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Improved resistance against coke deposition of titania supported cobalt and nickel bimetallic catalysts for carbon dioxide reforming of methane

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Abstract

The catalytic behavior of bi-metallic Co–Ni/TiO2 catalysts for CO2 reforming of CH4 to synthesis gas was investigated under atmospheric pressure with a particular attention to carbon deposition. The catalysts with optimized Co/Ni ratios showed high catalytic stability towards the reaction with very little amount of deposited carbon at a wide range of reaction temperature (773–1123 K). The results suggest that adjusting of composition of the active metals (Co and Ni) can kinetically control the elementary steps (formation of carbon species and its removal by oxygen species) of CH4/CO2 reaction.

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References

  1. D.R. Simbeck A.D. Karp R.L. Dickenson (2001) Fuel Process.Technol. 71 139 Occurrence Handle10.1016/S0378-3820(01)00140-0

    Article  Google Scholar 

  2. J.H. Lunsford (2000) Catal.Today 63 165 Occurrence Handle10.1016/S0920-5861(00)00456-9

    Article  Google Scholar 

  3. J.H. Edwards A.M. Maitra (1995) Fuel Process. Technol. 42 269 Occurrence Handle10.1016/0378-3820(94)00105-3

    Article  Google Scholar 

  4. J.R. Rostrup-Nielsen (1984) NoChapterTitle J.R. Anderson M. Boudart (Eds) Catalysis,Science and Technology NumberInSeries5 Springer-Verlag Berlin

    Google Scholar 

  5. G.F. Froment (2000) J. Mol. Catal. A 163 147

    Google Scholar 

  6. M.C.J. Bradford M.A. Vannice (1999) Catal. Rev. Sci. Eng. 41 1 Occurrence Handle10.1081/CR-100101948

    Article  Google Scholar 

  7. J.R.H. Ross A.N.J. Keulen Particlevan M.E.S. Hegarty K. Seshan (1996) Catal. Today 30 193 Occurrence Handle10.1016/0920-5861(96)00035-1

    Article  Google Scholar 

  8. S.C. Tsang J.B. Claridge M.L.H. Green (1995) Catal. Today 23 3 Occurrence Handle10.1016/0920-5861(94)00080-L

    Article  Google Scholar 

  9. K. Seshan and J.A. Lercher, in: Carbon Dioxide: Environmental Issues, J. Paul and C. Pradier (eds.), (The Royal Soc. Chem., Cambridge, 1994) 16.

  10. K. Nagaoka, K. Takanabe and K. Aika, Chem. Commun. (2002) 1006

  11. K. Nagaoka K. Takanabe K. Aika (2003) Appl. Catal. A 255 13 Occurrence Handle10.1016/S0926-860X(03)00631-8

    Article  Google Scholar 

  12. K. Nagaoka K. Takanabe K. Aika (2004) Appl. Catal. A 268 151 Occurrence Handle10.1016/j.apcata.2004.03.029

    Article  Google Scholar 

  13. K. Takanabe K. Nagaoka K. Aika (2005) J. Catal. 229 609

    Google Scholar 

  14. E. Ruckenstein H.Y. Wang (2002) J. Catal. 205 289 Occurrence Handle10.1006/jcat.2001.3458

    Article  Google Scholar 

  15. H.P. Klug L.E. Alexander (1974) X-ray Diffraction Procedures Wiley NewYork

    Google Scholar 

  16. K. Takanabe, K. Nagaoka, K. Nariai and K. Aika, submitted

  17. T.V. Choudhary D.W. Goodman (1999) Catal. Lett. 59 93 Occurrence Handle10.1023/A:1019008202235

    Article  Google Scholar 

  18. T. Koerts M.J.A.G. Deelen R. Santen Particlevan (1992) J. Catal. 138 101 Occurrence Handle10.1016/0021-9517(92)90010-F

    Article  Google Scholar 

  19. Y.-G. Chen O. Yamazaki K. Tomishige K. Fujimoto (1996) Catal. Lett. 39 91 Occurrence Handle10.1007/BF00805578

    Article  Google Scholar 

  20. Y.-G. Chen K. Tomishige K. Yokoyama K. Fujimoto (1997) Appl. Catal. A 165 335 Occurrence Handle10.1016/S0926-860X(97)00216-0

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Environmental Chemistry and Engineering, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama, 226-8502, Japan

    Kazuhiro Takanabe & Ken-ichi Aika

  2. CREST, JST (Japan Science and Technology Corporation), Japan

    Katsutoshi Nagaoka & Ken-ichi Aika

  3. Department of Applied Chemistry, Faculty of Engineering, Oita University, Dannoharu 700, Oita, 870-1192, Japan

    Katsutoshi Nagaoka

Authors
  1. Kazuhiro Takanabe
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  2. Katsutoshi Nagaoka
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  3. Ken-ichi Aika
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Correspondence to Ken-ichi Aika.

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Takanabe, K., Nagaoka, K. & Aika, Ki. Improved resistance against coke deposition of titania supported cobalt and nickel bimetallic catalysts for carbon dioxide reforming of methane. Catal Lett 102, 153–157 (2005). https://doi.org/10.1007/s10562-005-5848-4

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  • DOI: https://doi.org/10.1007/s10562-005-5848-4

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