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Effect of Desilication on the Performance of Hierarchical ZSM-11 Catalysts for Alkylation of Benzene with Dimethyl Ether

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Abstract

Hierarchical ZSM-11 zeolites (Z-xat) were prepared by treating the pristine ZSM-11 zeolite in a solution of NaOH with different concentrations (C NaOH). It was found the porosity and acidity (concentration, strength, distribution and accessibility factor of Brønsted and Lewis acid sites) of modified ZSM-11 zeolite changed obviously with C NaOH. When used for alkylation of benzene with dimethyl ether, the modified Z-xat exhibited better reaction stability than the unmodified HZSM-11 zeolite. Typically, the reaction stability of Z-xat zeolite catalysts was directly related to the mesopore volume, besides the weak-medium acid concentrations determined by Py-IR technique.

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Acknowledgments

The guidance and help of Professor Yide Xu is greatly appreciated.

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Authors and Affiliations

  1. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, Liaoning, China

    Hui Liu, Shenglin Liu, Sujuan Xie, Chao Song, Wenjie Xin & Longya Xu

  2. University of Chinese Academy of Sciences, Beijing, 100049, China

    Hui Liu & Chao Song

Authors
  1. Hui Liu
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  2. Shenglin Liu
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  3. Sujuan Xie
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  4. Chao Song
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  5. Wenjie Xin
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  6. Longya Xu
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Corresponding author

Correspondence to Longya Xu.

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Liu, H., Liu, S., Xie, S. et al. Effect of Desilication on the Performance of Hierarchical ZSM-11 Catalysts for Alkylation of Benzene with Dimethyl Ether. Catal Lett 145, 1972–1983 (2015). https://doi.org/10.1007/s10562-015-1589-1

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  • DOI: https://doi.org/10.1007/s10562-015-1589-1

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