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Mild and Efficient Ring Opening of Epoxides Catalyzed by Potassium Dodecatungstocobaltate(III)

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Summary.

Efficient ring opening of epoxides under mild conditions is reported. Potassium dodecatungstocobaltate(III) trihydrate was used as an efficient catalyst for the alcoholysis and acetolysis of epoxides. Conversion of epoxides to thiiranes was also performed efficiently in the presence of this catalyst.

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Authors and Affiliations

  1. Chemistry Department, Isfahan University, 81746-73441, Isfahan, Iran

    Shahram Tangestaninejad, Valiollah Mirkhani & S. Mohammad R. Mirmohammadi

  2. Chemistry Department, Yasouj University, 75918-74831, Yasouj, Iran

    Majid Moghadam

  3. Institute for Advanced Studies in Basic Sciences, 45138-79368, Gava-Zang, Zanjan, Iran

    Bahram Yadollahi

Authors
  1. Shahram Tangestaninejad
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  2. Majid Moghadam
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  3. Valiollah Mirkhani
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  4. Bahram Yadollahi
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  5. S. Mohammad R. Mirmohammadi
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Correspondence to Shahram Tangestaninejad.

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Tangestaninejad, S., Moghadam, M., Mirkhani, V. et al. Mild and Efficient Ring Opening of Epoxides Catalyzed by Potassium Dodecatungstocobaltate(III). Monatsh. Chem. 137, 235–242 (2006). https://doi.org/10.1007/s00706-005-0415-7

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  • DOI: https://doi.org/10.1007/s00706-005-0415-7

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