Abstract
In the work, a novel fabrication method for homogeneous and sharp nanoprobe array on (111) silicon wafer is presented. The specific spatial structure of {111} planes and the unique anisotropic etching mechanism on (111) wafer were utilized to form a size controllable funnel-neck structure. A highly downscaled size-reduction technology is developed for precise size control. Followed with a self-limiting oxidation procedure, sharp and long needles can be made with precise size control requiring only a series of conventional processes (dry etching of silicon by DRIE, anisotropic wet etching by potassium hydroxide solution and thermal-oxidation-based tip sharpening). The fabricated probe, whose tip’s diameter is less than 30 nm, can potentially have broad application to cell research.
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References
Beard JD, Gordeev SN (2011) fabrication and buckling dynamic of nanoneedle AFM probes. Nanotechnology 22:175303
Fazzini PF, Bonafos C, Claverie A, Hubert A, Ernst T (2011) Modeling stress retarded self-limiting oxidation of suspended silicon nanowires for the development of silicon nanowire-based nanodevices. J Appl Phys 110:033524
Fletcher PC, Felts JR, Dai Z, Jacobs TD, Zeng H, Lee W et al (2010) Wear-resistant diamond nanoprobe tips with integrated silicon heater for tip-based nanomanufacturing. ACS Nano 4:3338–3344
Gao D, He R, Carraro C, Howe RT, Yang P, Maboudian R (2005) Selective growth of Si nanowire arrays via galvanic displacement processes in water-in-oil microemulsions. JACS 127:4574–4575
Heike S, Hashizume T, Wada Y (1996) Nanoneedle formation on silicon (111) surface using a scanning tunneling microscope tip. J Appl Phys 80:4180–4188
Kawano T, Cho CY, Li W (2012) Carbon Nanotube-based nanoprobe electrode. Sens Actuators A 187:79–83
Kim BH, Pamungkas MA, Park M, Kim G, Lee K-R, Chung Y-C (2011) Stress evolution during the oxidation of silicon nanowires in the sub-10 nm diameter regime. J Appl Lett 99:143115
Lee KN, Jung S-W, Kim WH, Lee MH, Shin K-S, Seong WK (2007) Well controlled assembly of silicon nanowires by nanowire transfer method. Nanotechnology 18:445302
Paik S-J, Park S, Zarnitsyn V, Choi S, Guo XD, Prausnitz MR, et al (2012) A highly dense nanoneedle array for intracellular gene delivery. In: Hilton head workshop, South Carolina, pp 149–152
Rangelow IW, Gotzalk T, Abedinov N, Grabiec P, Edingger K (2001) Thermal nanoprobe. Microelectron Eng 57–58:737–748
Shalek AK, Robinson JT, Karp ES, Lee S, Ahn D, Yoon MH et al (2010) Vertical silicon nanowires as a universal platform for delivering biomolecules into living cells. PNA 107:1870–1875
Shin K, An T, Moon W, Lim G, Jeon JU (2011) A FET mounted nano probe with a CNT for surface electrical properties. Proc Eng 25:1657–1660
Yaghootkar B, Karhrizi M (2015) Promising method toward realization of ultra-low-cost silicon microrod array with nanotip. J Vac Sci Technol B 33(2):021803
Zhang XS, Liu J, Wang B, Zhang T (2014) Fabrication of silicon nanotip arrays with high aspect ratio by cesium chloride self-assembly and dry etching. AIP Adv 4:031335
Acknowledgements
We appreciate financial support from the National Basic Research Program of China Granted Nos. 2012CB933301, 2012CB934102, the Fund for Creative Research of NSFC Granted No. 61321492, the National Natural Science Foundation of China (Nos. 91323304, 81201358, 61327811, 81402468).
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Zhang, X., Yu, X., Li, T. et al. A novel method to fabricate silicon nanoprobe array with ultra-sharp tip on (111) silicon wafer. Microsyst Technol 24, 2913–2917 (2018). https://doi.org/10.1007/s00542-017-3687-z
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DOI: https://doi.org/10.1007/s00542-017-3687-z