Skip to main content
Log in

PGE reefs as an in situ crystallization phenomenon: the Nadezhda gabbronorite body, Lukkulaisvaara layered intrusion, Fennoscandian Shield, Russia

  • Published:
Mineralogy and Petrology Aims and scope Submit manuscript

Summary

The 100 m thick and 700 m long Nadezhda sill-like gabbronorite body, emplaced in the mafic-ultramafic Lukkulaisvaara layered intrusion, is associated with Cu-Ni-PGE mineralization that is mostly confined to mottled anorthosites developed from host gabbronorites and norites along the margin of the entire body. PGE and Au show distinct positive correlation with Cu, Ni and S suggesting that the noble metals are mainly controlled by sulphides. A mineralized layer about 1 m thick contains on average 0.74 wt.% S, 1.77 ppm Pt and 7.96 ppm Pd. Marginal location of PGE-rich sulphides and their absence in the Nadezhda body suggest that the mineralizing process must have been gravity-independent and not related to the bulk saturation of the magma in sulphides. We propose that the Nadezhda Cu-Ni-PGE mineralization formed as a result of local sulphide saturation that was achieved in situ at the margins as a result of the flux of ore-bearing fluids from the interior of the body towards its margins. The sulphides became PGE-rich due to interaction with a large volume of ore-bearing fluids that were introduced into the Nadezhda body during a juvenile stage of its development as a conduit through which a large volume of magma has passed on its way to the main chamber.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Alapieti TT, Lahtinen JJ (2002) Platinum-group element mineralization in layered intrusions of Northern Finland and the Kola Peninsular, Russia. In: Cabri LJ (ed) The geology, geochemistry, mineralogy and mineral beneficiation of platinum-group elements. Canadian Institute of Mining, Metallurgy and Petroleum, Spec, Vol. 54, pp 507–546

  • C Ballhaus P Sylvester (2000) ArticleTitleNoble metal enrichment processes in the Merensky reef, Bushveld Complex J Petrol 44 545–561 Occurrence Handle10.1093/petrology/41.4.545

    Article  Google Scholar 

  • CG Ballhaus M Cornelius EF Stumpfl (1988) ArticleTitleThe upper critical zone of the Bushveld Complex and the origin of Merensky-type ores – a discussion Econ Geol 83 1082–1091

    Google Scholar 

  • Barkov AY (1992) Aspects of petrology and geochemistry of the Lukkulaisvaara and Kivakka layered intrusions, Russian Karelia. Ph.D. thesis, Russian Academy of Sciences, IGEM, Moscow, Russia (in Russian)

  • AY Barkov YE Savchenko AA Zhangurov (1995) ArticleTitleFluid migration and its role in the formation of platinum-group minerals: evidence from the Imandrovsky and Lukkulaisvaara layered intrusions, Russia Mineral Petrol 54 249–260 Occurrence Handle10.1007/BF01162864

    Article  Google Scholar 

  • AY Barkov YP Men’shikov VD Begizov AI Lednev (1996) ArticleTitleOulankite, a new platinum-group mineral from the Lukkulaisvaara layered intrusion, northern Karelia, Russia Eur J Mineral 8 311–316

    Google Scholar 

  • AY Barkov RF Martin KVO Laajoki TT Alapieti MJ Iljina (1999) ArticleTitleParagenesis and origin of staurolite from a palladium-rich gabbronorite: an unusual occurrence from the Lukkulaisvaara layered intrusion, Russian Karelia N Jahrb Mineral Abh 175 191–222

    Google Scholar 

  • AY Barkov RF Martin M Tarkian G Poirier Y Thibault (2001) ArticleTitlePd-Ag tellurides from a Cl-rich environment in the Lukkulaisvaara layered intrusion, northern Russian Karelia Can Mineral 39 639–653 Occurrence Handle10.2113/gscanmin.39.2.639

    Article  Google Scholar 

  • AY Barkov ME Fleet RF Martin M Tarkian (2004) ArticleTitleCompositional variations in oulankaite and a new series of argentoan oulankaite from the Lukkulaisvaara layered intrusion, northern Russian Karelia Can Mineral 42 439–454 Occurrence Handle10.2113/gscanmin.42.2.439

    Article  Google Scholar 

  • SJ Barnes IH Campbell (1988) ArticleTitleRole of late magmatic fluids in Merensky-type platinum deposits: a discussion Geology 16 488–491 Occurrence Handle10.1130/0091-7613(1988)016<0488:ROLMFI>2.3.CO;2

    Article  Google Scholar 

  • SJ Barnes WD Maier (2002a) ArticleTitlePlatinum-group element and microstructures of normal Merensky Reef from Impala Platinum Mines, Bushveld Complex J Petrol 43 103–128 Occurrence Handle10.1093/petrology/43.1.103

    Article  Google Scholar 

  • Barnes SJ, Maier WD (2002b) Platinum-group element distributions in the Rustenburg Layered Suite of the Bushveld Complex, South Africa. In: Cabri LJ (ed) The geology, geochemistry, mineralogy and mineral beneficiation of platinum-group elements. Canadian Institute of Mining, Metallurgy and Petroleum, Spec, Vol. 54, pp 431–458

  • NI Bezmen M Asif GE Brügmann IM Romanenko AJ Naldrett (1994) ArticleTitleDistribution of Pd, Rh, Ru, Ir, Os, Os, and Au between sulfide and silicate metals Geochim Cosmochim Acta 58 1251–1260 Occurrence Handle10.1016/0016-7037(94)90379-4

    Article  Google Scholar 

  • AE Boudreau (1995) ArticleTitleSome geochemical considerations of platinum-group element exploration in layered intrusions Expl Min Geol 4 215–225

    Google Scholar 

  • AE Boudreau IS McCallum (1986) ArticleTitleInvestigations of the Stillwater Complex: III. The Picket Pin Pt/Pd deposit Econ Geol 81 1953–1975

    Google Scholar 

  • AE Boudreau IS McCallum (1992) ArticleTitleInfiltration metasomatism in layered intrusions – an example from the Stillwater Complex, Montana J Vol Geoth Res 52 171–183 Occurrence Handle10.1016/0377-0273(92)90139-5

    Article  Google Scholar 

  • AE Boudreau EA Mathez IS McCallum (1986) ArticleTitleHalogen geochemistry of the Stillwater and Bushveld Complexes: evidence for transport of the platinum-group elements by Cl-rich fluids J Petrol 27 967–986

    Google Scholar 

  • AE Boudreau WP Meurer (1999) ArticleTitleChromatographic separation of the platinum-group elements, gold, base metals and sulphur during degassing of compacted and solidifying igneous crystal pile Contrib Mineral Petrol 134 174–185 Occurrence Handle10.1007/s004100050477

    Article  Google Scholar 

  • Cabri LJ (ed) (2002) The geology, geochemistry, mineralogy and mineral beneficiation of platinum-group elements. Canadian Institute of Mining, Metallurgy and Petroleum, Spec, Vol. 54, p 852

  • IH Campbell (1977) ArticleTitleA study of macro-rhythmic layering and cumulate processes in the Jimberlana Intrusion, Western Australia. Part I: The upper layered series J Petrol 18 183–215

    Google Scholar 

  • IH Campbell AJ Naldrett (1979) ArticleTitleThe influence of silicate:sulfide ratios on the geochemistry of magmatic sulfides Econ Geol 76 1503–1506

    Google Scholar 

  • IH Campbell AJ Naldrett SJ Barnes (1983) ArticleTitleA model for the origin of platinum-rich sulphide horizons in the Bushveld and Stillwater complexes J Petrol 24 133–165

    Google Scholar 

  • RG Cawthorn (1999a) ArticleTitlePlatinum-group element mineralization in the Bushveld Complex – a critical reassessment of geochemical models S Afr J Geol 102 IssueID3 268–281

    Google Scholar 

  • RG Cawthorn (1999b) ArticleTitlePermeability of the footwall cumulates to the Merensky Reef, Bushveld Complex S Afr J Geol 102 IssueID3 293–310

    Google Scholar 

  • RG Cawthorn (1999c) ArticleTitleGeological models for platinum-group metal mineralization in the Bushveld Complex S Afr J Sci 95 490–498

    Google Scholar 

  • RG Cawthorn (2005a) ArticleTitleContrasting sulphide contents of the Bushveld and Sudbury Igneous Complexes Mineral Deposita 40 1–12 Occurrence Handle10.1007/s00126-005-0465-0

    Article  Google Scholar 

  • RG Cawthorn (2005b) ArticleTitlePressure fluctuations and the formation of the PGE-rich Merensky and chromitite reefs, Bushveld Complex Mineral Deposita 40 231–235 Occurrence Handle10.1007/s00126-005-0011-0

    Article  Google Scholar 

  • Cawthorn RG, Merkle RKW, Viljoen MJ (2002) Platinum-group element deposits in the Bushveld Complex, South Africa. In: Cabri LJ (ed) The geology, geochemistry, mineralogy and mineral beneficiation of platinum-group elements. Canadian Institute of Mining, Metallurgy and Petroleum, Spec, Vol. 54, pp 507–546

  • Cawthorn RG, Barnes SJ, Ballhaus C, Malitch KN (2005) Platinum group element, chromite, and vanadium deposits in mafic and ultramafic rocks. Econ Geol 100th Ann Vol. 1905–2005, pp 215–249

  • JA Chamberlain (1967) ArticleTitleSulfides in the Muskox intrusion Can J Earth Sci 4 105–153

    Google Scholar 

  • Crocket JH (2002) Platinum-group element geochemistry of mafic and ultramafic rocks. In: Cabri LJ (ed) The geology, geochemistry, mineralogy and mineral beneficiation of platinum-group elements. Canadian Institute of Mining, Metallurgy and Petroleum, Spec, Vol. 54, pp 177–210

  • ME Fleet T Wu (1993) ArticleTitleVolatile transport of platinum-group elements in sulphide-chloride assemblages at 1000 °C Geochim Cosmochim Acta 57 3519–3531 Occurrence Handle10.1016/0016-7037(93)90136-K

    Article  Google Scholar 

  • VA Glebovitsky VS Semenov BV Belyatsky EV Koptev-Dvornikov NF Pchelintseva BS Kireev (2001) ArticleTitleThe structure of the Lukkulaisvaara intrusion, Oulanka group, Northern Karelia: petrological implications Can Mineral 39 607–637 Occurrence Handle10.2113/gscanmin.39.2.607

    Article  Google Scholar 

  • Grohovskaya TL, Klyunin SF (1994) Processes of concentration of platinum metals in Lukkulaisvaara layered intrusion (northern Karelia). Geology and genesis of PGE deposits. Moscow, Nauka, pp 111–125

  • TL Grohovskaya VV Distler SF Klyunin AA Zakharov IP Laputina (1992) ArticleTitleLow-sulphide platinum group mineralization of the Lukkulaisvaara pluton, northern Karelia Int Geol Rev 34 503–520

    Google Scholar 

  • JJ Hanley T Pettke JE Mungall ETC Spooner (2005) ArticleTitleThe solubility of platinum and gold in NaCl brines at 1.5 kbar, 600 to 800 °C: a laser ablation ICP-MS pilot study of synthetic fluid inclusions Geochim Cosmochim Acta 69 2593–2611 Occurrence Handle10.1016/j.gca.2004.11.005

    Article  Google Scholar 

  • JJ Hemley JP Hunt (1992) ArticleTitleHydrothermal ore-forming processes in the light of studies in rock-buffered systems: II. Some general geologic applications Econ Geol 87 23–43

    Google Scholar 

  • DM Hoatson RR Keays (1989) ArticleTitleFormation of platiniferous sulphide horizons by crystal fractionation and magma mixing in the Munni Munni layered intrusion, west Pilbara block, Western Australia Econ Geol 84 1775–1804 Occurrence Handle10.2113/gsecongeo.84.7.1775

    Article  Google Scholar 

  • M Iljina (1994) ArticleTitleThe Portimo Layered Igneous Complex, with emphasis on diverse sulphide and platinum-group element deposits Acta Universitatis Ouluensis, Series A. Scientiae Rerum Naturalium 258 1–158

    Google Scholar 

  • TN Irvine DW Keith SG Todd (1983) ArticleTitleThe J-M platinum-palladium reef of the Stillwater Complex, Montana: II. Origin by double-diffusive convective magma mixing and implications for the Bushveld Complex Econ Geol 78 1287–1334

    Google Scholar 

  • James RS, Jobin-Bevans S, Easton RM, Wood P, Hrominchuk JL, Keays RR, Peck DC (2002) Platinum-group element mineralization in Paleoproterozoic basic intrusions in Central and Northeastern Ontario, Canada. In: Cabri LJ (ed) The geology, geochemistry, mineralogy and mineral beneficiation of platinum-group elements. Canadian Institute of Mining, Metallurgy and Petroleum, Spec, Vol. 54, pp 339–365

  • Kazanov OV, Prasolov EM, Tokarev IV (2003) He and Ar isotope data on platinum metal mineralization of the Lukkulaisvaara layered intrusion. Proceedings of the 7th Biennial SGA Meeting 5, Soc Geol Appl Mineral Dep, pp 595–598

  • Kazanov OV, Koptev-Dvornikov EV, Berezovskaya NV, Bychkova YaV, Epifanova TA, Pchelintseva NF (2005) The Oulanka (Olanga) Complex and related PGE deposits, Russian Karelia. In: Alapieti TT, Kaukonen RJ (eds) Guidebook to the field excursions. 10th International Platinum Symposium. Oulu University Press, p 31

  • RR Keays IH Campbell (1981) ArticleTitlePrecious metals in the Jimberlana Intrusion, Western Australia: implications for the genesis of platiniferous ores in layered intrusions Econ Geol 76 1118–1141

    Google Scholar 

  • JA Kinnaird A Hutchinson L Schurmann PAM Nex R Lange (2005) ArticleTitlePetrology and mineralization of the southern Platreef: northern limb of the Bushveld Complex, South Africa Mineral Deposita 40 576–597 Occurrence Handle10.1007/s00126-005-0023-9

    Article  Google Scholar 

  • V Kress (1997) ArticleTitleMagmatic mixing as a source for Pinatubo sulfur Nature 389 591–593 Occurrence Handle10.1038/39299

    Article  Google Scholar 

  • Latypov RM, Chistyakova SYu, Alapieti TT (2007) Fine-grained mafic bodies as preserved portions of magma replenishing layered intrusions: the Nadezhda gabbronorite body, Lukkulaisvaara layered intrusion, Fennoscandian Shield, Russia. Mineral Petrol (epub ahead of print)

  • WD Maier (2005) ArticleTitlePlatinum-group element (PGE) deposits and occurrences: mineralization styles, genetic concepts, and exploration criteria J Afr Earth Sci 41 IssueID3 165–191 Occurrence Handle10.1016/j.jafrearsci.2005.03.004

    Article  Google Scholar 

  • WD Maier SJ Barnes (1999) ArticleTitlePlatinum-group elements in silicate rocks of the lower, critical and main zones at union section, Western Bushveld Complex J Petrol 40 1647–1671 Occurrence Handle10.1093/petrology/40.11.1647

    Article  Google Scholar 

  • EA Mathez (1995) ArticleTitleMagmatic metasomatism and formation of the Merensky Reef, Bushveld Complex Contrib Mineral Petrol 119 277–286 Occurrence Handle10.1007/BF00307287

    Article  Google Scholar 

  • EA Mathez RH Hunter R Kinzler (1997) ArticleTitlePetrologic evolution of partially molten cumulate: the Atoc section of the Bushveld Complex Contrib Mineral Petrol 129 20–34 Occurrence Handle10.1007/s004100050320

    Article  Google Scholar 

  • I McDonald DA Holwell PEG Armitage (2005) ArticleTitleGeochemistry and mineralogy of Platreef and “Critical Zone” of the northern lobe of the Bushveld Complex, South Africa: implications for Bushveld stratigraphy and the development of PGE mineralization Mineral Deposita 40 526–549 Occurrence Handle10.1007/s00126-005-0018-6

    Article  Google Scholar 

  • Mungall JM (ed) (2005) Exploration for platinum-group element deposits. Mineralogical Association of Canada Short Course Series, Vol. 35, p 512

  • AJ Naldrett (1989) ArticleTitleStratiform PGE deposits in layered intrusions Rev Econ Geol 4 135–166

    Google Scholar 

  • Naldrett AJ, Cameron G, von Gruenewaldt G, Sharp MR (1987) The formation of stratiform PGE deposits in layered intrusions. In: Parsons I (ed) Origin of Igneous Layering. D. Reidel Publishing Company, pp 313–397

  • DC Peck RR Keays RS James PT Chubb SJ Reeves (2001) ArticleTitleControls on the formation of contact-type platinum-group element mineralization in the East Bull Lake intrusion Econ Geol 96 559–581 Occurrence Handle10.2113/96.3.559

    Article  Google Scholar 

  • Prendergast MD, Keyas RR (1989) Controls of platinum-group element mineralization and the origin of the PGE-rich Main Sulphide Zone in the Wedza Subchamber of the Great Dyke, Zimbabwe: implications for the genesis of, and exploration for, stratiform PGE mineralization in layered intrusions. In: Prendergast MD, Jones MJ (eds) Magmatic sulphides – the Zimbabwe Volume. The Institution of Mining and Metallurgy, London, pp 43–69

  • D Schissel AA Tsvetkov FP Mitrofanov AU Korchagin (2002) ArticleTitleBasal platinum-group element mineralization in the Federova Pansky layered mafic intrusion, Kola Peninsula, Russia Econ Geol 97 1657–1677 Occurrence Handle10.2113/97.8.1657

    Article  Google Scholar 

  • RN Scoon B Teigler (1994) ArticleTitlePlatinum-group element mineralization in the Critical Zone of the Western Bushveld Complex: I. Sulphide poor-chromitites below the UG-2 Econ Geol 89 1094–1121

    Google Scholar 

  • VS Semenov BV Belyatsky AB Koltsov NV Kotov OA Yakovleva NV Rudashevsky NF Pchelintseva (1997) ArticleTitleMetasomatites and related PGE mineralization of the Lukkulaisvaara layered complex, Olanga group of intrusions, northern Karelia Petrology 5 121–140

    Google Scholar 

  • EV Sharkov OA Bogatikov (1998) ArticleTitleConcentration mechanisms of the platinum-group elements in layered intrusions of the Kola-Karelia region Geol Ore Deposits 40 372–390

    Google Scholar 

  • Tolstykh N (2007) PGE mineralisation in marginal sulfide ores of the Chineisky Layered Pluton, Russia. Mineral Petrol (epub ahead of print)

  • Trofimov NN, Golubev AI, Filippov NB (2001) Platinum- and gold-bearing vanadium-titanomagnetite deposits in differentiated gabbro-dolerite intrusions of Karelia. In: Orlov VP (ed) Platinum of Russia. Possibilities of development of raw material base of platinum metals in 21st century, Moskow, Stock Company Geoinformmark, pp 200–211

  • CF Vermaak (1976) ArticleTitleThe Merensky reef – thoughts on its environment and genesis Econ Geol 71 1270–1298

    Google Scholar 

  • G von Gruenewaldt (1979) ArticleTitleA review of some recent concepts of the Bushveld Complex with particular reference to sulfide mineralization Can Mineral 17 233–256

    Google Scholar 

  • AH Wilson (2001) ArticleTitleCompositional and lithological controls on the PGE-bearing sulphide zones in the Selukwe Subchamber, Great Dyke: a combined equilibrium-Rayleigh fractionation model J Petrol 42 1845–1867 Occurrence Handle10.1093/petrology/42.10.1845

    Article  Google Scholar 

  • AH Wilson AJ Naldrett M Tredoux (1989) ArticleTitleDistribution and controls of platinum group elements and base metal mineralization in the Darwendale subchamber of the Great Dyke, Zimbabwe Geology 17 649–652 Occurrence Handle10.1130/0091-7613(1989)017<0649:DACOPG>2.3.CO;2

    Article  Google Scholar 

  • AH Wilson CZ Murahwi BM Coghill (2000) ArticleTitleThe geochemistry of the PGE subzone in the Selukwe Subchamber, Great Dyke: an intraformational layer model for platinum group element enrichment in layered intrusions Mineral Petrol 68 115–140 Occurrence Handle10.1007/s007100050006

    Article  Google Scholar 

  • SA Wood (1987) ArticleTitleThermodynamic calculations of the volatility of the platinum group elements (PGE): the PGE content of fluids at magmatic temperatures Geochim Cosmochim Acta 51 3041–3050 Occurrence Handle10.1016/0016-7037(87)90377-2

    Article  Google Scholar 

  • Wood SA (2002) The aqueous geochemistry of the platinum-group elements with applications to ore deposits. In: Cabri LJ (ed) The geology, geochemistry, mineralogy and mineral beneficiation of platinum-group elements. Canadian Institute of Mining, Metallurgy and Petroleum, Spec Vol. 54, pp 211–249

  • Zhu D, Luo T, Xu Y, Tao Y, Huang Z (2004) Soret fractionation – a novel process for origin of the PGE mineralization in the Zhubu mafic-ultramafic intrusion in SW China. In: Shellnutt JG, Zhou MF, Pang KN (eds) Proceedings of the IGCP 479, workshop “Recent advances in magmatic ore systems in mafic-ultramafic rocks”, Hong Kong, China, pp 64–66

Download references

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to R. M. Latypov, S. Yu. Chistyakova or T. T. Alapieti.

Additional information

Authors’ addresses: R. M. Latypov and S. Yu. Chistyakova, Kola Science Centre, Geological Institute, Fersman Str. 16, 184200 Apatity, Russia; Present address: Department of Geosciences, University of Oulu, P. O. Box 3000, Oulu, FIN-90014, Finland; T. T. Alapieti, Department of Geosciences, University of Oulu, P. O. Box 3000, Oulu, FIN-90014, Finland

Rights and permissions

Reprints and permissions

About this article

Cite this article

Latypov, R., Chistyakova, S. & Alapieti, T. PGE reefs as an in situ crystallization phenomenon: the Nadezhda gabbronorite body, Lukkulaisvaara layered intrusion, Fennoscandian Shield, Russia. Mineralogy and Petrology 92, 211–242 (2008). https://doi.org/10.1007/s00710-007-0189-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00710-007-0189-1

Keywords

Navigation