Abstract
Covariance between J and B parameters and indetermination of the actual symmetry suggest caution in making general statements about their values in FenSn centers. The Fe4S4 3+ case is further complicated by electronic isomerism and lack of information on the actual symmetry. Electronic ground states and relative J and B values are discussed in the light of hyperfine coupling values.
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Received: 12 January 1996 / Accepted: 26 January 1996
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Bertini, I., Luchinat, C. Experimental data and calculated parameters in FeS polymetallic centers in proteins. JBIC 1, 183–185 (1996). https://doi.org/10.1007/s007750050040
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DOI: https://doi.org/10.1007/s007750050040