Abstract
Water-soluble fluorescent CdTe nanorods (NRs) capped with L-cysteine (Cys) and thioglycolic acid (TGA) were prepared for optical determination of silver ions. These NRs are dispersible, uniform and strongly fluorescent, with an emission wavelength maximum of 585 nm. The fluorescence of such NRs is quenched by silver ions, and this is accompanied by a gradual red shift of the peak from 585 nm to 605 nm. The limit of determination for silver ions is 4.5 nM. The effect of alkali and alkali earth metal ions and of common anions is negligible even at high concentrations. Steady-state fluorescence and UV-vis spectroscopy reveals that competitive binding of Ag ions to Te atoms and to Cys/TGA moieties are responsible for the change in the optical properties observed.
Similar content being viewed by others
References
Bruchez M Jr, Moronne M, Gin P, Weiss S, Alivisatos AP (1998) Semiconductor nanocrystals as fluorescent biological labels. Science 281:2013
Chan WCW, Nie SM (1998) Quantum dot bioconjugates for ultrasensitive nonisotopic detection. Science 281:2016
Mattoussi H, Manro JM, Goldman ER, Anderson GP, Sunder VC, Mikula FV, Bawendi MG (2000) Self-assembly of CdSe-ZnS quantum dot bioconjugates using an engineered recombinant protein. J Am Chem Soc 122:12142
Chen YF, Rosenzweig Z (2002) Luminescent CdS quantum dots as selective ion probes. Anal Chem 74:5132
Jin WJ, Fernández-Argüelles MT, Costa-Feráanndez JM, Pereiro R, Sanz-Medel A (2005) Photoactivated luminescent CdSe quantum dots as sensitive cyanide probes in aqueous solutions. Chem Comm 7:883
Chen CY, Cheng CT, Lai CW, Wu PW, Wu KC, Chou PT, Chou YH, Chiu HT (2006) Potassium ion recognition by 15-crown-5 functionalized CdSe/ZnS quantum dots in H2O. Chem Comm 3:263
Wu CL, Zheng JS, Huang CB, Lai JP, Li SY, Chen C, Zhao YB (2007) Hybrid silica-nanocrystal-organic dye superstructures as post-encoding fluorescent probes. Angew Chem Int Ed 46:5393
Kobnishi K, Hiratani T (2006) Turn-on and selective luminescence sensing of copper ions by a water-soluble Cd10S16 molecular cluster. Angew Chem Int Ed 45:5191
Wu HM, Liang JG, Han HY (2007) A novel method for the determination of Pb2+ based on the quenching of the fluorescence of CdTe quantum dots. Microchim Acta 161:81
Cai ZX, Yang H, Zhang Y, Yan XP (2006) Preparation, characterization and evaluation of water-soluble L-cysteine-capped-CdS nanoparticles as fluorescence probe for detection of Hg (II) in aqueous solution. Anal Chim Acta 559:234
Spanhel L, Weller H, Fojtik A, Henglein A (1987) Photochemistry of semiconductor colloids.17. strong luminescing CdS and CdS-Ag2S particles. Ber Bunsenges Phys Chem 91:88
Kumar A, Kumar S (1996) Catalytic effect of Ag+ in colloidal CdS-induced photooxidation of aniline. Chem Lett 25:711
Xia YS, Cao C, Zhu CQ (2008) Two distinct photoluminescence responses of CdTe quantum dots to Ag (I). J Lumin 128:166
Dong CQ, Qian HF, Fang NH, Ren JC (2006) Study of fluorescence quenching and dialysis process of CdTe quantum dots, using ensemble techniques and fluorescence correlation spectroscopy. J Phys Chem B 110:11069
Liang JG, Ai XP, He ZK, Pang DW (2004) Functionalized CdSe quantum dots as selective silver ion chemodosimeter. Analyst 129:619
Gattǐıas-Asfura KM, Leblanc RM (2003) Peptide-coated CdS quantum dots for the optical detection of copper (II) and silver (I). Chem Comm 21:2684
Chen JL, Zhu CQ (2005) Functionalized cadmium sulfide quantum dots as fluorescence probe for silver ion determination. Anal Chim Acta 546:147
Lai SJ, Chang XJ, Mao J, Zhai YH, Lian N, Zheng H (2007) Determination of silver ion with cadmium sulfide quantum dots modified by bismuthiol II as fluorescence probe,. Ann Chim Rome 97:109
Wang L, Liang AN, Chen HQ, Liu Y, Qian BB, Fu J (2008) Ultrasensitive determination of silver ion based on synchronous fluorescence spectroscopy with nanoparticles. Anal Chim Acta 616:170
Tang B, Niu JY, Yu CG, Zhuo LH, Ge JC (2005) Highly luminescent water-soluble CdTe nanowires as fluorescent probe to detect copper (II). Chem Comm 33:4184
Hsu YJ, Lu SY, Lin YF (2008) Spontaneous reduction of metal ions initiated by ethylenediamine-capped CdS nanowires: a sensing mechanism revealed. Chem Mater 120:2854
Li J, Hong X, Li D, Zhao K, Wang L, Wang HZ, Du ZL, Li JH, Bai YB Li TJ (2004) Mixed ligand system of cysteine and thioglycolic acid assisting in the synthesis of highly luminescent water-soluble CdTe nanorods. Chem Comm 15:1740
Zhuang JQ, Zhang XD, Wang G, Li DM, Yang WS, Li TJ (2003) synthesis of water-soluble ZnS: Mn2+ nanocrystals by using mercaptopropionic acid as stabilizer. J Mater Chem 13:1853
Gao MY, Kirstein S, Mvhwald H, Rogach AL, Kornowski A, Eychmller A, Weller H (1998) Strongly photoluminescent CdTe nanocrystals by proper surface modification. J Phys Chem B 102:8360
Qin WW, Liu WH, Tan MY (2002) Study on the new fluorescence enhancement system of Tb-1,10-bis(2’-carboxylphenyl)-1,4,7,10-tetraoxadecane in silver chloride collosol and its analytical application. Anal Chim Acta 468:287
Wang ZH, Zhao ID, Zhao ZY, He YL (1996) Determination of silver by fluorescence quenching reaction of silver-1, 10-phenanthroline-o-chlorophenylfluorone system. Chin J Anal Chem 24:964
Pan ZT, Zhang T, Xu MY (1997) Determination of trace silver by fluorescence quenching with meso-tetra(4-pyridyl ) porphyrin and its application. Chin J Anal Chem 25:1293
Shi WJ, Xu F, Yu Y (2005) Study and spectrophotometric determination of trace silver with iodide-victoria pure blue BO System. Spectrosc Spectr Anal 25:765
Murphy CJ (2002) Optical sensing with quantum dots. Anal Chem 74:520A
Lianos P, Thomas JK (1986) Cadmium sulfide of small dimensions produced in inverted micelles. Chem Phys Lett 125:299
Isarov A, Chrysochoos J (1997) Optical and photochemical properties of nonstoichiometric cadmium sulfide nanoparticles: surface modification with copper (II) ions. Langmuir 13:3142
Borchert H, Talapin DV, Gaponik N, McGinley C, Adam S, Lobo A, Möller T, Weller H (2003) Relations between the photoluminescence efficiency of CdTe Nanocrystals and their surface properties revealed by synchrotron XPS. J Phys Chem B 107:9662
Yougjin K, Robert JC, Joscph HT (2001) Gold nanoparticle-based sensing of “spectroscopically silent” heavy metal ions. Nano Lett 1:165
Acknowledgments
The work was financially supported by the Education Commission Natural Science Foundation of Anhui Province (NO. 2006kj153B, 2006jql204, 2008jp1101).
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
ESM 1
(DOC 659 KB).
Rights and permissions
About this article
Cite this article
Zheng, A., Chen, J., Li, H. et al. Highly sensitive fluorescence determination of silver ions based on functionalized cadmium telluride nanorods. Microchim Acta 165, 187–194 (2009). https://doi.org/10.1007/s00604-008-0119-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00604-008-0119-x