
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  3. Pingping Hu
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  4. Zhiwei Huang
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  7. Zhen Ma
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  8. Xingfu Tang
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Correspondence to Zhen Ma or Xingfu Tang.

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Wang, Y., Liu, H., Hu, P. et al. Enhancing the Catalytic Activity of Hollandite Manganese Oxide by Supporting Sub-10 nm Ceria Particles. Catal Lett 145, 1880–1884 (2015). https://doi.org/10.1007/s10562-015-1594-4

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  • DOI: https://doi.org/10.1007/s10562-015-1594-4

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