Abstract
Zirconia supported nickel and cobalt-nickel bimetallic catalysts were prepared and characterized for various physico-chemical properties. The hydrogenation of carbon monoxide was studied over these catalysts in the pressure range of 101.3–1654kPa, temperature range of 513–533K, weight hourly space velocity range of 8–14h−1 and H2/CO mole ratio of 2. Catalysts containing both Co and Ni were found to give higher C5+ hydrocarbons selectivity compared to that containing only Ni. A maximum C5+ hydrocarbons selectivity of 55wt% was obtained at 655kPa pressure, 523K and 9.6h−1 of WHSV with catalyst containing 4.03wt% Co and 2.64wt% Ni. The C2 and C3 olefin contents of the products decreased with increase in pressure. Improved deactivation behavior of the catalysts was observed when operated at high pressure.
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References
M. E. Dry, Appl. Catal. A. Gen. 189 (1999) 185.
G. L. Ott, T. Fleisch and W. N. Delgass, J. Catal. 60 (1979) 394.
R. L. Verma, L. Dan-Chu, J. F. Mathews and N. N. Bakhshi, Can. J. Chem. Eng. 63 (1985) 72.
D. J. Duvenhage and N. J. Coville, Appl. Catal. A 153 (1997) 43.
E. S. Colley, R. G. Copperthwaite, G. J. Hutchings, G. A. Foulds and N. J. Coville, Appl. Catal. 84 (1992) 1.
H. Chen and A. A. Adesina, Appl. Catal. 112 (1994) 87.
M. E. Cooper and J. Frost, Appl. Catal. 57 (1990) L5.
T. Ishihara, K. Eguchi and H. Arai, Appl. Catal. 30 (1987) 225.
K. Jothirmurugason and S. K. Gangwal, Ind. Eng. Chem. Res. 37 (1998) 1181.
L. Fan, M. Miyauchi and K. Fujimoto, J. Jpn. Pet. Inst. 40 (1997) 298.
H. C. Long, M. L. Turner, P. Fomasiero, J. Kaspar, M. Graziani and P. M. Maitlis, J. Catal. 167 (1997) 172.
C. L. Bianchi and V. Ragaini, J. Catal. 168 (1997) 70.
V. Ragaini, R. Carli, C. L. Bianchi, D. Lorenzetti and G. Vergani, Appl. Catal. A 139 (1996) 17.
V. Ragaini, R. Carli, C. L. Bianchi, D. Lorenzetti, G. Predieri and P. Moggi, Appl. Catal. A 139 (1996) 31.
Y. W. Chen and W. J. Wang, Catal. Today 6 (1989) 105.
L. A. Bruce, M. Hoang, A. E. Hughes and T. W. Tumey, Appl. Catal. A 100 (1993) 51.
A. R. Belambe, R. Oukaci and J. Goodwin, J. Catal. 166 (1997) 8.
T. E. Hoost and J. G. Goodwin, J. Catal. 137 (1992) 22.
E. Kikuchi, M. Matsumoto, T. Takahashi, A. Machino and Y. Morita, Appl. Catal. 10 (1984) 251.
M. A. Vannice and R. L. Garten, J. Catal. 63 (1980) 255.
L. A. Bruce, G. J. Hope and J. F. Mathews, Appl. Catal. 9 (1984) 351.
S. Fujita, N. Hiyoshi and N. Takezawa, Appl. Catal. A 185 (1999) 323.
J. W. Jenkins, B. D. McNicol and S. D. Robertson, Chem. Tech. 7 (1977) 316.
R. L. Varma, J. F. Mathew and N. N. Bakhshi in: Frontiers in Chemical Reaction Engineering, L. K. Doraiswamy, R. A. Mashelkar eds, Vol. II, (1984) 118.
T. Paryjczak, J. Rynkowski and S. Karski, J. Chromatogr. 188 (1980) 254.
C. H. Bartholomew and R. B. Pannell, J. Catal. 65 (1980) 390.
H. H. Stroch, N. Golumbic and R. B. Anderson, The Fischer –Tropsch and Related Synthesis, (John Wiley & Sons, 1952) 323.
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Das, P.C., Pradhan, N.C., Dalai, A.K. et al. Carbon Monoxide Hydrogenation over Zirconia Supported Ni and Co-Ni Bimetallic Catalysts. Catalysis Letters 98, 153–160 (2004). https://doi.org/10.1007/s10562-004-7931-7
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DOI: https://doi.org/10.1007/s10562-004-7931-7