Skip to main content
SpringerLink
Log in

Characteristics and catalytic activity of platinum reforming catalysts based on aluminum oxide modified by organic acids

  • Catalysis in Petroleum Refining Industry
  • Published:
Catalysis in Industry Aims and scope Submit manuscript

Abstract

The effect of treating aluminum oxide with organic acids (acetic acid, oxalic acid) on the dispersity, composition, and catalytic properties of the platinum sites of reforming catalysts is investigated. It is established that due to the high number of support defects, a Pt/О х -Al2O3 sample prepared on the basis of aluminum oxide treated with oxalic acid solution has the the highest activity. The role the acid modification of a support plays in the formation of charged atoms of platinum, resulting in an increase of catalytic activity, is established.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Mang, Th., Breitscheidel, B., Polanek, P., and Knözinger, H., Appl. Catal., A, 1993, vol. 106, no. 2, pp. 239–258.

    Article  CAS  Google Scholar 

  2. Spieker, W.A. and Regalbuto, J.R., Chem. Eng. Sci., 2001, vol. 56, no. 11, pp. 3491–3504.

    Article  CAS  Google Scholar 

  3. Spieker, W.A., Liu, J., Hao, X., Miller, J.T., Kropf, A.J., and Regalbuto, J.R., Appl. Catal., A, 2003, vol. 243, no. 1, pp. 53–66.

    Article  CAS  Google Scholar 

  4. Shelimov, B., Lambert, J.-F., Che, M., and Didillon, B., J. Am. Chem. Soc., 1999, vol. 121, no. 3, pp. 545–556.

    Article  CAS  Google Scholar 

  5. Shelimov, B., Lambert, J.-F., Che, M., and Didillon, B., J. Catal., 1999, vol. 185, no. 2, pp. 462–478.

    Article  CAS  Google Scholar 

  6. Shelimov, B.N., Lambert, J.-F., Che, M., and Didillon, B., J. Mol. Catal. A: Chem., 2000, vol. 158, no. 1, pp. 91–99.

    Article  CAS  Google Scholar 

  7. Marceau, E., Carrier, X., and Che, M., in Synthesis of Solid Catalysts, de Jong, K.P., Ed., Weinheim: Wiley-VCH, 2009, pp. 59–82.

  8. Lygin, V.I., Zh. Fiz. Khim., 2004, vol. 78, no. 8, pp. 1469–1474.

    CAS  Google Scholar 

  9. Lamberov, A.A., Romanova, R.G., Shmelev, I.G., and Sopin, V.F., Russ. J. Appl. Chem., 2002, vol. 75, no. 3, pp. 396–401.

    Article  CAS  Google Scholar 

  10. Barrett, E.P., Joyner, L.G., and Halenda, P.P., J. Am. Chem. Soc., 1951, vol. 73, no. 1, pp. 373–380.

    Article  CAS  Google Scholar 

  11. Belyi, A.S., Kiryanov, D.I., Smolikov, M.D., Zatolokina, E.V., Udras, I.E., and Duplyakin, V.K., React. Kinet. Catal. Lett., 1994, vol. 53, no. 1, pp. 183–189.

    Article  CAS  Google Scholar 

  12. Wang, H., Fan, Y., Shi, G., Liu, H., and Bao, X., J. Catal., 2008, vol. 260, no. 1, pp. 119–127.

    Article  CAS  Google Scholar 

  13. Zhang, S. and Rasmuson, A.C., CrystEngComm, 2012, vol. 14, pp. 4644–4655.

    Article  CAS  Google Scholar 

  14. Elwardany, A., Nasir, E.F., Es-sebbar, Et., and Farooq, A., Proc. Combust. Inst., 2015, vol. 35, no. 1, pp. 429–436.

    Article  CAS  Google Scholar 

  15. Lieske, H., Lietz, G., Spindler, H., and Völter, J., J. Catal., 1983, vol. 81, no. 1, pp. 8–16.

    Article  CAS  Google Scholar 

  16. Belskaya, O.B., Duplyakin, V.K., and Likholobov, V.A., Smart Nanocompos., 2011, vol. 1, no. 2, pp. 99–133.

    Google Scholar 

  17. Kwak, J.H., Hu, J., Mei, D., Yi, C.-W., Kim, D.H., Peden, C.H.F., Allard, L.F., and Szanyi, J., Science, 2009, vol. 325, no. 5948, pp. 1670–1673.

    Article  CAS  Google Scholar 

  18. Mei, D., Kwak, J.H., Hu, J.Z., Cho, S.J., Szanyi, J., Allard, L.F., and Peden, C.H.F., J. Phys. Chem. Lett., 2010, vol. 1, no. 18, pp. 2688–2691.

    Article  CAS  Google Scholar 

  19. Belyi, A.S., Kinet. Catal., 2008, vol. 49, no. 4, pp. 562–567.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Hydrocarbons Processing, Siberian Branch, Russian Academy of Sciences, Omsk, 644040, Russia

    V. Yu. Tregubenko, I. E. Udras, T. I. Gulyaeva & A. S. Belyi

  2. Omsk State Technical University, Omsk, 644050, Russia

    V. Yu. Tregubenko & A. S. Belyi

Authors
  1. V. Yu. Tregubenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. E. Udras
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. I. Gulyaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. S. Belyi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. Yu. Tregubenko.

Additional information

Original Russian Text © V.Yu. Tregubenko, I.E. Udras, T.I. Gulyaeva, A.S. Belyi, 2017, published in Kataliz v Promyshlennosti.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Tregubenko, V.Y., Udras, I.E., Gulyaeva, T.I. et al. Characteristics and catalytic activity of platinum reforming catalysts based on aluminum oxide modified by organic acids. Catal. Ind. 9, 317–322 (2017). https://doi.org/10.1134/S2070050417040110

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070050417040110

Keywords

Search

Navigation