Skip to main content
SpringerLink
Log in

Ozone Promotion of Monochlorobenzene Catalytic Oxidation Over Carbon Nanotubes-Supported Copper Oxide at High Temperature

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

Ozone is found to promote the monochlorobenzene (CB) catalytic oxidation over carbon nanotubes supported copper oxide composite up to reaction temperature of 300 °C. Especially at 250 °C, a CB conversion of 99 %, together with a CO2 selectivity of 98 %, was observed. The selective adsorption of CB, the promotion of Cu+ to Cu2+ oxidation, and the combination of O3 and high temperature activated gas phase O2 are all considered to attribute to the high CB conversion and CO2 selectivity at temperature above 250 °C.

Graphical Abstract

Effects of O3 on catalytic oxidation of CB over CuOX/CNTs were studied. A CB conversion of 99 % and a CO2 selectivity of 98 % were achieved at 250 °C, which could be mainly attributed to the synergy between the CB oxidation by O3 and activated O2.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Corella J, Toledo JM (2002) Ind Eng Chem Res 41:1171–1181

    Article  CAS  Google Scholar 

  2. Matatov-Meytal YI, Sheintuch M (1998) Ind Eng Chem Res 37:309–326

    Article  CAS  Google Scholar 

  3. Huang H, Buekens A (1995) Chemosphere 31:4099–4117

    Article  CAS  Google Scholar 

  4. Debecker DP, Delaigle R, Bouchmella K, Eloy P, Gaigneaux EM, Mutin PH (2010) Catal Today 157:125–130

    Article  CAS  Google Scholar 

  5. Debecker DP, Bertinchamps F, Blangenois N, Eloy P, Gaigneaux EM (2007) Appl Catal B Environ 74:223–232

    Article  CAS  Google Scholar 

  6. Wu M, Wang X, Dai Q, Gu Y, Li D (2010) Catal Today 158:336–342

    Article  CAS  Google Scholar 

  7. Lichtenberger J, Amiridis MD (2004) J Catal 223:296–308

    Article  CAS  Google Scholar 

  8. Khaleel A, Nayli AA (2008) Appl Catal B Environ 80:176–184

    Article  CAS  Google Scholar 

  9. Van den Brink RW, Krzan M, Feijen-Jeurissen MMR, Louw R, Mulder P (2000) Appl Catal B Environ 24:255–264

    Article  Google Scholar 

  10. Scirè S, Minicò S, Crisafulli C (2003) Appl Catal B Environ 45:117–125

    Article  Google Scholar 

  11. Jong VD, Cieplik MK, Louw R (2004) Environ Sci Technol 38:5217–5223

    Article  Google Scholar 

  12. Finocchio E, Busca G, Notaro M (2006) Appl Catal B Environ 62:12–20

    Article  CAS  Google Scholar 

  13. Liu Y, Wei ZB, Feng ZC, Luo MF, Ying PL, Li C (2001) J Catal 202:200–204

    Article  CAS  Google Scholar 

  14. Gaillard F, Artizzu P, Brulle Y, Primet M (1998) Surf Inter Anal 26:367–373

    Article  CAS  Google Scholar 

  15. Tian W, Fan XY, Yang HS, Zhang XB (2010) J Hazard Mater 177:887–891

    Article  CAS  Google Scholar 

  16. Tian W, Yang HS, Fan XY, Zhang XB (2010) Catal Commun 11:1185–1188

    Article  CAS  Google Scholar 

  17. Fan XY, Yang HS, Tian W, Nie AM, Hou TF, Qiu FM, Zhang XB (2011) Catal Lett 141:158–162

    Article  CAS  Google Scholar 

  18. Sinquin G, Hindermanmn JP, Petit C, Kiennemann A (1999) Catal Today 54:107–118

    Article  CAS  Google Scholar 

  19. Poplawski K, Lichtenberger J, Keil FJ, Schnitzlein K, Amiridis MD (2000) Catal Today 62:329–337

    Article  CAS  Google Scholar 

  20. Mehandjiev D, Naydenov A, Ivanov G (2001) Appl Catal A Gen 206:13–18

    Article  CAS  Google Scholar 

  21. Dimitrova S, Ivanov G, Mehandjiev D (2004) Appl Catal A Gen 266:81–87

    Article  CAS  Google Scholar 

  22. Einaga H, Futamura S (2004) J Catal 227:304–312

    Article  CAS  Google Scholar 

  23. Einaga H, Ogata A (2009) J Hazard Mater 164:1236–1241

    Article  CAS  Google Scholar 

  24. Gervasini A, Bianchi CL, Ragaini V (1994) ACS Symp Ser 552:353–369

    Article  CAS  Google Scholar 

  25. Gervasini A, Vezzoli GC, Ragaini V (1996) Catal Today 29:449–455

    Article  CAS  Google Scholar 

  26. Naydenov A, Mehandjiev D (1993) Appl Catal 97:17–22

    Article  CAS  Google Scholar 

  27. Wang HC, Liang HS, Chang MB (2011) J Hazard Mater 186:1781–1787

    Article  CAS  Google Scholar 

  28. Yuan MH, Chang CY, Shie JL, Chang CC, Chen JH, Tsai WT (2010) J Hazard Mater 175:809–815

    Article  CAS  Google Scholar 

  29. Liang HS, Wang HC, Chang MB (2011) Ind Eng Chem Res 50:13322–13329

    Article  CAS  Google Scholar 

  30. Petersson M, Jonsson D, Persson H, Cruise N, Andersson B (2006) J Catal 238:321–329

    Article  CAS  Google Scholar 

  31. Wang HC, Liang HS, Chang MB (2011) Chemosphere 82:1090–1095

    Article  CAS  Google Scholar 

  32. Sultana A, Nanba T, Haneda M, Sasaki M, Hamada H (2010) Appl Catal B Environ 101:61–67

    Article  CAS  Google Scholar 

  33. Devadas M, Kröcher O, Elsener M, Wokaun A, Söger N, Pfeifer M, Demel Y, Mussma L (2006) Appl Catal B Environ 67:187–196

    Article  CAS  Google Scholar 

  34. Sultana A, Nanba T, Haneda M, Hamada H (2009) Catal Commun 10:1859–1863

    Article  CAS  Google Scholar 

  35. Qi G, Wang Y, Yang RT (2008) Catal Lett 121:111–117

    Article  CAS  Google Scholar 

  36. Sjövall H, Olsson L, Fridell E, Blint RJ (2006) Appl Catal B Environ 64:180–188

    Article  Google Scholar 

  37. Olsson L, Sjövall H, Blint RJ (2008) Appl Catal B Environ 81:203–217

    Article  CAS  Google Scholar 

  38. Li Q, Yang HS, Ma ZX, Zhang XB (2012) Catal Commun 17:8–12

    Article  CAS  Google Scholar 

  39. Li Q, Yang HS, Nie AM, Fan XY, Zhang XB (2011) Catal Lett 141:1237–1242

    Article  CAS  Google Scholar 

  40. Lin QC, Hao JM, Li JH, Ma ZF, Lin WM (2007) Catal Today 126:351–358

    Article  CAS  Google Scholar 

  41. Wan Y, Ma JX, Wang Z, Zhou W, Kaliaguine S (2004) J Catal 227:242–252

    Article  CAS  Google Scholar 

  42. Dorado F, Lucas AD, Garcia PB, Romero A, Valverde JL (2006) Appl Catal A Gen 305:189–196

    Article  CAS  Google Scholar 

  43. Oyama ST (2000) Catal Rev Sci Eng 42:279–322

    Article  CAS  Google Scholar 

  44. Einaga H, Ogata A (2010) Environ Sci Technol 44:2612–2617

    Article  CAS  Google Scholar 

  45. Sun CZ, Zhu J, Lv YY, Qi L, Liu B, Gao F, Sun KQ, Dong L, Chen Y (2011) Appl Catal B Environ 103:206–220

    Article  CAS  Google Scholar 

  46. Nie AM, Yang HS, Li Q, Fan XY, Qiu FM, Zhang XB (2011) Ind Eng Chem Res 50:9944–9948

    Article  CAS  Google Scholar 

  47. Long RQ, Yang RT (2001) J Am Chem Soc 123:2058–2059

    Article  CAS  Google Scholar 

  48. Yang DQ, Hennequin B, Sacher E (2006) Chem Mater 18:5033–5038

    Article  CAS  Google Scholar 

  49. Chen W, Duan L, Zhu D (2007) Environ Sci Technol 41:8295–8300

    Article  CAS  Google Scholar 

  50. Peng X, Li Y, Luan Z, Di Z, Wang H, Tian B, Jia Z (2003) Chem Phys Lett 376:154–158

    Article  CAS  Google Scholar 

  51. Lichtenberger J, Amiridis MD (2004) J Catal 223:296–308

    Article  CAS  Google Scholar 

  52. Reed C, Xi Y, Oyama ST (2005) J Catal 235:378–392

    Article  CAS  Google Scholar 

  53. Gervasini A, Ragaini V (2000) Catal Today 60:129–138

    Article  CAS  Google Scholar 

  54. Naydenov A, Konova P, Nikolov P, Klingstedt F, Kumar N, Kovacheva D, Stefanov P, Stoyanova R, Mehandjiev D (2008) Catal Today 137:471–474

    Article  CAS  Google Scholar 

  55. Radhakrishnan R, Ohminami Y, Asakura K (2001) J Phys Chem 105:9067–9070

    Article  CAS  Google Scholar 

  56. Konova P, Stoyanova M, Naydenov A, Christoskova St, Mehandjiev D (2006) Appl Catal A Gen 298:109–114

    Article  CAS  Google Scholar 

  57. Yu QS, Cai GQ (1995) Acta Phys Chim Sin 11:516–520

    CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the Environmentally Sustainable Management of Medical Wastes in China (Contract No. C/V/S/10/251), the National Natural Foundation of Zhejiang Province, China (Grant No. Z4080070), and Zhejiang Province Environmental Protection Science Research Plan of China (Grant No. 2011B14).

Author information

Authors and Affiliations

  1. State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Zhejiang University, Zheda Road 38, Hangzhou, 310027, China

    Ru Chen, Dongdong Jin, Hangsheng Yang, Zhaoxia Ma, Fu Liu & Xiaobin Zhang

Authors
  1. Ru Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Dongdong Jin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Hangsheng Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Zhaoxia Ma
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Fu Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Xiaobin Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Hangsheng Yang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chen, R., Jin, D., Yang, H. et al. Ozone Promotion of Monochlorobenzene Catalytic Oxidation Over Carbon Nanotubes-Supported Copper Oxide at High Temperature. Catal Lett 143, 1207–1213 (2013). https://doi.org/10.1007/s10562-013-1059-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-013-1059-6

Keywords

Search

Navigation