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Realumination of MCM-22 Zeolite and Its Application in Alkylation Reaction

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Abstract

A mechanism of the realumination process was proposed when MCM-22 was post-treated in Al(NO3)3 solution. Al atoms would deposit into zeolite with the amorphous alumina form, or insert into the framework by substituting Si atoms on certain T sites near the surface. The realumination process increased the amount of acid sites on the surface of MCM-22, significantly improved the catalytic activity and stability for olefins conversions in the alkylation of benzene with diluted olefins.

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Acknowledgments

We acknowledge the National Basic Research Program of China (No. 2009CB623501) for the financial support.

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Authors and Affiliations

  1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China

    Kefeng Liu, Shenglin Liu, Sujuan Xie, Huijuan Wei, Chao Song, Xiujie Li & Longya Xu

  2. Petrochemical Research Institute of PetroChina Company Limited, Beijing, 100029, China

    Kefeng Liu

  3. University of Chinese Academy of Sciences, Beijing, 100049, China

    Huijuan Wei & Chao Song

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  1. Kefeng Liu
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  2. Shenglin Liu
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  3. Sujuan Xie
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  4. Huijuan Wei
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  6. Xiujie Li
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  7. Longya Xu
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Correspondence to Longya Xu.

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Liu, K., Liu, S., Xie, S. et al. Realumination of MCM-22 Zeolite and Its Application in Alkylation Reaction. Catal Lett 144, 1223–1232 (2014). https://doi.org/10.1007/s10562-014-1256-y

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  • DOI: https://doi.org/10.1007/s10562-014-1256-y

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