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Enantioselective Ammonolysis of Phenylglycine Methyl Ester with Lipase–Pluronic Nanoconjugate in Tertiary Butanol

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Abstract

Asymmetrical ammonolysis of (R)- and (S)-phenylglycine methyl ester was carried out by using a lipase (CALB)–polymer (Pluronic) nanoconjugate as the catalyst, displaying a 11-fold increased catalytic rate compared to the free CALB in tertiary butanol.

Graphical Abstract

The asymmetrical ammonolysis of (R)- and (S)-phenylglycine methyl ester was accomplished using a lipase–Pluronic nanoconjugate, displaying a 11-fold higher catalytic rate compared to the free lipase.

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Acknowledgment

This work was supported by the National Natural Science Foundation of China under the Grant Number of 21206082 and 21036003.

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Authors and Affiliations

  1. Department of Chemical Engineering, Tsinghua University, Beijing, China

    Xiaoling Wu, Rui Wang, Yifei Zhang, Jun Ge & Zheng Liu

Authors
  1. Xiaoling Wu
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  2. Rui Wang
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  3. Yifei Zhang
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  4. Jun Ge
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  5. Zheng Liu
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Corresponding authors

Correspondence to Jun Ge or Zheng Liu.

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Wu, X., Wang, R., Zhang, Y. et al. Enantioselective Ammonolysis of Phenylglycine Methyl Ester with Lipase–Pluronic Nanoconjugate in Tertiary Butanol. Catal Lett 144, 1407–1410 (2014). https://doi.org/10.1007/s10562-014-1289-2

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  • DOI: https://doi.org/10.1007/s10562-014-1289-2

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