Skip to main content
SpringerLink
Log in

Partial Oxidation and Dry Reforming of Methane Over Ca/Ni/K(Na) Catalysts

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Partial oxidation and dry reforming of methane to synthesis gas over Ca/Ni/K(Na) catalysts have been studied. Effects of temperature, pressure, and oxygen/methane ratios on catalytic activity, selectivity, and carbon formation have been determined. Also reforming of 13CH4 in the presence of CO2 and Temperature-Programmed Oxidation (TPO) of deposited carbon after the reaction indicated that both methane and CO2 contribute to carbon formation. The TPO of deposited carbon on Ca/Ni/K catalyst showed that the catalyst consumed a significant amount of oxygen, only a fraction of which was consumed by carbon species on the surface, indicating that the surface oxygen plays a significant role in oxidizing and removing carbon species from the catalyst surfaces

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. H.-F. Liu K.Y. Liu R.E. Johnson J.H. Lunsford (1984) J. Am. Soc. 106 117 Occurrence Handle10.1021/ja00313a024

    Article  Google Scholar 

  2. A. Shamsi K. Zahir (1989) Energy & Fuel 3 727 Occurrence Handle1:CAS:528:DyaL1MXlvFOhtrs%3D Occurrence Handle10.1021/ef00018a012

    Article  CAS  Google Scholar 

  3. P. Pereira S. Lee G. Somorjai H. Heinemann (1991) Catal. Lett. 9 395 Occurrence Handle10.1007/BF00764831

    Article  Google Scholar 

  4. A. Shamsi (1994) Catal. Lett. 25 97 Occurrence Handle1:CAS:528:DyaK2MXktFyr Occurrence Handle10.1007/BF00815419

    Article  CAS  Google Scholar 

  5. K. Tomishige Y.-G Chen K. Fujimoto (1999) J. Catal. 181 91 Occurrence Handle1:CAS:528:DyaK1MXltlaqtQ%3D%3D Occurrence Handle10.1006/jcat.1998.2286

    Article  CAS  Google Scholar 

  6. L. Xiancai W. Min L. Zhihua H. Fei (2005) Appl. Catal. A: General 290 81 Occurrence Handle10.1016/j.apcata.2005.05.021 Occurrence Handle1:CAS:528:DC%2BD2MXmvVWms7c%3D

    Article  CAS  Google Scholar 

  7. T. Sperle D. Chen R. Lødeng A. Holmen (2005) Appl. Catal. A: General 282 195 Occurrence Handle1:CAS:528:DC%2BD2MXhslehsb8%3D Occurrence Handle10.1016/j.apcata.2004.12.011

    Article  CAS  Google Scholar 

  8. W.-Z. Sun G.-Q. Jin X.-Y. Guo (2005) Catal. Commun. 6 135 Occurrence Handle1:CAS:528:DC%2BD2MXksVWktg%3D%3D Occurrence Handle10.1016/j.catcom.2004.11.013

    Article  CAS  Google Scholar 

  9. S.M. Stagg D.E. Resasco (1998) Stud. Surf. Sci. Catal. 119 813 Occurrence Handle1:CAS:528:DyaK1cXms1Glt7w%3D Occurrence Handle10.1016/S0167-2991(98)80532-6

    Article  CAS  Google Scholar 

  10. S.M. Stagg E. Romeo C. Padro D.E. Resasco (1998) J. Catal. 178 137 Occurrence Handle1:CAS:528:DyaK1cXls1ShtLY%3D Occurrence Handle10.1006/jcat.1998.2146

    Article  CAS  Google Scholar 

  11. L. Wenying F. Jie X. Kechang (1998) React. Kinet. Lett. 64 IssueID2 381–388

    Google Scholar 

  12. B.J. Wood K.M. Sancier (1984) Catal. Rev. Sci. Eng. 26 IssueID2 233 Occurrence Handle1:CAS:528:DyaL2cXkslGgtL4%3D

    CAS  Google Scholar 

  13. T. Wigmans, Ph.D. Thesis, University of Amsterdam (1982).

  14. H.S. Bengaard I. Alstrup I. Chorkendorff S. Ullmann J.R. Rostrup-Nielsen J.K. Norskov (1999) J. Catal. 187 238 Occurrence Handle1:CAS:528:DyaK1MXlvFagsLo%3D Occurrence Handle10.1006/jcat.1999.2612

    Article  CAS  Google Scholar 

  15. M. Ito T. Tagawa S. Goto (1999) Appl. Catal. 184 73 Occurrence Handle1:CAS:528:DyaK1MXjsFKntbw%3D Occurrence Handle10.1016/S0926-860X(99)00082-4

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. U.S. Department of Energy, National Energy Technology Laboratory (NETL), P.O. Box 880, 3610 Collins Ferry Road, Morgantown, WV, 26505-0880

    Abolghasem Shamsi

Authors
  1. Abolghasem Shamsi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Abolghasem Shamsi.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shamsi, A. Partial Oxidation and Dry Reforming of Methane Over Ca/Ni/K(Na) Catalysts. Catal Lett 109, 189–193 (2006). https://doi.org/10.1007/s10562-006-0076-0

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-006-0076-0

Keywords

Search

Navigation