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A review on pH sensitive materials for sensors and detection methods

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Abstract

This article focuses on the review of current material and techniques for the selection of best combination among the pH sensitive materials related to pH detection methods and sensors. Researchers have studied various pH sensitive polymers, chemicals and found that few measurement techniques do not have enough accuracy to observe the pH when salt is present and this has been examined further. The current work is based on comprehensive literature survey and discusses a variety of pH sensitive materials for detection methods using different sensors including their applications, mechanism of action and merits, demerits. This analysis leads to a conclusion that there are a number of important properties of the pH sensitive material and the matrix, which has to be considered in the light of a target application finally dictating the characteristics of the sensor. In many cases, a combinatorial approach of two pH sensitive materials or sensors seems to be more effective with better real time response, sensitivity, sensor resolution and operational stability in place of the common standard techniques.

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References

  • Arshak A, Gill EI, Arshak K, Korostynska O, Cunniffe C (2007) Drop-coated polyaniline composite conductimetric pH sensors. In: Electronics technology, 30th international Spring seminar on. IEEE, pp 213–218

  • Bashir R, Gupta A (2007) Nanotechnology in biology and medicine. Chapter 38. Integrated Cantilever-Based Biosensors for the Detection of Chemical and Biological Entities, CRC Press, Boca Raton

  • Boisen A, Thundat T (2009) Design and fabrication of cantilever array biosensors. Materials Today 12:9

    Article  Google Scholar 

  • Bojinov VB, Simeonov DB, Georgiev NI (2008) A novel blue fluorescent 4-(1,2,2,6,6-pentamethylpiperidin-4-yloxy)-1,8-naphthalimide pH chemosensor based on photoinducedelectron transfer. Dyes Pigments 76:41–46

    Article  Google Scholar 

  • Cai QY, Grimes CA (2000) A remote query Magnetoelastic pH sensor. Elsevier, Amsterdam

    Google Scholar 

  • Davis J, Vaughan DH, Cardosi MF (1998) Modification of catechol polymer, redox properties during lectropolymerization in the presence of aliphatic amines. Electrochim Acta 43:291–300

    Article  Google Scholar 

  • Deronzier A, Moutet JC (1996) Polypyrrole films containing metal complexes: syntheses and applications. Coord Chem Rev 147:339–371

    Article  Google Scholar 

  • Gillies RJ, Raghunand N, Garcia-Martin ML, Gatenby RA (2004) pH imaging A review of pH measurement methods and applications in cancers. IEEE Eng Med Biol Mag 23:57–64

    Article  Google Scholar 

  • Hashemi P, Mehdi M (2005) Preparation of a novel optical sensor for low pH values using agarose memberanes as support. Elsevier, Amsterdam

    Google Scholar 

  • Herlem G, Lakard B, Herlem M, Fahys B (2001) pH sensing at Pt electrode surfaces coated with linear polyethylenimine from anodic polymerization of ethylenediamine. J Electrochem Soc 148:E435–E438

    Article  Google Scholar 

  • Hizawa T, Sawada K, Takao H, Ishida M (2006a) Fabrication of two-dimensional pH image sensor using a charge transfer technique. Elsevier, Amsterdam

    Google Scholar 

  • Hizawa T, Sawada K, Takao H, Ishida M (2006b) Fabrication of two dimensional pH image sensor using a charge transfer technique. Elsevier, Amsterdam

    Google Scholar 

  • Ji H-F, Hansen KM, Hu Z, Thundat T (2001) Detection of pH variation using modified microcantilever sensors. Sens Actuators B 72:233–238

    Article  Google Scholar 

  • Kang TF, Xie ZY, Tang H, Shen GL, Yu RQ (1997) Potentiometric pH sensors based on chemically modified electrodes with electropolymerized metal-tetraaminophthalocyanine. Talanta 45:291–296

    Article  Google Scholar 

  • Karyakin AA, Bobrova OA, Lukachova LV, Karyakina EE (1996) Potentiometric biosensors based on polyaniline semiconductor films. Sens Actuators B: Chem 33(34–38):53

    Google Scholar 

  • Khan MI, Lin F (2014a) Comparative analysis and design of harmonic aware low power latches and flip-flops. 2014 IEEE International Conference on Electron Devices and Solid-State Circuits, Chengdu, China

  • Khan MI, Lin F (2014b) Impact of transistor model accuracy on harmonic spectra emitted by logic circuits. 2014 12th IEEE conference on solid-state and integrated circuit technology, Guilin, China

  • Khan MI, Khan AM, Nouman A, Azhar MI, Saleem MK (2012) pH sensing materials for MEMS sensors and detection techniques. In: International conference on solid-state and integrated circuit vol. 32 (ICSIC 2012), vol. 22

  • Khan MI, Buzdar AR, Lin F (2014b) Self-heating and reliability issues in FinFETs and 3D ICs. 2014 12th IEEE conference on solid-state and integrated circuit technology, Guilin, China

  • Khan MI, Buzdar AR, Lin F (2014) Ballistic transport modeling in advanced transistors. 2014 12th IEEE conference on solid-state and integrated circuit technology, Guilin, China

  • Khan MI, Shoukat R, Mukherjee K, Dong H (2017) Analysis of harmonic contents of switching waveforms emitted by the ultra high speed digital CMOS integrated circuits for use in future micro/nano systems applications. Microsyst Technol. doi:10.1007/s00542-017-3486-6

  • Komura T, Ishihara M, Yamaguchi T, Takahashi K (2000) Charge-transporting properties of electropolymerized phenosafranin in aqueous media. Journal of Electroanalytical Chemistry 493:84–92

    Article  Google Scholar 

  • Korostynska O, Arshak K, Gill E, Arshak A (2007) Review on state-of-the-art in polymer based pH sensors. Sensors 7:3027–3042

    Article  Google Scholar 

  • Kumar S, Babankumar RT, Kumar M (2015) Soil pH sensing techniques and technologies—a review. Int J Adv Res Electr Electr Instrum Eng 4(5):4452–4456

    Google Scholar 

  • Lakard B, Herlem G, De Labachelerie M, Daniau W, Martin G et al (2004) Miniaturized pH biosensors based on electrochemically modified electrodes with biocompatible polymers. Biosens Bioelectron 19(595–606):54

    Google Scholar 

  • Lakard B, Herlem G, Lakard S, Guyetant R, Fahys B (2005) Potentiometric pH sensors based on electrodeposited polymers. Polymer 46(12233–12239):55

    Google Scholar 

  • Lakard B, Segut O, Lakard S, Herlem G, Gharbi T (2007) Potentiometric miniaturized pH sensors based on polypyrrole films. Sens Actuators B: Chem 122:101–108

    Article  Google Scholar 

  • Mahaveer KJ, Cai Q, Grimes CA (2001) A wireless micro-sensor for simultaneous measurement of pH, temperature and pressure. Smart Mater Struct 10:347–353

    Article  Google Scholar 

  • Maleki N, Safavi AF (2004) Sedaghatpour. Talanta 64:830

    Article  Google Scholar 

  • Mcnaughton BH, Anker JN, Kopelman R (2005) Magnetic microdrill as a modulated fluorescent pH sensor. J Magn Magn Mater 293:696–701

    Article  Google Scholar 

  • MICROSENS EPFL Switzerland (2007) Product specific data sheet—Ion sensitive field effect transistors (ISFETS). MICROSENS EPFL Innovation Park Building, Lausanne, Switzerland. http://microsens.ch/products/pdf/MSFET_Datasheet.pdf. Accessed 10 May 2017

  • O’Hare D, Parker KH, Winlove CP (2006) Metal-Oxide pH sensors for physiological application. Elsevier, Amsterdam

    Google Scholar 

  • Ploshinskii AV (1988) Electrically focused conductometric sensors. Meas Tech 31:1015. doi:10.1007/BF00864891

    Article  Google Scholar 

  • Ruan C, Ong KG, Mungle EC, Maggie P, Nickl NJ, Grimes CA (2003) A wireless pH sensor based on the use of salt-independent polymer spheres. Sens Acuators B, Chem 9(1–2):61–69

    Article  Google Scholar 

  • Safavi A, Maleki N, Rostmzadeh A, Maesum S (2007) CCD camera full range pH sensor array. Talanta. 71(1):498–501

    Article  Google Scholar 

  • Santiago KS, Bartolome AJ, John VB (1998) Electrochemically synthesized polymer-based pH sensors. Philipp J Sci 128:120–126

    Google Scholar 

  • Santiago KS, Bartolome AJ, John VB (1999) Electrochemically synthesized polymer-based pH sensors. Philipp J Sci 128:120–126

    Google Scholar 

  • Shoukat R, Khan MI (2017a) Design and development of a clip building block system for MEMS. Microsyst Technol. doi:10.1007/s00542-017-3453-2

    Google Scholar 

  • Shoukat R, Khan MI (2017b) Synthesis of vertically aligned carbon nanofibers using inductively coupled plasma-enhanced chemical vapor deposition. Electr Eng. doi:10.1007/s00202-017-0561-z

    Google Scholar 

  • Shoukat R, Khan MI (2017c) Growth of nanotubes using IC-PECVD as benzene carbon carrier. Microsyst Technol. doi:10.1007/s00542-017-3353-5

    Google Scholar 

  • Shoukat R, Khan MI (2017d) Nanotechnology based electrical control and navigation system for worm guidance using electric field gradient. Microsyst Technol. doi:10.1007/s00542-017-3444-3

    Google Scholar 

  • Slim C, Ktari N, Cakara D, Kanoufi F, Combellas C (2007) Polyaniline films based ultramicroelectrodes sensitive to pH. Elsevier, Amsterdam

    Google Scholar 

  • Stetter JR, Heketh PJ, Hunter GW (2006) Sensors: engineering structures and materials from micro to nano. The electrochemical society interface, spring

  • Talaie A (1997) Conducting polymer based pH detector: A new outlook to pH sensing technology. Polymer 38:1145–1150

    Article  Google Scholar 

  • Thong TQ, Gerlach G, Sorber J, Arndt KF (2006) Hydrogel-based piezoresistive pH sensors:design, simulation and output characteristics. Sensor Actuators B: Chem 117:17–26

    Article  Google Scholar 

  • Wang X, Boschetti C, Ruedas-Rama MJ, Tunnacliffe A, Hall EA (2010) Ratiometric pH-dot ANSors. Analyst. 135(7):1585–1591. doi:10.1039/b922751b (Epub 2010 May 6)

    Article  Google Scholar 

  • Yuqing M, Jianrong C, Keming F (2005) New technology for the detection of pH. Elsevier, New York

    Google Scholar 

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Correspondence to Muhammad Imran Khan.

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Khan, M.I., Mukherjee, K., Shoukat, R. et al. A review on pH sensitive materials for sensors and detection methods. Microsyst Technol 23, 4391–4404 (2017). https://doi.org/10.1007/s00542-017-3495-5

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