Abstract
New WO x –TiO2 photocatalysts were prepared via sol–gel method from tetraisopropyl orthotitanate and WO2. For comparison TiO2 was also prepared by the same method. These photocatalysts were tested for phenol degradation in an aqueous solution under UV irradiation. Experimentally measured OH radicals formation on WO x –TiO2 photocatalysts was quantitatively much higher than on TiO2, what increased their photocatalytic activity towards phenol decomposition. Band gap of the prepared photocatalysts was calculated from the obtained derivatives of UV–Vis/DR spectra and it was observed that E g decreased with increasing calcination temperature in both, TiO2 and WO x –TiO2. This was caused by the improving crystallinity of anatase phase and formation of rutile, which had a lower value of E g than anatase. In general the presence of WO x in TiO2 suppressed transformation of anatase to rutile.
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References
Poulios I, Tsachpinis I (1999) J Chem Technol Biotechnol 74:349
Araña J, Doña-Rodríguez JM, Tello Rendón E, Garriga C, Cabo I, González-Díaz O, Herrera-Melián JA, Pérez-Peña J, Colón G, Navío JA (2003) Appl Catal B 44:161
Song H, Jiang H, Liu X, Meng G (2006) J Photochem Photobiol A 181:421
Shen M, Wu Z, Huang H, Du Y, Zou Z, Yang P (2006) Mater Lett 60:693
Gondal AM, Sayeed MN, Alarfaj A (2007) Chem Phys Lett 445:325
Shifu C, Lei C, Shen G, Gengyu C (2005) Powder Technol 160:198
Li XZ, Li FB, Yang CL, Ge WK (2001) J Photochem Photobiol A 5744:1
Yang H, Shi R, Zhang K, Hu Y, Tang A, Li X (2005) J Alloy Comp 398:200
Xiu Q, Yuan Xiao H, Sheng Li W, Sheng Li W, Qing Na Y, Ping Zhou X (2005) Appl Catal A 290:25
Keller N, Barraud E, Bosc F, Edwards D, Keller V (2007) Appl Catal B 70:423
Bosc F, Edwards D, Keller N, Keller V, Ayral A (2006) Thin Solid Films 495:272
Radecka M, Sobas P, Wierzbicka M, Rekas M (2005) Physica B 364:85
Alemany LJ, Larrubia MA, Jimènez MC (1997) React Kinet Catal Lett 60:41
Guo Y, Quan X, Lu N, Zhano H, Chen S (2007) Environ Sci Technol 41:4422
Ke D, Liu H, Peng T, Liu X, Dei K (2008) Mater Lett 62:447
Komornicki S, Radecka M, Sobaś P (2004) Mater Res Bull 39:2007
Yang H, Zhang D, Wang L (2002) Mater Lett 57:674
Ishibashi K, Fujishima A, Watanabe T, Hashimoto K (2000) Electrochem Commun 2:207
Dai Q, Wang D, Yuan Ch (1998) Supramol Sci 5:469
Tryba B, Toyoda M, Morawski AW, Nonaka R, Inagaki M (2007) Appl Catal B 71:163
Janus M, Morawski AW (2007) Appl Catal B 75:118
Tryba B, Morawski AW, Inagaki M (2003) Appl Catal B 46:203
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This work was supported by the research project from the Ministry of Science and Higher Education Nr COST/299/2006 for 2007–2010.
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The work was presented during the conference ‘Catalysis for Society', Krakow, May 11–15, 2008.
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Piszcz, M., Tryba, B., Grzmil, B. et al. Photocatalytic Removal of Phenol Under UV Irradiation on WO x –TiO2 Prepared by Sol–Gel Method. Catal Lett 128, 190–196 (2009). https://doi.org/10.1007/s10562-008-9730-z
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DOI: https://doi.org/10.1007/s10562-008-9730-z