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Silicon-containing poly(p-arylene vinylene)s: Synthesis and photophysics

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Abstract

A series of new silicon-containing poly(p-arylene vinylene)s (PAVs) with anthracene units in the main chain were synthesized by hydrosilylation reaction. The introduction of organosilicon units improved the solubility of the polymers, and the π-π conjugation of polymeric chains was interrupted. These polymers behaved as blue-green light emitters with their fluorescence maximum at 447–499 nm and quantum yields in the range of 0.28–0.30 in solution.

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Authors and Affiliations

  1. Department of Chemistry, School of Science, Beijing Technology and Business University, Beijing, 100048, China

    Shu-hong Li  (李书宏)

  2. Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China

    Lei Fang, Rui Wang & Cai-hong Xu  (徐彩虹)

Authors
  1. Shu-hong Li  (李书宏)
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  2. Lei Fang
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  3. Rui Wang
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  4. Cai-hong Xu  (徐彩虹)
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Corresponding authors

Correspondence to Shu-hong Li  (李书宏) or Cai-hong Xu  (徐彩虹).

Additional information

This work was financially supported by the National Natural Science Foundation of China (Nos. 50673094 and 20774102).

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Li, Sh., Fang, L., Wang, R. et al. Silicon-containing poly(p-arylene vinylene)s: Synthesis and photophysics. Chin J Polym Sci 30, 589–594 (2012). https://doi.org/10.1007/s10118-012-1157-8

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  • DOI: https://doi.org/10.1007/s10118-012-1157-8

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