Abstract
This study reports an ISFET-based pH sensor utilizing a tantalum pentoxide (Ta2O5) as the sensing layer. Commercial PET film for mass production of touch panel coated with Ta2O5 film is used as the extended gate electrode connecting to a MOSFET chip for H+ ion measurement. The low-cost and plug-and-sense PET sensing file makes the developed sensor is disposable. The high corrosion-resistance of Ta2O5 layer greatly extends the lifetime and the pH sensing range for the solid-state sensor. Theoretical Nernst response is adopted to evaluate the sensing performance of the developed pH sensor. Results show that the developed pH sensor exhibits high sensitivity of 24.18 mV/pH and good linearity of R2 = 0.9798 in the pH range from 1 to 13. In addition, the developed sensor also shows excellent sensing performance including ultra-fast response (<10 s), good repeatability (variation ~0.32 %) and good stability (variation <1 %). Moreover, the developed Ta2O5-based pH sensor shows low interference response to the existence of sodium and potassium interference ions. The developed solid state pH sensor provides a low-cost yet high performance way for developing disposable pH sensors.
Similar content being viewed by others
References
Artigas J, Beltran A, Jimenez C, Baldi A, Mas R, Dominguez C, Alonso J (2001) Application of ion sensitive field effect transistor based sensors to soil analysis. Comput Electron Agr 31:281–293
Banna MH, Najjaran H, Sadiq R, Imran SA, Rodriguez MJ, Hoorfar M (2014) Miniaturized water quality monitoring pH and conductivity sensors. Sensor Actuat B Chem 193:434–441
Batista PD, Mulato M (2005) ZnO extended-gate field-effect transistors as pH sensors. Appl Phys Lett 87:143508
Bausells J, Carrabina J, Errachid A, Merlos A (1999) Ion-sensitive field-effect transistors fabricated in a commercial CMOS technology. Sensor Actuat B Chem 57:56–62
Bergveld P (1970) Development of an ion-sensitive solid-state device for neurophysiological measurements. IEEE Trans Biomed Eng 17:70–71
Bohnke C, Duroy H, Fourquet JL (2003) PH sensors with lithium lanthanum titanate sensitive material: applications in food industry. Sensor Actuat B Chem 89:240–247
Chen M, Jin Y, Qu XH, Jin QH, Zhao JL (2014) Electrochemical impedance spectroscopy study of Ta2O5 based EIOS pH sensors in acid environment. Sensor Actuat B Chem 192:399–405
Chiang JL, Jhan SS, Hsieh SC, Huang AL (2009) Hydrogen ion sensors based on indium tin oxide thin film using radio frequency sputtering system. Thin Solid Films 517:4805–4809
Fog A, Buck RP (1984) Electronic semiconducting oxides as Ph sensors. Sens Actuator 5:137–146
Gao W, Song JF (2009) Polyaniline film based amperometric pH sensor using a novel electrochemical measurement system. Electroanalysis 21:973–978
Gutes A, Carraro C, Maboudian R (2013) Nitrate amperometric sensor in neutral pH based on Pd nanoparticles on epoxy-copper electrodes. Electrochim Acta 103:38–43
Hosoki A, Nishiyama M, Igawa H, Seki A, Choi Y, Watanabe K (2013) A surface plasmon resonance hydrogen sensor using Au/Ta2O5/Pd multi-layers on hetero-core optical fiber structures. Sensor Actuat B Chem 185:53–58
Huang WD, Cao H, Deb S, Chiao M, Chiao JC (2011) A flexible pH sensor based on the iridium oxide sensing film. Sens Actuat A Phys 169:1–11
Karyakin AA, Bobrova OA, Luckachova LV, Karyakina EE (1996) Potentiometric biosensors based on polyaniline semiconductor films. Sensor Actuat B-Chem 33:34–38
Kwon DH, Cho BW, Kim CS, Sohn BK (1996) Effects of heat treatment on Ta2O5 sensing membrane for low drift and high sensitivity pH-ISFET. Sensor Actuat B-Chem 34:441–445
Liao YH, Chou JC (2009) Preparation and characterization of the titanium dioxide thin films used for pH electrode and procaine drug sensor by sol-gel method. Mater Chem Phys 114:542–548
Pan CW, Chou JC, Sun TP, Hsiung SK (2005) Development of the tin oxide pH electrode by the sputtering method. Sensor Actuat B Chem 108:863–869
Rao J, Varlamov S, Park J, Dligatch S, Chtanov A (2013) Optimization of dielectric-coated silver nanoparticle films for plasmonic-enhanced light trapping in thin film silicon solar cells. Plasmonics 8:785–791
Schoning MJ, Brinkmann D, Rolka D, Demuth C, Poghossian A (2005) CIP (cleaning-in-place) suitable “non-glass” pH sensor based on a Ta2O5-gate EIS structure. Sens Actuat B Chem 111:423–429
Suss W, Eggert H, GorgesSchleuter M, Jakob W, Lindemann K, Hoffmann W, Rapp R (1997) Step by step development of an electrochemical microanalytical system. Microsyst Technol 3:97–101
Tao C, Xu LL, Guan JG (2013) Well-dispersed mesoporous Ta2O5 submicrospheres: enhanced photocatalytic activity by tuning heating rate at calcination. Chem Eng J 229:371–377
Vanderspiegel J, Lauks I, Chan P, Babic D (1983) The extended gate chemically sensitive field-effect transistor as multi-species microprobe. Sensor Actuator 4:291–298
Wang Z, Hu YM, Wang W, Zhang X, Wang BX, Tian HY, Wang Y, Guan JG, Gu HS (2012) Fast and highly-sensitive hydrogen sensing of Nb2O5 nanowires at room temperature. Int J Hydrogen Energ 37:4526–4532
Zhuo VYQ, Jiang Y, Li MH, Chua EK, Zhang Z, Pan JS, Zhao R, Shi LP, Chong TC, Robertson J (2013) Band alignment between Ta2O5 and metals for resistive random access memory electrodes engineering. Appl Phys Lett 102:062106
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Wu, YC., Wu, SJ. & Lin, CH. Mass-produced polyethylene-terephthalate film coated with tantalum pentoxide for pH measurement under ISFET detection configuration. Microsyst Technol 23, 293–298 (2017). https://doi.org/10.1007/s00542-015-2474-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00542-015-2474-y