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Fabrication of a hierarchical dodecyl sulfate-layered double hydroxide nanocomposite on porous aluminum wire as an efficient coating for solid-phase microextraction of phenols

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Abstract

We have synthesized, by a hydrothermal crystallization method, a layered double hydroxide of aluminum that is intercalated with the dodecyl sulfate anion. This nanocomposite is formed on a porous aluminum wire and can be used as a fiber coating for solid-phase microextraction. The nanocomposite has a flowerlike morphology and a high specific surface. The coating can be prepared easily, is mechanically stable, and exhibits relatively high thermal stability. It is capable of extracting phenolic compounds from water samples. Following thermal desorption, the phenols were quantified by GC-MS. The effects of extraction temperature, extraction time, sample ionic strength, stirring rate, pH, desorption temperature and desorption time were studied. Under optimal conditions, the repeatability for one fiber (for n = 5), expressed as the relative standard deviation, is between 3.9 and 7.6 %. The detection limits range from 0.2 to 4 pg mL−1. The method is simple, fast, and inexpensive. The fibers are thermally stable and yield better recoveries than conventional methods of analysis.

We have synthesized, by a hydrothermal crystallization method, a layered double hydroxide of aluminum that is intercalated with the dodecyl sulfate anion. This nanocomposite is formed on a porous aluminum wire and can be used as a fiber coating for solid-phase microextraction.

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References

  1. Benzo M, Gilardoni G, Gandini C, Caccialanza G, Finzi PV, Vidari G, Abdo S, Layedra P (2007) Determination of the threshold odor concentration of main odorants in essential oils using gas chromatography–olfactometry incremental dilution technique. J Chromatogr A 1150:131–135

    Article  CAS  Google Scholar 

  2. Gherman C, Culea M, Cozar O (2000) Comparative analysis of some active principles of herb plants by GC/MS. Talanta 53:253–262

    Article  CAS  Google Scholar 

  3. Bertoli A, Pistelli L, Morelli I, Fraternale D, Giamperi L, Ricci D (2004) Volatile constituents of different parts (roots, stems and leaves) of Smyrnium olusatrum L. Flavour Fragr J 19:522–525

    Article  CAS  Google Scholar 

  4. Gholivand MB, Shamsipur M, Shamizadeh M, Moradian R, Astinchap B (2014) Cobalt oxide nanoparticles as a novel high-efficiency fiber coating for solid phase microextraction of benzene, toluene, ethylbenzene and xylene from aqueous solutions. Anal Chim Acta 822:30–36

    Article  CAS  Google Scholar 

  5. Abolghasemi MM, Karimi B, Yousefi V (2013) Periodic mesoporous organosilica with ionic liquid framework as a novel fiber coating for headspace solid-phase microextraction of polycyclic aromatic hydrocarbons. Anal Chim Acta 804:280–286

    Article  CAS  Google Scholar 

  6. Gholivand MB, Piryaei M, Abolghasemi MM (2011) Anodized aluminum wire as a solid-phase microextraction fiber for rapid determination of volatile constituents in medicinal plant. Anal Chim Acta 701:1–5

    Article  CAS  Google Scholar 

  7. Yu T, Lim B, Xia Y (2010) Aqueous-phase synthesis of single-crystal ceria nanosheets. Angew Chem Int Ed 49:4484–4487

    Article  CAS  Google Scholar 

  8. Shibata T, Fukuda K, Ebina Y, Kogure T, Sasaki T (2008) One-nanometer-thick seed layer of unilamellar nanosheets promotes oriented growth of oxide crystal films. Adv Mater 20:231–235

    Article  CAS  Google Scholar 

  9. Siril PF, Ramos L, Beaunier P, Archirel P, Etcheberry A, Remita H (2009) Synthesis of ultrathin hexagonal palladium nanosheets. Chem Mater 21:5170–5175

    Article  CAS  Google Scholar 

  10. Hernan L, Morales J, Sánchez L, Santos J, Rodríguez-Castellón E, Martínez JL (2000) Kinetics of intercalation of lithium and sodium into lead sulfide-niobium sulfide ((PbS)1.14(NbS2)2). Chem Mater 12:3792–3797

    Article  CAS  Google Scholar 

  11. Günes F, Shin HJ, Biswas C, Han GH, Kim ES, Chae SJ, Choi JY, Lee YH (2010) Layer-by-layer doping of few-layer graphene film. ACS Nano 8:4595–4600

    Article  Google Scholar 

  12. Ma R, Sasaki T (2010) Nanosheets of oxides and hydroxides: ultimate 2D charge-bearing functional crystallites. Adv Mater 22:5082–5104

    Article  CAS  Google Scholar 

  13. Zhang H, Xu ZP, Lu GQ, Smith SC (2009) Intercalation of sulfonate into layered double hydroxide: comparison of simulation with experiment. J Phys Chem C 113:559–563

    Article  CAS  Google Scholar 

  14. Jaubertie C, Holgado MJ, SanRomán MS, Rives V (2006) Comparative study of the synthesis and properties of vanadate-exchanged layered double hydroxides. Chem Mater 18:3114–3121

    Article  CAS  Google Scholar 

  15. Chen W, Feng L, Qu B (2004) Preparation of nanocomposites by exfoliation of ZnAl layered double hydroxides in nonpolar LLDPE solution. Chem Mater 16:368–370

    Article  CAS  Google Scholar 

  16. Iyi N, Ebina Y, Sasaki T (2008) Water-swellable MgAl − LDH (layered double hydroxide) hybrids: synthesis, characterization, and film preparation. Langmuir 24:5591–5598

    Article  CAS  Google Scholar 

  17. Xing LL, Yuan B, Hu SX, Zhang YD, Lu Y, Mai ZH, Li M (2008) Electrochemical synthesis of highly oriented layered zinc hydroxide with intercalated p-aminobenzoic acid. J Phys Chem C 112:3800–3809

    Article  CAS  Google Scholar 

  18. Li B, He J (2008) Multiple effects of dodecanesulfonate in the crystal growth control and morphosynthesis of layered double hydroxides. J Phys Chem C 112:10909–10917

    Article  CAS  Google Scholar 

  19. Romeo V, Gorrasi G, Vittoria V (2007) Encapsulation and exfoliation of inorganic lamellar fillers into polycaprolactone by electrospinning. Biomacromolecules 8:3147–3152

    Article  CAS  Google Scholar 

  20. Xu ZP, Lu GQ (2005) Hydrothermal synthesis of layered double hydroxides (LDHs) from mixed MgO and Al2O3: LDH formation mechanism. Chem Mater 17:1055–1062

    Article  CAS  Google Scholar 

  21. Lazaridis NK, Pandi TA, Matis KA (2004) Chromium(VI) removal from aqueous solutions by Mg − Al − CO3 hydrotalcite: sorption–desorption kinetic and equilibrium studies. Ind Eng Chem Res 43:2209–2215

    Article  CAS  Google Scholar 

  22. Auxilio AR, Andrews PC, Junk PC, Spiccia L (2009) The adsorption behavior of C.I. Acid Blue 9 onto calcined Mg–Al layered double hydroxides. Dyes Pigm 81:103–112

    Article  CAS  Google Scholar 

  23. Zhang P, Qian Gu X, Shi Hu ZP, Ruan X, Yang J, Frost RL (2012) Effective adsorption of sodium dodecylsulfate (SDS) by hydrocalumite (CaAl-LDH-Cl) induced by self-dissolution and re-precipitation mechanism. J Coll Int Sci 367:264–271

    Article  CAS  Google Scholar 

  24. Hermonsín MC, Pavlovic I, UlibarrMA CJ (1997) Hydrotalcite as sorbent for trinitrophenol: sorption capacity and mechanism. Water Res 30:171–179

    Article  Google Scholar 

  25. Wang B, Zhang H, Evans DG, Duan X (2005) Surface modification of layered double hydroxides and incorporation of hydrophobic organic compounds. Mat Chem Phys 92:190–196

    Article  CAS  Google Scholar 

  26. You YW, Vance GF, Zhao HT (2001) Selenium adsorption on Mg–Al and Zn–Al layered double hydroxides. Appl Clay Sci 20:13–25

    Article  CAS  Google Scholar 

  27. Zhao H, Nagy KL (2004) Dodecyl sulfate–hydrotalcite nanocomposites for trapping chlorinated organic pollutants in water. J Coll Int Sci 274:613–624

    Article  CAS  Google Scholar 

  28. You YW, Zhao HT, Vance GF (2002) Surfactant-enhanced adsorption of organic compounds by layered double hydroxides. Colloids Surf A 205:161–165

    Article  CAS  Google Scholar 

  29. You YW, Zhao HT, Vance GF (2002) Hybrid organic–inorganic derivatives of layered double hydroxides and dodecylbenzenesulfonate: preparation and adsorption characteristics. J Mater Chem 12:907–912

    Article  CAS  Google Scholar 

  30. Dékány I, Berger F, Imrik K, Lagaly G (1997) Hydrophobic layered double hydroxides (LDHs): selective adsorbents for liquid mixtures. Colloid Polym Sci 275:681–688

    Article  Google Scholar 

  31. Celis R, Koskinen WC, Cecchi AM, Bresnahan GA, Car-risoza MJ, Ulibarri M, Pavlovic I, Hermosín MC (1999) Sorption of the ionizable pesticide imazamox by organo‐clays and organohydrotalcites. J Environ Sci Health Part B 34:929–941

    Article  Google Scholar 

  32. Celis R, Koskinen WC, Hermosín MC, Ulibarri MA, Cornejo J (2000) Triadimefon interactions with organoclays and organohydrotalcites. J Soil Sci Soc Am 64:36–43

    Article  CAS  Google Scholar 

  33. Jakupca M, Dutta PK (1995) Growth of zinc sulfide thin films with the successive ionic layer adsorption and reaction method as studied by atomic force microscopy. Chem Mater 7:985–989

    Article  Google Scholar 

  34. Dekany I, Haraszti T (1997) Synthesis and photocatalytic activity of TiO2-hectorite layer-by-layer thin films. Colloids Surf A 123:391–401

    Article  Google Scholar 

  35. Aziz-Zanjani MO, Mehdinia A (2014) A review on procedures for the preparation of coatings for solid phase microextraction. Microchim Acta 181:1169–1190

    Article  CAS  Google Scholar 

  36. Abdolmohammad-Zadeh H, Jouyban A, Amini R, Sadeghi G (2013) Nickel-aluminum layered double hydroxide as a nano-sorbent for the solid phase extraction of selenium, and its determination by continuous flow HG-AAS. Microchim Acta 180:619–626

    Article  CAS  Google Scholar 

  37. Abdolmohammad-Zadeh H, Talleb Z (2012) Dispersive solid phase micro-extraction of dopamine from human serum using a nano-structured Ni-Al layered double hydroxide, and its direct determination by spectrofluorometry. Microchim Acta 179:25–32

    Article  CAS  Google Scholar 

  38. Dutta PK, Robins R (1994) DS pyrene sorption in organic-layered double-metal hydroxides. Langmuir 10:1851–1856

    Article  CAS  Google Scholar 

  39. Gholivand MB, Abolghasemi MM, Fattahpour P (2011) Polypyrrole/hexagonally ordered silica nanocomposite as a novel fiber coating for solid-phase microextraction. Anal Chim Acta 704:174–179

    Article  CAS  Google Scholar 

  40. Gholivand MB, Abolghasemi MM, Fattahpour P (2012) Highly porous silica-polyaniline nanocomposite as a novel solid-phase microextraction fiber coating. J Sep Sci 35:101–106

    Article  CAS  Google Scholar 

  41. Gholivand MB, Abolghasemi MM (2012) Inside needle capillary adsorption trap device for headspace solid-phase dynamic extraction based on polyaniline/hexagonally ordered silica nanocomposite. J Sep Sci 35:695–701

    Article  CAS  Google Scholar 

  42. Abolghasemi MM, Yousefi V (2014) Three dimensionally honeycomb layered double hydroxides framework as a novel fiber coating for headspace solid-phase microextraction of phenolic compounds. J Chromatogr A 1345:9–16

    Article  CAS  Google Scholar 

  43. Abolghasemi MM, Yousefi V, Hazizadeh B (2014) An inorganic–organic hybrid material based on ZnO nanoparticles anchored to a composite made from polythiophene and hexagonally ordered silica for use in solid-phase fiber microextraction of PAHs. Microchim Acta 181:639–645

    Article  CAS  Google Scholar 

  44. Abolghasemi MM, Yousefi V, Rafiee E (2014) Keggin-type heteropoly compounds supported on montmorillonite clays offering strong option for efficient solid-phase microextraction coating. J Chromatogr A 1327:14–18

    Article  CAS  Google Scholar 

  45. Abolghasemi MM, Yousefi V, Rafiee E (2014) Polyoxotungstate nanoclusters supported on silica as an efficient solid-phase microextraction fiber of polycyclic aromatic hydrocarbons. Microchim Acta 181:1807–1814

    Article  CAS  Google Scholar 

  46. Boehm HP, Steinle J, Vieweger C (1977) [Zn2Cr(Oh)6]X·2H2O, New Layer Compounds Capable of Anion Exchange and Intracrystalline Swelling. Angew Chem Int Ed Engl 16:265–268

  47. Drezdzon MA (1988) Synthesis of isopolymetalate-pillared hydrotalcite via organic-anion-pillared precursors. Inorg Chem 27:4628–4632

    Article  CAS  Google Scholar 

  48. Bagheri H, Babanezhad E, Khalilian F (2008) A novel sol–gel-based amino-functionalized fiber for headspace solid-phase microextraction of phenol and chlorophenols from environmental samples. Anal Chim Acta 616:49–55

    Article  CAS  Google Scholar 

  49. Ribeiro A, Neves MH, Almeida MF, Alves A, Santos L (2002) Direct determination of chlorophenols in landfill leachates by solid-phase micro-extraction-gas chromatography–mass spectrometry. J Chromatogr A 975:267–274

    Article  CAS  Google Scholar 

  50. Alizadeh N, Zarabadipour H, Mohammadi A (2007) Headspace solid-phase microextraction using an electrochemically deposited dodecylsulfate-doped polypyrrole film to determine of phenolic compounds in water. Anal Chim Acta 605:159–165

    Article  CAS  Google Scholar 

  51. Liu X, Ji Y, Zhang Y, Zhang H, Liu M (2007) Oxidized multiwalled carbon nanotubes as a novel solid-phase microextraction fiber for determination of phenols in aqueous samples. J Chromatogr A 1165:10–17

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Maragheh, Maragheh 55181-83111, Iran

    Mir Mahdi Abolghasemi & Vahid Yousefi

  2. Research Center for Pharmaceutical Nanotechnology, Tabriz University of Medical Sciences, Tabriz, Iran

    Marzieh Piryaei

  3. Faculty of Pharmacy, Tabriz University of Medical Sciences, Tabriz, Iran

    Marzieh Piryaei

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  1. Mir Mahdi Abolghasemi
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  2. Vahid Yousefi
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  3. Marzieh Piryaei
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Correspondence to Mir Mahdi Abolghasemi.

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Abolghasemi, M.M., Yousefi, V. & Piryaei, M. Fabrication of a hierarchical dodecyl sulfate-layered double hydroxide nanocomposite on porous aluminum wire as an efficient coating for solid-phase microextraction of phenols. Microchim Acta 182, 1177–1186 (2015). https://doi.org/10.1007/s00604-014-1441-0

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