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Reactivity of Aluminum Spinels in the Ethanol Steam Reforming Reaction

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Abstract

Aluminum spinels, MAl2O4 with M2+ = Cu, Zn or Ni, were prepared by citrate method and its reactivity in the ethanol steam reforming reaction was studied at 500 °C. They were characterized by TG, BET surface area, XRD, FTIR and TPR techniques. The catalytic behavior depended strongly on the nature of divalent metal which determines the physico-chemical properties of samples. In all cases, very active catalysts with a complete ethanol conversion were reached. Hydrogen yield follows the order of ZnAl > NiAl > CuAl.

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Authors and Affiliations

  1. Instituto de Investigaciones en Tecnología Química - (UNSL-CONICET), Chacabuco y Pedernera, 5700, San Luis, Argentina

    M. Noelia Barroso, Manuel F. Gomez, Luis A. Arrúa & M. Cristina Abello

Authors
  1. M. Noelia Barroso
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  2. Manuel F. Gomez
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  3. Luis A. Arrúa
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  4. M. Cristina Abello
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Correspondence to M. Cristina Abello.

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Barroso, M.N., Gomez, M.F., Arrúa, L.A. et al. Reactivity of Aluminum Spinels in the Ethanol Steam Reforming Reaction. Catal Lett 109, 13–19 (2006). https://doi.org/10.1007/s10562-006-0051-9

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  • DOI: https://doi.org/10.1007/s10562-006-0051-9

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