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Nanocomposites consisting of nanoporous platinum-silicon and graphene for electrochemical determination of bisphenol A

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Abstract

Three-dimensional nanoporous PtSi (NP-PtSi) alloy was prepared by dealloying ternary PtSiAl alloy ribbons. By combining the nanoporous morphology of PtSi and graphene (GR), a new composite material was developed, which was used to modify the surface of a glassy carbon electrode (GCE). The resulting modified electrodes showed an excellent electrocatalytic activity towards the electro oxidation of bisphenol A. Based on differential pulse voltammetry measurements, NP-PtSi/GR/GCE showed linear response over the concentration range 0.30 to 85 μM bisphenol A, while the detection limit was found to be 0.11 μM (S/N = 3). NP-PtSi/GR/GCE showed also satisfactory stability and selectivity over various compounds present in real samples, and they were successfully applied to the determination of bisphenol A in inoculated milk samples.

Nanoporous PtSi (NP-PtSi) was fabricated by dealloying PtSiAl alloy ribbons. Based on the NP-PtSi alloy and graphene (GR) composites that modified glassy carbon electrode (GCE), a sensitive and stable electrochemical sensor was developed for the determination of bisphenol A by differential pulse voltammetric (DPV) method.

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Acknowledgments

We greatly appreciate the support of Major Natural Science Foundation of Jiangsu Provincial Education Department (16KJA150007), National Natural Science Foundation of China (51371004), and Jiangsu Province Qing Lan Project (SZ2014005).

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Authors and Affiliations

  1. Department of Chemistry and Materials Engineering, Jiangsu Laboratory of Advanced Functional Materials, Changshu Institute of Technology, Changshu, 215500, China

    Shufei Zhang, Yufan Shi, Jiamin Wang, Lei Xiao, Xiaofang Yang, Rongjing Cui & Zhida Han

  2. College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang, 050024, China

    Shufei Zhang

  3. Suzhou Key Laboratory of Food Quality and Safety, School of Biology and Food Engineering, Changshu Institute of Technology, Changshu, 215500, China

    Rongjing Cui

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  1. Shufei Zhang
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  2. Yufan Shi
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Correspondence to Rongjing Cui.

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Zhang, S., Shi, Y., Wang, J. et al. Nanocomposites consisting of nanoporous platinum-silicon and graphene for electrochemical determination of bisphenol A. Microchim Acta 187, 241 (2020). https://doi.org/10.1007/s00604-020-4219-6

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