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Preparation and electrochemical performance of Li3V2(PO4)3/C cathode material by spray-drying and carbothermal method

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Abstract

Composite Li3V2(PO4)3/C cathode material can be synthesized by spray-drying and carbothermal method. The monoclinic-phase Li3V2(PO4)3/C was prepared with the process of double spray drying at 260 °C and subsequent heat treatment at 750 °C for 12 h. The results indicate that the Li3V2(PO4)3/C presents large reversible discharge capacity of 121.9 mA h g−1 and charge capacity of 131.8 mA h g−1 at the current density of C/5, good rate capability with 61.1 mA h g−1 at 20C, and excellent capacity retention rate close to 100% at various current densities in the region of 3.0–4.3 V.

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References

  1. Scrosati B (1995) Nature 373:557

    Article  CAS  Google Scholar 

  2. Whittingham MS (2004) Chem Rev 104:4271

    Article  CAS  Google Scholar 

  3. Grey CP, Dupre N (2004) Chem Rev 104:4493

    Article  CAS  Google Scholar 

  4. Padhi AK, Nanjundaswamy KS, Goodenough JB (1997) J Electrochem Soc 144:1188

    Article  CAS  Google Scholar 

  5. Padhi AK, Nanjundaswamy KS, Masquelier C, Goodenough JB (1997) J Electrochem Soc 144:2581

    Article  CAS  Google Scholar 

  6. Nanjundaswamy KS, Padhi AK, Goodenough JB, Okada S, Ohtsuka H, Arai H, Yamaki J (1996) Solid State Ionics 92:1

    Article  CAS  Google Scholar 

  7. Gaubicher J, Wurm C, Goward G, Masquelier C, Nazar L (2000) Chem Mater 12:3240

    Article  CAS  Google Scholar 

  8. Saidi MY, Barker J, Huang H, Swoyer JL, Adamson G (2003) J Power Sources 119–121:266

    Article  Google Scholar 

  9. Yin SC, Grondey H, Strobel P, Anne M, Nazar LF (2003) J Am Chem Soc 125:10402

    Article  CAS  Google Scholar 

  10. Huang H, Yin SC, Kerr T, Taylor N, Nazar LF (2002) Adv Mater 14:1525

    Article  CAS  Google Scholar 

  11. Chen QQ, Wang JM, Tang Z, He WC, Shao HB, Zhang JQ (2007) Electrochim Acta 52:5251

    Article  CAS  Google Scholar 

  12. Barker J, Saidi MY, Swoyer JL (2003) J Electrochem Soc 150:A684

    Article  CAS  Google Scholar 

  13. Liu SQ, Li SC, Tang LX, Huang KL (2006) Chin J Inorg Chem 22:645

    Google Scholar 

  14. Fu P, Zhao YM, Dong YZ, An XN, Shen GP (2006) J Power Sources 162:651

    Article  CAS  Google Scholar 

  15. Ren MM, Zhou Z, Li YZ, Gao XP, Yan J (2006) J Power Sources 162:1357

    Article  CAS  Google Scholar 

  16. Ren MM, Zhang Z, Gao XP, Peng WX, Wei JP (2008) J Phys Chem C 112:5689

    Article  CAS  Google Scholar 

  17. Li YZ, Zhou Z, Ren MM, Gao XP, Yan J (2006) Electrochim Acta 51:6498

    Article  CAS  Google Scholar 

  18. Li YZ, Zhou Z, Gao XP, Yan J (2007) Electrochim Acta 52:4922

    Article  CAS  Google Scholar 

  19. Chang CX, Xiang JF, Shi XX, Han XY, Yuan LJ, Sun JT (2008) Electrochim Acta 53:2232

    Article  CAS  Google Scholar 

  20. Ju SH, Kang YC (2008) Mater Chem Phys 107:328

    Article  CAS  Google Scholar 

  21. Wu HM, Tu JP, Chen XT, Shi DQ, Zhao XB, Gao GS (2006) Electrochim Acta 51:4148

    Article  CAS  Google Scholar 

  22. Reddy MV, Pecquenard B, Vinatier P, Levasseur A (2007) Electrochem Commun 9:409

    Article  CAS  Google Scholar 

  23. Striebel K, Shim J, Sierra A, Yang H, Song XY, Kostecki R, Mccarthy K (2005) J Power Sources 146:33

    Article  CAS  Google Scholar 

  24. Yin SC, Grondey H, Strobel P, Huang H, Nazar LF (2003) J Am Chem Soc 125:326

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, People’s Republic of China

    Feng Yu, Jingjie Zhang, Yanfeng Yang & Guangzhi Song

  2. Graduate School of Chinese Academy of Sciences, Beijing, 100049, People’s Republic of China

    Feng Yu

Authors
  1. Feng Yu
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  2. Jingjie Zhang
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  3. Yanfeng Yang
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  4. Guangzhi Song
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Correspondence to Jingjie Zhang.

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Yu, F., Zhang, J., Yang, Y. et al. Preparation and electrochemical performance of Li3V2(PO4)3/C cathode material by spray-drying and carbothermal method. J Solid State Electrochem 14, 883–888 (2010). https://doi.org/10.1007/s10008-009-0882-6

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  • DOI: https://doi.org/10.1007/s10008-009-0882-6

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