Abstract
This review summarizes recent progress of the robust and smart hydrogels prepared from natural polymers including polysaccharides, proteins, etc. These hydrogels exhibit outstanding mechanical properties due to their nanofibrous aggregated microstructures and special crosslinking networks. Furthermore, these hydrogels show some smart stimuli-responsive behaviors triggered by pH, temperature, light, electricity and magnetism. Hopefully, these hydrogels derived from natural polymers with inherent biodegradation and biocompatibility have great application potential in the fields of biomedicine, tissue engineering, soft robots and bio-machine.
Similar content being viewed by others
References
Gong, J.P., Soft Matter, 2010, 6(12): 2583
Mukhopadhyay, P., Fujita, N., Takada, A., Kishida, T., Shirakawa, M. and Shinkai, S., Angew. Chem. Int. Ed., 2010, 49(36): 6338
Ivanenko, Y.P., Poppele, R.E. and Lacquaniti, F., J. Physiol., 2004, 556(1): 267
Hammock, M.L., Chortos, A., Tee, B.C.K., Tok, J.B.H. and Bao, Z., Adv. Mater., 2013, 25(42): 5997
Gan, Y., Yin, J. and Jiang, X., J. Mater. Chem. A, 2014, 2(43): 18574
Ionov, L., Mater. Today, 2014, 17(10): 494
Takashima, Y., Hatanaka, S., Otsubo, M., Nakahata, M., Kakuta, T., Hashidzume, A., Yamaguchi, H. and Harada, A., Nat. Commun., 2012, 3: 1270
Hasnat Kabir, M., Hazama, T., Watanabe, Y., Gong, J., Murase, K., Sunada, T. and Furukawa, H., J. Taiwan Inst. Chem. E, 2014, 45(6): 3134
Sun, J.Y., Keplinger, C., Whitesides, G.M. and Suo, Z., Adv. Mater., 2014, 26(45): 7608
Kerin, A.J., Wisnom, M.R. and Adams, M.A., P. I. Mech. Eng. H, 1998, 212(4): 273
Bastide, J. and Leibler, L., Macromolecules, 1988, 21(8): 2647
Furukawa, H., Horie, K., Nozaki, R. and Okada, M., Phys. Rev. E, 2003, 68(3): 031406
Hassan, C.M. and Peppas, N.A., Macromolecules, 2000, 33(7): 2472
Okumura, Y. and Ito, K., Adv. Mater., 2001, 13(7): 485
Sakai, T., Matsunaga, T., Yamamoto, Y., Ito, C., Yoshida, R., Suzuki, S., Sasaki, N., Shibayama, M. and Chung, U.I., Macromolecules, 2008, 41(14): 5379
Haraguchi, K. and Takehisa, T., Adv. Mater., 2002, 14(16): 1120
Cui, W., Ji, J., Cai, Y.F., Li, H. and Ran, R., J. Mater. Chem. A, 2015, 3(33): 17445
Zhang, Y., Song, M., Diao, Y., Li, B., Shi, L. and Ran, R., RSC Adv., 2016, 6(113): 112468
Gong, J.P., Katsuyama, Y., Kurokawa, T. and Osada, Y., Adv. Mater., 2003, 15(14): 1155
Hu, J., Kurokawa, T., Nakajima, T., Sun, T.L., Suekama, T., Wu, Z.L., Liang, S.M. and Gong, J.P., Macromolecules, 2012, 45(23): 9445
Sun, T.L., Kurokawa, T., Kuroda, S., Ihsan, A.B., Akasaki, T., Sato, K., Haque, M.A., Nakajima, T. and Gong, J.P., Nat. Mater., 2013, 12(10): 932
Zhao, Y., Nakajima, T., Yang, J.J., Kurokawa, T., Liu, J., Lu, J., Mizumoto, S., Sugahara, K., Kitamura, N. and Yasuda, K., Adv. Mater., 2014, 26(3): 436
Ladet, S., David, L. and Domard, A., Nature, 2008, 452(7183): 76
Shen, W., Zhang, K., Kornfield, J.A. and Tirrell, D.A., Nat. Mater., 2006, 5(2): 153
Chang, C., Duan, B., Cai, J. and Zhang, L., Eur. Polym. J., 2010, 46(1): 92
Murakami, K., Aoki, H., Nakamura, S., Nakamura, S., Takikawa, M., Hanzawa, M., Kishimoto, S., Hattori, H., Tanaka, Y. and Kiyosawa, T., Biomaterials, 2010, 31(1): 83
Zheng, W.J., An, N., Yang, J.H., Zhou, J. and Chen, Y.M., ACS Appl. Mater. Interfaces, 2015, 7(3): 1758
Chen, Q., Zhu, L., Zhao, C., Wang, Q. and Zheng, J., Adv. Mater., 2013, 25(30): 4171
Guo, H., Zhang, J., Xu, T., Zhang, Z., Yao, J. and Shao, Z., Biomacromolecules, 2013, 14(8): 2733
Cai, J., Zhang, L., Liu, S., Liu, Y., Xu, X., Chen, X., Chu, B., Guo, X., Xu, J. and Cheng, H., Macromolecules, 2008, 41(23): 9345
Chang, C., Chen, S. and Zhang, L., J. Mater. Chem., 2011, 21(11): 3865
Fang, Y., Duan, B., Lu, A., Liu, M., Liu, H., Xu, X. and Zhang, L., Biomacromolecules, 2015, 16(4): 1410
Duan, J., Liang, X., Cao, Y., Wang, S. and Zhang, L., Macromolecules, 2015, 48(8): 2706
He, M., Wang, Z., Cao, Y., Zhao, Y., Duan, B., Chen, Y., Xu, M. and Zhang, L., Biomacromolecules, 2014, 15(9): 3358
Xu, S., Lin, Y., Huang, J., Li, Z., Xu, X. and Zhang, L., J. Mater. Chem. A, 2013, 1(13): 4198
Duan, B., Zheng, X., Xia, Z., Fan, X., Guo, L., Liu, J., Wang, Y., Ye, Q. and Zhang, L., Angew. Chem. Int. Ed., 2015, 54(17): 5152
Fengel, D. and Wegener, G.,“Wood: chemistry, ultrastructure, reactions”, Walter de Gruyter, 1984, p. 613
Khalil, H.A., Davoudpour, Y., Islam, M.N., Mustapha, A., Sudesh, K., Dungani, R. and Jawaid, M., Carbohyd. Polym., 2014, 99: 649
Ifuku, S., Nogi, M., Abe, K., Yoshioka, M., Morimoto, M., Saimoto, H. and Yano, H., Biomacromolecules, 2009, 10(6): 1584
Raabe, D., Romano, P., Sachs, C., Fabritius, H., Al-Sawalmih, A., Yi, S.B., Servos, G. and Hartwig, H., Mater. Sci. Eng. A, 2006, 421(1): 143
Luo, K., Yang, Y. and Shao, Z., Adv. Funct. Mater., 2016, 26(6): 872
Li, Z., Zheng, Z., Yang, Y., Fang, G., Yao, J., Shao, Z. and Chen, X., ACS Sustain. Chem. Eng., 2016, 4(3): 1500
Gong, J.P., Science, 2014, 344(6): 180
Yu, Q.M., Tanaka, Y., Furukawa, H., Kurokawa, T. and Gong, J.P., Macromolecules, 2009, 42(12): 3852
Webber, R.E., Creton, C., Brown, H.R. and Gong, J.P., Macromolecules, 2007, 40(8): 2919
Henderson, K.J., Zhou, T.C., Otim, K.J. and Shull, K.R., Macromolecules, 2010, 43(14): 6193
Dai, X., Zhang, Y., Gao, L., Bai, T., Wang, W., Cui, Y. and Liu, W., Adv. Mater., 2015, 27(23): 3566
Haque, M.A., Kurokawa, T., Kamita, G. and Gong, J.P., Macromolecules, 2011, 44(22): 8916
Tuncaboylu, D.C., Sari, M., Oppermann, W. and Okay, O., Macromolecules, 2011, 44(12): 4997
Sun, J.Y., Zhao, X., Illeperuma, W.R., Chaudhuri, O., Oh, K.H., Mooney, D.J., Vlassak, J.J. and Suo, Z., Nature, 2012, 489(7414): 133
Xu, D., Huang, J., Zhao, D., Ding, B., Zhang, L. and Cai, J., Adv. Mater., 2016, 28(28): 5844
Zhao, D., Huang, J., Zhong, Y., Li, K., Zhang, L. and Cai, J., Adv. Funct. Mater., 2016, 26(34): 6279
Hu, J., Kurokawa, T., Hiwatashi, K., Nakajima, T., Wu, Z.L., Liang, S.M. and Gong, J.P., Macromolecules, 2012, 45: 5218
Hu, J., Hiwatashi, K., Kurokawa, T., Liang, S.M., Wu, Z.L. and Gong, J.P., Macromolecules, 2011, 44(19): 7775
Duan, J., Liang, X., Guo, J., Zhu, K. and Zhang, L., Adv. Mater., 2016, 28(36): 8037
Ma, J., Lee, J., Han, S.S., Oh, K.H., Nam, K.T. and Sun, J.Y., ACS Appl. Mater. Interfaces, 2016, 8(43): 29220
Meng, Z., Smith, M.H. and Lyon, L.A., Colloid Polym. Sci., 2009, 287(3): 277
Bhattacharya, S., Eckert, F., Boyko, V. and Pich, A., Small, 2007, 3(4): 650
Haraguchi, K., Murata, K. and Takehisa, T., Macromolecules, 2011, 45(1): 385
McKee, J.R., Hietala, S., Seitsonen, J., Laine, J., Kontturi, E. and Ikkala, O., ACS Macro Lett., 2014, 3(3): 266
Capadona, J.R., Shanmuganathan, K., Tyler, D.J., Rowan, S.J. and Weder, C., Science, 2008, 319(5868): 1370
Gargava, A., Arya, C. and Raghavan, S.R., ACS Appl. Mater. Interfaces, 2016, 8(28): 18430
Sun, Y.L., Dong, W.F., Yang, R.Z., Meng, X., Zhang, L., Chen, Q.D. and Sun, H.B., Angew. Chem. Int. Ed., 2012, 51(7): 1558
Sidorenko, A., Krupenkin, T., Taylor, A., Fratzl, P. and Aizenberg, J., Science, 2007, 315(5811): 487
Kim, Y.S., Liu, M., Ishida, Y., Ebina, Y., Osada, M., Sasaki, T., Hikima, T., Takata, M. and Aida, T., Nat. Mater., 2015, 14(10): 1002
Motokawa, T., Comp. Biochem. Phys. B, 1994, 109(4): 613
Thurmond, F. and Trotter, J., J. Exp. Biol., 1996, 199(8): 1817
Wilkie, I., J. Exp. Biol., 2002, 205(2): 159
Kong, N., Peng, Q. and Li, H., Adv. Funct. Mater., 2014, 24(46): 7310
Lee, J.B., Peng, S., Yang, D., Roh, Y.H., Funabashi, H., Park, N., Rice, E.J., Chen, L., Long, R., Wu, M. and Luo, D., Nat. Nanotechnol., 2012, 7(12): 816
Chen, S.C., Wu, Y.C., Mi, F.L., Lin, Y.H., Yu, L.C. and Sung, H.W., J. Control. Release, 2004, 96(2): 285
Gong, R., Li, C., Zhu, S., Zhang, Y., Du, Y. and Jiang, J., Carbohyd. Polym., 2011, 85(4): 869
Rafat, M., Li, F., Fagerholm, P., Lagali, N.S., Watsky, M.A., Munger, R., Matsuura, T. and Griffith, M., Biomaterials, 2008, 29(29): 3960
Chang, C., He, M., Zhou, J. and Zhang, L., Macromolecules, 2011, 44(6): 1642
Xu, W., He, X., Zhong, M., Hu, X. and Xiao, Y., RSC Adv., 2015, 5(5): 3157
Huang, Y., Yao, M., Zheng, X., Liang, X., Su, X., Zhang, Y., Lu, A. and Zhang, L., Biomacromolecules, 2015, 16(11): 3499
Shou, K., Huang, Y., Qi, B., Hu, X., Ma, Z., Lu, A., Jian, C., Zhang, L. and Yu, A., J. Tissue. Eng. Regen. M, 2017, DOI: 10.1002/term.2400
Wang, E., Desai, M.S. and Lee, S.W., Nano Lett., 2013, 13(6): 2826
Yu, C., Yuan, P., Erickson, E.M., Daly, C.M., Rogers, J.A. and Nuzzo, R.G., Soft Matter, 2015, 11(4): 7953
Liu, S., Gao, G., Xiao, Y. and Fu, J., J. Mater. Chem. B, 2016, 4(19): 3239
Lee, B.P. and Konst, S., Adv. Mater., 2014, 26(21): 3415
Li, H., Go, G., Ko, S.Y., Park, J.O. and Park, S., Smart Mater. Struct., 2016, 25(2): 027001
Bakarich, S.E., Gorkin, R. and Spinks, G.M., Macromol. Rapid Commun., 2015, 36(12): 1211
Duan, J., Liang, X., Zhu, K., Guo, J. and Zhang, L., Soft Matter, 2017, 13(2): 345
Olsson, R.T., Azizi Samir, M.A., Salazar-Alvarez, G., Belova, L., Strom, V., Berglund, L.A., Ikkala, O., Nogues, J. and Gedde, U.W., Nat. Nanotechnol., 2010, 5(8): 584
Helminger, M., Wu, B., Kollmann, T., Benke, D., Schwahn, D., Pipich, V., Faivre, D., Zahn, D. and Cölfen, H., Adv. Funct. Mater., 2014, 24(21): 3187
Haider, H., Yang, C.H., Zheng, W.J., Yang, J.H., Wang, M.X., Yang, S., Zrinyi, M., Osada, Y., Suo, Z., Zhang, Q., Zhou, J. and Chen, Y.M., Soft Matter, 2015, 11(42): 8253
Shi, X., Zhang, L., Cai, J., Cheng, G., Zhang, H., Li, J. and Wang, X., Macromolecules, 2011, 44(12): 4565
Shi, X., Hu, Y., Tu, K., Zhang, L., Wang, H., Xu, J., Zhang, H., Li, J., Wang, X. and Xu, M., Soft Matter, 2013, 9(42): 10129
Xue, B., Qin, M., Wang, T., Wu, J., Luo, D., Jiang, Q., Li, Y., Cao, Y. and Wang, W., Adv. Funct. Mater., 2016, 26(48): 9053
Author information
Authors and Affiliations
Corresponding author
Additional information
This work was financially supported by the Major Program of National Natural Science Foundation of China (No. 21334005) and the Major International (Regional) Joint Research Project of National Natural Science Foundation of China (No. 21620102004).
Rights and permissions
About this article
Cite this article
Duan, Jj., Zhang, Ln. Robust and smart hydrogels based on natural polymers. Chin J Polym Sci 35, 1165–1180 (2017). https://doi.org/10.1007/s10118-017-1983-9
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10118-017-1983-9