Abstract
The wettability property of a material surface is highly dependent on the topography of the surface micro/nanostructure. Femtosecond (fs) laser can be used to fabricate various kinds of surface micro/nanostructures. We present parallel microgroove arrays with unique cross-sectional profiles on the surface of an aluminum foil induced by varying the laser fluence and the scanning spacing. The laser textured aluminum surface shows directional spreading of water and inherently hydrophilic aluminum surface becomes superhydrophilic. A water droplet spreads highly anisotropically on the processed area and flows preferentially along the microgrooves. The maximum average spreading velocity of water droplet along the laser textured microgrooves is ~ 200 mm/s, while it is much slower in the direction perpendicular to the microgrooves, which is 41 mm/s. Moreover, the spreading distance of water and time t in both directions have a linear relation with t1/2. The fast-self-spreading motion of water along the microgroove is due to its capillary pressure and a local energy barrier at the boundary between two parallel microgrooves. In addition, laser-modified surface roughness and laser-altered chemical composition on the aluminum surface play a role in enhancing the superhydrophilicity and the directional water spreading behavior. Our research can be applied in the fields of microfluidics, lab-on-chip technology, chemical and biological sensors and heat transfer devices.
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References
Baldacchini T, Carey JE, Zhou M, Mazur E (2006) Superhydrophobic surfaces prepared by microstructuring of silicon using a femtosecond laser. Langmuir 22:4917–4919. https://doi.org/10.1021/la053374k
Bico J, Tordeux C, Quéré D (2001) Rough wetting. Europhys Lett 55:214
Bizi-bandoki P, Valette S, Audouard E, Benayoun S (2013) Time dependency of the hydrophilicity and hydrophobicity of metallic alloys subjected to femtosecond laser irradiations. Appl Surf Sci 273:399–407. https://doi.org/10.1016/j.apsusc.2013.02.054
Boinovich LB, Modin EB, Sayfutdinova AR, Emelyanenko KA, Vasiliev AL, Emelyanenko AM (2017) Combination of functional nanoengineering and nanosecond laser texturing for design of superhydrophobic aluminum alloy with exceptional mechanical and chemical properties. ACS Nano 11:10113–10123. https://doi.org/10.1021/acsnano.7b04634
Cardoso J, Aguilar-Morales A, Alamri S, Huerta-Murillo D, Cordovilla F, Lasagni A, Ocaña J (2018) Superhydrophobicity on hierarchical periodic surface structures fabricated via direct laser writing and direct laser interference patterning on an aluminium alloy. Opt Lasers Eng 111:193–200
Cassie A, Baxter S (1944) Wettability of porous surfaces. Trans Faraday Soc 40:546–551
Chen F et al (2011) Anisotropic wetting on microstrips surface fabricated by femtosecond laser. Langmuir 27:359–365. https://doi.org/10.1021/la103293j
Chu KH, Xiao R, Wang EN (2010) Uni-directional liquid spreading on asymmetric nanostructured surfaces. Nat Mater 9:413–417. https://doi.org/10.1038/nmat2726
Cunha A, Serro AP, Oliveira V, Almeida A, Vilar R, Durrieu M-C (2013) Wetting behaviour of femtosecond laser textured Ti–6Al–4 V surfaces. Appl Surf Sci 265:688–696
De Marco C et al (2010) Surface properties of femtosecond laser ablated PMMA. ACS Appl Mater Interfaces 2:2377–2384. https://doi.org/10.1021/am100393e
Feng XJ, Jiang L (2006) Design and creation of superwetting/antiwetting surfaces. Adv Mater 18:3063–3078. https://doi.org/10.1002/adma.200501961
Feng L, Zhu Y, Wang J, Shi X (2017) One-step hydrothermal process to fabricate superhydrophobic surface on magnesium alloy with enhanced corrosion resistance and self-cleaning performance. Appl Surf Sci 422:566–573
Gao X, Yao X, Jiang L (2007) Effects of rugged nanoprotrusions on the surface hydrophobicity and water adhesion of anisotropic micropatterns. Langmuir 23:4886–4891. https://doi.org/10.1021/la0630357
Goniakowski J, Finocchi F, Noguera C (2007) Polarity of oxide surfaces and nanostructures. Rep Prog Phys 71:016501
Jokinen V, Leinikka M, Franssila S (2009) Microstructured surfaces for directional wetting. Adv Mater 21:4835–4838. https://doi.org/10.1002/adma.200901171
Kenar H et al (2013) Femtosecond laser treatment of 316L improves its surface nanoroughness and carbon content and promotes osseointegration: an in vitro valuation. Colloids Surf B Biointerfaces 108:305–312. https://doi.org/10.1016/j.colsurfb.2013.02.039
Kondo R, Nakajima D, Kikuchi T, Natsui S, Suzuki RO (2017) Superhydrophilic and superhydrophobic aluminum alloys fabricated via pyrophosphoric acid anodizing and fluorinated SAM modification. J Alloys Compd 725:379–387
Ley JR, Kwon YW, Park C, Menon SK (2017) Corrosion of femtosecond laser surface textured aluminium alloy. Corros Eng Sci Technol 52:526–532
Li BJ, Li H, Huang LJ, Ren NF, Kong X (2016) Femtosecond pulsed laser textured titanium surfaces with stable superhydrophilicity and superhydrophobicity. Appl Surf Sci 389:585–593. https://doi.org/10.1016/j.apsusc.2016.07.137
Li J, Zhao S, Du F, Zhou Y, Yu H (2018) One-step fabrication of superhydrophobic surfaces with different adhesion via laser processing. J Alloys Compd 739:489–498
Lian Z, Xu J, Wang Z, Wang Z, Weng Z, Yu H (2017) Fabrication and applications of two-and three-dimensional curved surfaces with robust underwater superoleophobic properties. J Mater Sci 52:1123–1136
Liang J et al (2015) Facile fabrication of superhydrophilic/superhydrophobic surface on titanium substrate by single-step anodization and fluorination. Appl Surf Sci 338:126–136
Long J et al (2018) Hierarchical micro-and nanostructures induced by nanosecond laser on copper for superhydrophobicity, ultralow water adhesion and frost resistance. Mater Des 155:185–193
Ngo CV, Chun DM (2018) Control of laser-ablated aluminum surface wettability to superhydrophobic or superhydrophilic through simple heat treatment or water boiling post-processing. Appl Surf Sci 435:974–982
Saleema N, Sarkar DK, Gallant D, Paynter RW, Chen XG (2011) Chemical nature of superhydrophobic aluminum alloy surfaces produced via a one-step process using fluoroalkyl-silane in a base medium. ACS Appl Mater Interfaces 3:4775–4781. https://doi.org/10.1021/am201277x
Sarbada S, Shin YC (2017) Superhydrophobic contoured surfaces created on metal and polymer using a femtosecond laser. Appl Surf Sci 405:465–475. https://doi.org/10.1016/j.apsusc.2017.02.019
Song Y et al (2018) Controllable superhydrophobic aluminum surfaces with tunable adhesion fabricated by femtosecond laser. Opt Laser Technol 102:25–31
Tavakoli AH et al (2013) Amorphous alumina nanoparticles: structure, surface energy, and thermodynamic phase stability. J Phys Chem C 117:17123–17130
Vorobyev AY, Guo CL (2009) Metal pumps liquid uphill. Appl Phys Lett 94:224102. https://doi.org/10.1063/1.3117237
Vorobyev AY, Guo CL (2010) Laser turns silicon superwicking. Opt Express 18:6455–6460. https://doi.org/10.1364/OE.18.006455
Vorobyev A, Guo CL (2013) Nanochemical effects in femtosecond laser ablation of metals. Appl Phys Lett 102:074107
Vorobyev A, Guo C (2015) Multifunctional surfaces produced by femtosecond laser pulses. J Appl Phys 117:033103
Washburn EW (1921) The dynamics of capillary flow. Phys Rev 17:273
Wenzel RN (1936) Resistance of solid surfaces to wetting by water. Ind Eng Chem 28:988–994
Wu SZ et al (2010) One-step preparation of regular micropearl arrays for two-direction controllable anisotropic wetting. Langmuir 26:12012–12016. https://doi.org/10.1021/la1015753
Yan H, Rashid MRBA, Khew SY, Li F, Hong M (2018) Wettability transition of laser textured brass surfaces inside different mediums. Appl Surf Sci 427:369–375. https://doi.org/10.1016/j.apsusc.2017.08.218
Yin K, Yang S, Dong X, Chu D, Duan JA, He J (2018) Ultrafast achievement of a superhydrophilic/hydrophobic janus foam by femtosecond laser ablation for directional water transport and efficient fog harvesting. ACS Appl Mater Interfaces 10:31433–31440. https://doi.org/10.1021/acsami.8b11894
Yong J, Chen F, Yang Q, Jiang Z, Hou X (2018) A review of femtosecond-laser-induced underwater superoleophobic surfaces. Adv Mater Interf 5:1701370
Zhang C, Yao J, Lan S, Trofimov VA, Lysak TM (2013) Effects of plasma confinement on the femtosecond laser ablation of silicon. Opt Commun 308:54–63
Acknowledgements
This work was supported by the Science and Technology Planning Project of Guangzhou, China (Grant no. 201607010261), the Research Fund Program of Guangdong Provincial Key Laboratory of Nanophotonic Functional Materials and Devices, National Natural Science Foundation of China (Grant no. 11204044), Young Top-Notch Personnel Program of Guangzhou University (Grant no. BJ201711) and the 2018 State Scholarship Fund for University Young Teacher Study Abroad.
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Zhang, C., Cheng, L., Tan, B. et al. Directional liquid spreading on laser textured aluminum surface. Microsyst Technol 26, 2767–2776 (2020). https://doi.org/10.1007/s00542-020-04914-6
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DOI: https://doi.org/10.1007/s00542-020-04914-6