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Temporal stability of standard potentials of silver–silver chloride reference electrodes

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Abstract

The four-year evolution of standard potential of a silver–silver chloride reference electrode (denoted further in the text as an Ag/AgCl electrode) is presented together with some suggestions for the improvement of pH primary measurement procedure.

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References

  1. Janz GJ (1961) In: Ives DJG, Janz GJ (eds) Reference electrodes. Academic Press, New York

  2. Bates RG, Bower VE (1954) J Res Nat Bur Stand 53:283–290

    Article  CAS  Google Scholar 

  3. Buck RP, Rondinini S, Covington AK, Baucke FGK, Brett CMA, Camoes MF, Milton MJT, Mussini T, Naumann R, Pratt KW, Spitzer P, Wilson GS (2002) Measurement of pH. Definition, standards, and procedures (IUPAC Recommendations 2002). Pure Appl Chem 74:2169–2200

    Article  CAS  Google Scholar 

  4. Bates RG (1973) Determination of pH, 2nd edn. Wiley, New York

    Google Scholar 

  5. Brewer PJ, Brown RJC, Gonzaga FB, Hongyu X, Bing W, Spitzer P, Jakobsen PT, Champion R, Fisicaro P, Stoica D, Ohata M, Vyskocil L, Mariassy M, Pratt K, Monroy M, Reyes A, Kozlowski W, Kardash E, Ivanova D, Camoes MF, Lee H, Hwang E (2011) Report on CCQM-P37.1. Preparation of Ag/AgCl electrodes for Harned cell measurements. http://www.bipm.org/en/committees/cc/ccqm/

  6. Cohen ER, Cvitas T, Frey JG, Holmström B, Kuchitsu K, Marquardt R, Mills I, Pavese F, Quack M, Stohner J, Strauss HL, Takami M, Thor AJ (2008) Quantities, units and symbols in physical chemistry, IUPAC Green Book, 3rd edn. IUPAC & RSC Publishing, Cambridge. http://media.iupac.org/publications/books/gbook/IUPAC-GB3-2ndPrinting-Online-22apr2011.pdf

  7. Vyskočil L, Máriássy M, Mathiasová A, Vospělová A, Werner B, Rivier C, Ivanova D, Hwang E, Kristensen HB, Kuselman I, Pérez Urquiza M, Spitzer P, Nakamura S, Nagyné-Szilágyi ZC (2002) Report on CCQM–P37 Fundamental studies on pH standards

  8. Mariassy M, Pratt K, Spitzer P (2009) Metrologia 46:199–213

    Article  CAS  Google Scholar 

  9. Asakai T, Hioki A (2010) Accred Qual Assur 15:391–399

    Article  CAS  Google Scholar 

  10. Maksimov I, Ohata M, Nakamura S, Hioki A, Chiba K, Spitzer P (2008) Accred Qual Assur 13:381–387

    Article  CAS  Google Scholar 

  11. IUPAC publication (1978) Standard potential of the silver–silver chloride electrode. Pure Appl Chem 50:1701–1706

    Google Scholar 

  12. pH scale of aqueous solutions (OIML Recommendation 54 Edition 1981(E)) http://www.oiml.org/publications/R/R054-e81.pdf

  13. Kristensen HB, Salomon A, Kokholm G (1991) Anal Chem 63:885A–891A

    CAS  Google Scholar 

  14. Yamauchi Y, Hioki A (2008) Accred Qual Assur 13:415–419

    Article  CAS  Google Scholar 

  15. Lito MJG, Camões MF (2009) J Sol Chem 38:1471–1482

    Article  CAS  Google Scholar 

  16. Breitenbach M, Einert P, Moritz M (1983) Metrologische Abhandlungen 3:245–248

    Google Scholar 

  17. Brewer PJ, Brown RJC (2009) Sensors 9:118–130

    Article  CAS  Google Scholar 

  18. Brown RJC, Brewer PJ, Brett DJL (2009) Accred Qual Assur 14:139–145

    Article  CAS  Google Scholar 

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Acknowledgments

We gratefully acknowledge Dr. Petra Spitzer from Physikalisch-Technische Bundesanstalt, Germany, for her valuable comments to the text of the manuscript.

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Correspondence to Igor Maksimov.

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Maksimov, I., Ohata, M., Asakai, T. et al. Temporal stability of standard potentials of silver–silver chloride reference electrodes. Accred Qual Assur 17, 529–533 (2012). https://doi.org/10.1007/s00769-012-0913-3

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  • DOI: https://doi.org/10.1007/s00769-012-0913-3

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